Extraction and recovery of precious metals from electronic waste printed circuit boards by bioleaching acidophilic fungi

Printed circuit boards contain precious metals. They are produced in large volumes, rendering them an important component of the electronic waste. In view of the heterogeneity of the metals present, reprocessing of electronic waste is a heinous task. The present study focused on leaching of valuable metals from electronic waste printed circuit boards using Aspergillus niger DDNS1. The adaptation phases began at 0.1, 0.5 and 1.0% of fine powder of printed circuit boards with 10% inoculum and were optimized with three effective factors, viz. initial pH, particle size and pulp density, to achieve the maximum simultaneous recovery of the valuable metals. The interactions of these metals were also deciphered using scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction, Fourier transform infrared spectrum and atomic absorption spectroscopy. The results indicated that extraction of the precious metals was accomplished mainly through the unique organic acids originating from A. niger DDNS1. The initial pH played an important role in the extraction of the precious metals and the metals precipitate formation. The leaching rate of the metals was generally higher at low powder dosage of printed circuit boards. The toxicity of the printed circuit boards had little effect on two-step bioleaching at the pulp density of 0.1% compared to one-step bioleaching. The two-step bioleaching process was followed under organic acid-forming conditions for the maximum mobilization of metals. Thus, the precious metals from printed circuit boards could be mobilized through fungal bioleaching which promises an important industrial application in recycling of electronic wastes.     

Rare earth elements in the clay fraction of coaliferous sediments of the Arkagalinskoe (Magadan district) and Dolinskoe (Sakhalin Island) coalfields

The study of REE distribution in the clay fraction of sedimentary rocks from two coalfields made it possible to distinguish several types of REE distribution, which correlate with their mineral composition. It is shown that the REE fractionation was related to the mineral reconstruction of the primary clay fraction and some detrital minerals in the course of postsedimentary transformations of rocks during diagenesis, early catagenesis, and beginning of late catagenesis. These transformations were governed by several factors, such as the composition of sediments; hydrochemical features of accumulation environment; the chemical composition, dynamics, and feeding sources of pore solutions; the porosity and permeability of sediments and rocks; and the content of organic matter and its reaction ability.     

Snow measurement techniques for land-surface-atmosphere exchange studies in boreal landscapes

Summary  Snow has been studied widely in hydrology for many decades whereas recent meteorological interest in snow is caused by increased emphasis on high latitudes and wintertime in climate-change research as well as by the need to improve weather-forecast models during these conditions. Ground-based measurements of snow properties are needed both to improve understanding of surface-atmosphere exchange processes and to provide ground truth to new remote-sensing algorithms. This justifies a review of techniques to measure snow in combination with establishment of criteria for the suitability of the methods for process studies. This review assesses the state-of-art in ground-based snow-measurement techniques in the end of the 1990s in view of their accuracy, time resolution, possibility to automate, practicality and suitability in different terrain. Methods for snow-pack water equivalent, depth, density, growth, quality, liquid-water content and water leaving the snow pack are reviewed. Synoptic snow measurements in Fennoscandian countries are widely varying and there is no single standard on which process-related studies can build. A long-term, continuous monitoring of mass and energy properties of a snow cover requires a combination of point-measurement techniques. Areally representative values of snow properties can be achieved through a combination of automatically collected point data with repeated manual, areally covering measurements, remote-sensing data and digital elevation models, preferably in a GIS framework. Received August 27, 1999     

Diurnal variation of deep cloud systems over the Indian region using INSAT-1B pixel data

Summary Among the various time scales of deep clouds, diurnal variation is found to be prominent over the tropics. The present study examines the diurnal variation in the number and area cover associated with the cloud systems over the tropical Indian region using INSAT-1B pixel data. Three periods, namely, April–May 1988, July–August 1988, and January–February 1989 are considered. The dependence of diurnal characteristics on the temperature threshold, life duration and size of cloud systems, and land-sea contrast has been explored. The diurnal characteristics of cloud systems living for more than a day have been studied for the first time. It is shown that cloud systems exhibit strong diurnal dependence at the coldest temperature threshold used (201 K). Also, the diurnal variation is more for larger cloud systems and for longer living systems. In general, more deep cloud activity is found from the satellite data during the pre-dawn and early morning hours. Precipitation is enhanced during morning to early noon hours. Further, using data from a recent field experiment, clear evidence of diurnal variation in precipitation over the Bay of Bengal is also presented. Received March 20, 2000/Revised October 3, 2000     

Réflexions sur la contingence des lois de la Nature

There are two fundamental conceptions concerning the laws of nature — these laws are eternal or they may vary in the course of time. We suggest an experiment in order to find an intermediary thesis — i.e. to discover that law, if it really exists, according to which a given law of nature varies, or, at least, to find out the direction in which this variation is performed.     

A Spectrophotometric Study of the Be Star HD 164447

Spectra of the Be star HD 164447 have been studied. The equivalent widths and the intensities of the measured lines are given. No emission is apparent on the plates. Applying the thin layer theory some parameters of the stars atmosphere were derived.     

Formation Mechanism of Mud Bank Along the Southwest Coast of India

Mud bank formation during the southwest monsoon along the southwest coast of India remains an enigma to the researchers and coastal community in spite of several earlier studies. The present study attempts to unravel the mystery through a high-frequency, season-long time-series observation at Alappuzha, located at the southern part of the west coast of India, a region of frequent occurrence of mud bank. Using 7-month-long weekly time-series observation, we identified strong winds and high waves associated with onset of the southwest monsoon and subsequent three episodic atmospheric low-pressure events (LPEs).With the help of in situ time-series data, we show that the strong winds and high waves associated with southwest monsoon pre-conditions the near shore bottom sediment to bring it into suspension. The high amplitude waves associated with the southwest monsoon, while propagating from the deep water to shallow water region, interact with the bottom initiating bottom-sediment movement and its suspension due to wave refraction and shoaling. The sporadic occurrence of the atmospheric LPEs enhances the process of suspension of bottom sediment in the near shore region leading to the formation of fluid mud. Simulations with a cohesive sediment transport model yielded realistic estimates of sediment transport, in the presence of an onshore current, a pre-requisite for transporting the fluid mud toward the coast. The prevailing onshore upwelling current during the southwest monsoon provides the favorable pre-requisite conditions for transporting the fluid mud through depression channel network towards the coast. Once sufficient quantity and thickness of fluid mud is accumulated in the near shore region, it acts as a wave damper for subsequent high monsoon waves, as indicated by the time-series wave data, leading to the formation of tranquil mud bank region. Depression channel networks extending from the shelf to the coast off Alappuzha, Kochi, Ponnani, Beypore, and Ullal were found in the bathymetric charts, thus explaining why mud banks occur only at few locations in spite of the prevalence of similar monsoon conditions.     

Numerical simulation of undersea cable dynamics

A fully three-dimensional code has been written to compute the motion of a towed cable. The code is based on a robust and stable finite difference approximation to the differential equations derived from basic dynamics. A 3500-ft (1.07 km) cable pulled at 18.5 knots (34.3 km hr⁻¹) through a circular turn of 700 yd (0.64 km) radius has been computed in about half of the real time of the maneuver. The computed displacements are close to the measured ones; the changes in depth are within 2%.     

Analysis of mutations in the p53 tumor suppressor gene and Ki- and Ha-ras proto-oncogenes in hepatic tumors of European flounder (Platichthys flesus).

DNA from five tumors, three other-injured livers and two normal liver tissue samples from the European flounder were analyzed for mutations in exons 5-8 of the tumor suppressor gene p53 and at codons 12, 13 and 61 of Ha- and Ki-ras proto-oncogenes. No tumor-specific mutations were identified by direct sequencing and single-strand conformation polymorphism of these genes. A number of silent polymorphisms were noted in p53. In addition to a need for more extensive analyses of flounder liver tumor samples for ras or p53 mutations, other cancer-related genes should be investigated.