Travel times for snowmelt-dominated headwater catchments: Influences of wetlands and forest harvesting,and linkages to stream water quality

The time it takes water to travel through a catchment, from when it enters as rain and snow to when it leaves as streamflow, may influence stream water quality and catchment sensitivity to environmental change. Most studies that estimate travel times do so for only a few, often rain-dominated, catchments in a region and use relatively short data records (<10 years). A better understanding of how catchment travel times vary across a landscape may help diagnose inter-catchment differences in water quality and response to environmental change. We used comprehensive and long-term observations from the Turkey Lakes Watershed Study in central Ontario to estimate water travel times for 12 snowmelt-dominated headwater catchments, three of which were impacted by forest harvesting. Chloride, a commonly used water tracer, was measured in streams, rain, snowfall and as dry atmospheric deposition over a 31 year period. These data were used with a lumped convolution integral approach to estimate mean water travel times. We explored relationships between travel times and catchment characteristics such as catchment area, slope angle, flowpath length, runoff ratio and wetland coverage, as well as the impact of harvesting. Travel time estimates were then used to compare differences in stream water quality between catchments. Our results show that mean travel times can be variable for small geographic areas and are related to catchment characteristics, in particular flowpath length and wetland cover. In addition, forest harvesting appeared to decrease mean travel times. Estimated mean travel times had complex relationships with water quality patterns. Results suggest that biogeochemical processes, particularly those present in wetlands, may have a greater influence on water quality than catchment travel times.     

Vegetation in western Central Mexico during the last 50 000 years: modern analogs and climate in the Zacapu Basin

The late glacial and the transition towards the Holocene marked a period of significant environmental change at a global scale. In western Central Mexico, few records span beyond the Holocene, and little is known about Pleistocene climatic and environmental variability. Here we report on the pollen record of a composite sequence made of three cores that cover the last 50 ka (thousands of calibrated radiocarbon years before present) in the Zacapu Basin, western Central Mexico (～1970 m asl). The conjunction of modern pollen rain from the area with the composite fossil pollen sequence from cores Cantabria, Cantabria 1 and CEMCA Point‐1 provided a detailed history of the vegetation of the area. Recognition of modern environmental patterns through individual modern pollen taxa proved difficult, but multivariate analysis separated different vegetation types. No‐modern‐analog communities relative to the modern vegetation cover of the area were evident, especially during periods of drought. Apparently, summer precipitation was significant before 40 ka and after the deglaciation. However, this moisture source declined from ～40 to 10 ka because tradewinds from the Gulf of Mexico were blocked by the eastern mountains of Central Mexico as a result of lower temperatures. By contrast, westerly and northerly winds were enhanced by maximum ice cover from ～19 to 17 ka, providing abundant winter precipitation and therefore preventing extreme drought in the area. Copyright © 2012 John Wiley & Sons, Ltd.     

Spectral characteristics of Rossby waves in the Northwestern Pacific based on satellite altimetry

Using satellite altimetry measurement data for 1993–2013, we study the spectral characteristics of Rossby waves in the Northwestern Pacific (25°–50° N, 140°–180° E). For each latitude degree, we draw integral plots of spectral power density calculated with a two-dimensional Fourier transform (2D-FFT). We compare the dispersion equations of Rossby waves calculated from the WKB-approximation and an approximation of a two-layer ocean model with the empirical velocities determined by the slope of isopleths by the Radon method; also, we compare the dispersion equations with the spectral distributions of level variations. It is shown that the main energy of Rossby waves in the Northwestern Pacific corresponds to the first baroclinic mode. At almost all latitudes, there is good agreement between the empirical phase velocities calculated by isopleths by the Radon method and the theoretical values; also, the spectral peaks correspond to graphs of the dispersion equations for the first baroclinic mode Rossby waves, except for the Kuroshio region, where some peaks correspond to the second mode.     

Check dam positioning by prioritization of micro-watersheds using SYI model and morphometric analysis — Remote sensing and GIS perspective

Sediment Yield Index (SYI) model and results of morphometric analysis have been used to prioritize watersheds and to locate sites for checkdam positioning in Tarafeni watershed in Midnapur district. West Bengal. Various thematic maps such as land use/land cover, slope, drainage, soil etc. were prepared from 1RS ID LISS III digital data, SOI toposheets of 1:50,000 scale and other reference maps. Morphometric parameters such as bifurcation ratio (R_b). drainage density (D_d), texture ratio (T), length of overland flow (L_o), stream frequency (F_u), compactness coefficient (C_c), circularity ratio (R_c), elongation ratio (E_r), shape factor (B_s) and form factor (R_f) were computed. Automated demarcation of prioritization of micro-watersheds was done by using GIS overlaying technique by assigning weight factors to all the identified features in each thematic map and ranks were assigned to the morphometric parameters. Five categories of priority viz., very high, high, medium, low and very low, were given to all the watersheds in both the methods. Sixty-two micro-watersheds using SYI method and twenty-three micro-watersheds using morphometric have been prioritized as very high priority. Final priority map was prepared by considering the commonly occurred very high-prioritized micro-watersheds in both SYI model and morphometric analysis. Twenty-four suitable sites were identified for check dam construction in 21 highly prioritized watersheds. It is proved that integrated study of SYI model and morphometric analysis yield good result in prioritization of watersheds.     

Comparison of different models of water quality index in the assessment of surface water quality

The method of water quality index is widely used in evaluation of the surface water quality because of its capability to summarize a number of water quality parameters into one numeric value, along with defined scale of water quality range. The current investigation includes application of modified model for calculating water quality index values, generated using experimental data and literary models. Software was created using modular design. Fourteen physical, chemical and biological parameters representing water quality state along with the assigned weights were elected. Comparison between models generated based on Serbian and American models of water quality index was done. Selected parameters differ mutually in number of parameters used in calculation of index, as well as in values of the weighting factors. In order to enable an efficient water quality analysis and to reconcile the requirements of both Serbian and American model, two software solutions were generated and processed on the example of the water quality of the Danube River in Serbia. Danube water quality was assessed at seventeen measuring locations along the river flow. Index values obtained from the two generated software applications were compared with the results of the official Serbian online calculator. Water quality determined using new generated models shows stricter approach and one class lower water quality compared to the existing Serbian model. Therefore, modular and open-generated simulation software is of great significance for the comparison and testing of different water quality models, not just those two shown in this study.     

The geology and mineralisation at the Golden Pride gold deposit,Nzega Greenstone Belt,Tanzania

The Golden Pride gold deposit (∼3 Moz) is located in the central part of the Nzega Greenstone Belt at the southern margin of the Lake Victoria Goldfields in Tanzania. It represents an inferred Late Archaean, orogenic gold deposit and is hosted in intensely deformed meta-sedimentary rocks in the hanging wall of the approximately E–W striking Golden Pride Shear Zone. The hanging-wall sequence also includes felsic (quartz porphyritic) to mafic (lamprophyric) intrusions, as well as banded iron formations. Hydrothermal alteration phases associated with mineralisation are dominated by sericite and chlorite. Two main ore types can be distinguished, chlorite and silica ore, both occupying dilational sites and structural intersections in the hanging wall of the main shear zone. Sulphide minerals in both ore types include pyrrhotite, arsenopyrite, pyrite and accessory sphalerite, galena, sulphosalts and Ni–Co–Bi sulphides. Gold and tellurides are late in the paragenetic sequence and associated with a secondary phase of pyrrhotite deposition. Sulphur isotope compositions range from −6 to 7 per mil and are interpreted to reflect contributions from two distinct sources to the mineralising fluids in the Golden Pride gold deposit. A redox change, potentially induced by the intrusion of mafic melts, together with structural elements in the hanging wall of the Golden Pride Shear Zone, are interpreted to be the main controls on gold mineralisation in this deposit.     

Cloud drop spectra at different levels and with respect to cloud thickness and rain

Measurements on drop size were made in cumulus clouds over Pune (inland region) during the summer monsoon seasons. In this paper, the measurements of the cloud drop spectra made in non-raining clouds at different levels and for different thickness have been studied. Also, those on the days with rain and with no rain (the rain being observed within the clouds) have been compared. The average spectra broadened with height. The concentration of drops >50 μm (N_L), liquid water content (LWC), mean volume diameter (MVD) and dispersion increased with height. The concentration of drops <20 μm (N_S) and total concentration (N_T) decreased with height. The spectra were broader, while N_S and N_T are smaller and the other parameters are greater for thicker clouds as compared to those for thinner. The spectra were broader, while N_S and N_T are smaller and the other parameters are greater on the days with rain with respect to those on the days with no rain. The distributions were bimodal at higher levels, for thicker clouds and on the days with rain, while they were unimodal at lower levels, for thinner clouds and on the days with no rain. The variations of the cloud drop spectra, preceding rain, at initial stage of rain and following rain are discussed.     

Axtell,a new CV3 chondrite find from Texas

Abstract— We describe a previously unreported meteorite found in Axtell, Texas, in 1943. Based on the mineralogical composition and texture of its matrix and the sizes and abundance of chondrules, we classify it as a CV3 carbonaceous chondrite. The dominant opaque phase in the chondrules is magnetite, and that in refractory inclusions is Ni-rich NiFe metal (awaruite). Axtell, therefore, belongs to the oxidized subgroup of CV3 chondrites, although unlike Allende it escaped strong sulfidation. The meteorite bears a strong textural resemblance to Allende, and its chondrule population and matrix appear to be quite similar to those of Allende, but its refractory inclusions, thermoluminescence properties, and cosmogenic ⁶⁰Co abundances are not. Our data are consistent with a terrestrial age for Axtell of ～100 years and a metamorphic grade slightly lower than that of Allende.     

Quantitative Analysis of Micro-structural Changes in a Bituminous Coal After Exposure to Supercritical CO2 and Water

Natural Resources Research - High-volatile bituminous coal samples were reacted in deionized water with supercritical CO2 (ScCO2–water) under simulated in situ pressure and temperature...     

Nature of sudden auroral activations at the beginning of magnetic storms

Certain large magnetic lays, registered by magnetometers in the auroral and subauroral zones simultaneously with SC instant and accompanying events, substantially differ from activations at the beginning of auroral substorm. Such basic substorm elements as energy accumulation during the growth phase and breakup—activation in the localized region near midnight—are absent. During such sudden auroral activations (SAs), a disturbance begins in a wide sector of longitudes and latitudes. It is proposed to combine SAs into an individual class of magnetospheric disturbances. The particle acceleration and injection mechanism, which causes SAs, is considered.