On a power series solution to the Boussinesq equation

For certain initial and boundary conditions the Boussinesq equation, a nonlinear partial differential equation describing the flow of water in unconfined aquifers, can be reduced to a boundary value problem for a nonlinear ordinary differential equation. Using Song et al.'s (2007) [7] approach, we show that for zero head initial condition and power-law flux boundary condition at the inlet boundary, the solution in the form of power series can be obtained with Barenblatt's (1990) [2] rescaling procedure applied to the power series solution obtained in Song et al. (2007) [7] for the power-law head boundary condition. Polynomial approximations can then be obtained by taking terms from the power series. Although for a small number of terms the newly obtained approximations may be worse than polynomial approximations obtained by other techniques, any desired accuracy can be achieved by taking more terms from the power series.     

Paleoproterozoic quartz-pebble conglomerate type uranium mineralisation in Mankarhachua area,Angul district,Orissa

Ground Radiometric survey of Paleoproterozoic pyritiferous quartz-pebble conglomerate (QPC) occurring to the north of Pallahara area led to the discovery of a QPC type uranium mineralisation near Mankarhachua village. Significant radioactivity is recorded in three sub-parallel uraniferous QPC horizons with metamorphosed pebbly to medium grained recrystallised massive sandstones. Detrital grains of uranothorite, thorite, radioactive allanite, monazite, zircon, minute uraninite grains in carbonaceous matter and thucolite contributes to the radioactive phases present in QPC matrix. Adsorbed U on limonite and goethite, secondary uranyl minerals in matrix, along bedding planes and fractures are commonly observed. This discovery has opened up a new horizon for future exploration for QPC type uranium mineralization in the area. The paper presents observations on geology, radioactivity, petrological and geochemical nature of the uraniferous QPC horizons.     

Effects of soil type and fertilizer on As speciation in rice paddy contaminated with As-containing pesticide

Inorganic arsenic (As) pesticides have been widely used for decades in many countries. However, insufficient data are available on the chemical speciation of inorganic arsenicals in tropical paddy soils. Inorganic As-containing pesticides were used in tropical countries, a few decades ago, however, their fate have not been studied. Hence, the objective of this study was to determine fractionation of inorganic arsenicals and to assess As lability with/without fertilizer application using a static incubation experiment. Eight soils from wet and dry regions of Sri Lanka were amended with 1,000 mg/kg arsenate for this purpose. The FT-IR and XRF results suggested that soils in the wet region were rich in Fe/Al-oxides. Paddy soils in the dry zone showed high As lability. These low-humic gley soils have low Fe/Al oxyhydroxide and alkaline pH. In contrast, the wet zone had soils with higher As retention capacity, high amounts of Fe/Al oxyhydroxide, and acidic pH. Arsenic lability increased considerably 30 days after fertilizer application. Overall, As lability was mainly influenced by soil mineralogical and chemical properties, i.e., Fe/Al oxyhydroxide, pH, organic matter, and fertilizer application.     

Hydrogeochemical processes and quality assessment of groundwater in Dumka and Jamtara districts, Jharkhand, India

The hydrogeochemical study of groundwater in Dumka and Jamtara districts has been carried out to assess the major ion chemistry, hydrogeochemical processes and groundwater quality for domestic and irrigation uses. Thirty groundwater samples were collected and analyzed for pH, electrical conductivity, total dissolved solids (TDS), total hardness, anions (F^?, Cl^?, NO₃ ^?, HCO₃ ^?, SO₄ ^2?) and cations (Ca²⁺, Mg²⁺, Na⁺, K⁺). The analytical results show the faintly alkaline nature of water and dominance of Mg²⁺ and Ca²⁺ in cationic and HCO₃ ^? and Cl^? in anionic abundance. The concentrations of alkaline earth metals (Ca²⁺?+?Mg²⁺) exceed the alkali metals (Na⁺?+?K⁺) and HCO₃ ^? dominates over SO₄ ^2??+?Cl^? concentrations in the majority of the groundwater samples. Ca?CMg?CHCO₃ is the dominant hydrogeochemical facies in 60?% of the groundwater samples, while 33?% samples occur as a mixed chemical character of Ca?CMg?CCl hydrogeochemical facies. The water chemistry is largely controlled by rock weathering and ion exchange processes with secondary contribution from anthropogenic sources. The inter-elemental correlations and factor and cluster analysis of hydro-geochemical database suggest combined influence of carbonate and silicate weathering on solute acquisition processes. For quality assessment, analyzed parameter values were compared with Indian and WHO water quality standards. In majority of the samples, the analyzed parameters are well within the desirable limits and water is potable for drinking purposes. Total hardness and concentrations of TDS, Cl^?, NO₃ ^? _, Ca²⁺ and Mg²⁺ exceed the desirable limits at a few sites, however, except NO₃ ^? all these values were below the highest permissible limits. The calculated parameters such as sodium adsorption ratio, percent sodium (%Na) and residual sodium carbonate revealed excellent to good quality of groundwater for agricultural purposes, except at few sites where salinity and magnesium hazard (MH) values exceeds the prescribed limits and demands special management.     

Ocean model derived global surface circulation and Vertical velocity

In this article, the authors examine Sea surface temperature (SST), Sea surface circulation (SSC) and Vertical velocity (VV) fields from simulation of 25 layers coarse resolution Modular ocean model (MOM version 3.0) with prescribed wind forcing for the region 74.25°S to 65°N, 180°W-180°E. It is found that distribution of SST simulated by the model shows its consistency with the observed climatology. However, simulated SST in the areas of Arabian Sea, Bay of Bengal, Indonesian Throughflow (ITF) region and east of North America near equator exhibit slight warming with respect to observation, which may be due to model deficiency and forcing problems. Circulation features suggest that one of the strongest current viz. Antarctic circumpolar current (ACC) along with other major current systems viz. Gulf stream current, North and South Pacific current, Agulhas current, Labrador current, Canary current, etc are captured well by the model. In the Indian Ocean and other ocean basins, current patterns are well captured by the model simulation. Intense upwelling as well as downwelling areas is marked in the horizontal distribution of VV, which is as expected. VV show quasi-stagnant and convergent regions suggesting that floating materials may be accumulated during January/July in the real ocean and wind driven circulation may act as an important contribution for such transport of floating materials in these regions. An attempt has also been made to understand the fluctuations of the SST in NINO 3.4 region during the period of model simulation using SST anomalies.     

The effect that coarse particles have on estimates of both optical and radiation characteristics of dust aerosol

Based on mathematical simulation, quantitative estimates of the effect that coarse dust particles have on the accuracy of retrieving the optical characteristics of aerosol have been obtained from the results of ground-based measurements of the spectral fluxes of both direct and scattered solar radiations. The results of verifying a retrieval algorithm (used at the AERONET ground-based network) based on special test models showed that the aerosol characteristics retrieved with this algorithm are unsuitable for calculating integral solar fluxes and for simulating space spectrometric IR measurements when the concentration of dust particles in the atmosphere exceeds their concentration in the well-known CONT model of continental aerosol by a factor of two or more.     

X-ray absorption contrast images of binary chemical reactions

Low-divergence synchrotron-sourced X-rays enable a radiographic imaging scheme for full characterization of binary chemical reactions and characterization by type of more complex reactions, in situ, in diamond anvil cells (DAC). Spatially resolved reactants are induced to react by laser heating of their interface. The spatially intermediate products are observed through X-ray absorption contrast. Limits to the technique include the ability to maintain controlled experiment geometry during compression and the ability to resolve chemical differences between reactants and products by X-ray absorption. The ability to make in situ observations at experimental pressure and temperature obviates the problem with quenching techniques for capturing liquid compositions in experiments with dimensions smaller than the diffusion length during quenching time. Partially molten Fe-alloy systems, of poor quenchability, are examined at DAC pressures and temperatures for relevance to Earth's core constitution and evolution. Determinations of eutectic melting in Fe–FeS match known results. Of the probable light elements that may alloy with Fe in the Earth's liquid outer core, Fe–FeS experiments show only modest quenching problems, but C and Si alloy experiments are highly vulnerable to quenching artifacts. The observed reactivity of FeS, Fe₃C, FeSi, and FeO(OH) with Fe in DAC makes the observed non-reactivity between Fe and FeO more significant, reducing the probability that oxygen alone is the major alloy in Earth's molten outer core.     

Geoarchaeological evidence on a Late Bronze Age earthquake,Ohrid Basin (North Macedonia)

Geoarchaeological investigations on the northeastern shore of Lake Ohrid revealed 3.5 m thick deepwater lacustrine sediments overlying terrestrial vegetation macrofossils, worked wood and abundant potsherds dated to the Late Bronze Age (LBA). Distinct contact of deepwater sediment with the sub-aerial weathered limestone bedrock point to a sudden increase in lake level. According to radiocarbon data, catastrophic flooding occurred shortly after 1214 yr bc. Because the area is located in a highly active seismic zone, we propose that this event was caused by tectonically induced, metre-scale coseismic subsidence related to faults bordering the Ohrid alluvial plain. Moreover, this event coincides well with a dramatic switch in the habitation and settlement strategy in the region. More important, however, is the finding that the age of the proposed massive tectonic event and change in habitation lies within the interval of the proposed ‘earthquake storm’ in the eastern Mediterranean dated to 1225–1175 bc. As the Ohrid-Korça zone belongs to the same tectonic province, a relationship between the abovementioned earthquakes and the proposed event can be expected. This research therefore might provide the first direct evidence of a large-scale earthquake event linkable to the LBA collapse of Europe's first urban civilisation in the Aegean.