Constraints on spatial variability in soft-sediment communities affected by contamination from an Antarctic waste disposal site

A small-scale (<500 m length) transect-based survey was conducted in December 1998 to examine the spatial distribution of soft-sediment communities and of concentrations of heavy metals and hydrocarbons in sediments in Brown Bay, adjacent to an abandoned waste dump, at Casey Station, Antarctica. Samples were taken along three transects at increasing distances (nine stations) from the shore-line waste dump. A gradient of contamination was detected, but concentrations of contaminants were very variable with "hotspots" or high levels of contaminants at some stations. Multivariate analysis revealed that the distribution of soft-sediment communities was distinctly different between the inner, middle and outer stations. Abundances of most taxa were very variable with few patterns apparent, but some fauna displayed an abundance gradient from the inner to the outer part of the bay. Many taxa had maximum abundances at outer stations and minimum at inner stations. Multivariate correlations between environmental variables and soft-sediment communities indicated that combinations of some metals (Cd, Cu, Sn, Pb) and grain size (mainly finer fractions, fine sands and coarse silts) were the variables that best "matched" the community patterns within Brown Bay. This study indicated that there were significant correlations between the presence of contaminants and the distribution and composition of soft-sediment communities over very small spatial scales.     

NPZ Models of Plankton Dynamics: Their Construction, Coupling to Physics, and Application

Nutrient-phytoplankton-zooplankton (NPZ) models have been in use in oceanography for at least three decades, and are still a common research tool. Given the discoveries of the last two decades, particularly concerning the role of bacteria in the plankton, there are questions as to whether NPZ models can still be supported as a useful tool in planktonic research. Here I review the construction of NPZ models, and some of the physical platforms they have been coupled to. I then discuss the applications of NPZ-physical models, and conclude that they still constitute an important and viable research tool, provided that the questions being explored are clearly stated. This revised version was published online in August 2006 with corrections to the Cover Date.     

Geology of the volcanic-hosted Brockman rare-metals deposit,Halls Creek Mobile Zone,northwest Australia. l. Volcanic environment,geochronology and petrography of the Brockman volcanics

Summary Rare-metals mineralization of the Brockman deposit (Halls Creek Mobile Zone, NW Australia) is hosted in a fluorite-bearing, rhyolitic volcaniclastic unit informally termed the Niobium Tuff. The Tuff, more correctly described as a tuffaceous volcaniclastic deposit, is the lowermost unit of a sequence of trachyte-to-rhyolite lavas, trachyandesite subvolcanic rocks, and volcaniclastic units of the Brockman volcanics located within the Halls Creek Group, a thick, early Proterozoic volcano-sedimentary sequence. High precision SHRIMP ion-microprobe zircon dating of the Niobium Tuff gives an eruption age of 1870 ± 4 Ma. Regional geochronological constraints indicate the Niobium Tuff was deposited about 15 Ma before major orogenic activity affected the area. Despite folding, faulting and low-grade metamorphism, the Brockman volcanics show excellent preservation of primary volcanological features, including pillow-lavas and pillow-breccias, that suggest a dominantly subaqueous, below-wave-base emplacement environment. The style of eruption products and magma volume constraints suggest the trachyte-dominated volcanics were erupted from a small shield volcanic complex probably in a rift-related basin in a shallow-marine setting. The tectonic setting was intraplate but differs from most Tertiary to recent trachyte volcanic complexes which are largely subaerial, are built on relatively thick continental crust, and show no post-eruptive orogenic history. Brockman-style rare-metal deposits are characterized by preservation of subaqueous volcanics beneath a thick sedimentary sequence, eruption of early incompatible-element enriched products followed by less differentiated magmas, and fine-grained mineralogy influenced by alteration processes. Prospects exist for discovery of analogous deposits, particularly in early Proterozoic mobile belts and Tertiary intraplate shield volcanic provinces.

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Geologie der an Vulkanite gebundenen Seltene-Metalle-Lagerstätte Brockman, Halls Creek Mobile Zone, Nordwest-Australien. I. Vulkanologie, Geochronologie und Petrographie der Brockman-Vulkanite

Zusammenfassung Selten-Metall-Vererzung der Brockman-Lagerstätten (Halls Creek Mobile Zone, NW Australien) sitzt in einer Fluorit-führenden, rhyolitischen vulkanoklastischen Einheit auf, die informell als der Niob-Tuff bezeichnet wird. Es handelt sich hier um ein vulkanoklastisches Tuff-Sediment; dieses ist die unterste Einheit einer Abfolge vor Trachyt bis Rhyolit-Laven, trachyandesitischen Subvulkaniten and vulkanoklastischen Einheiten der Brockman Vulkanite innerhalb der Halls Creek Gruppe, einer mächtigen frühproterozoischen vulkanosedimentdren Abfolge. Prüzisionsdatierungen des Niob Tuffs mit der SHRIMP Ionen-Mikrosonde ergeben ein Eruptionsalter von 1870 +-4 Millionen Jahren. Regionale geochronologische Zusammenhänge zeigen, daß der Niob Tuff etwa 15 Millionen Jahre vor einer größeren Orogenese, die das Gebiet betroffen hat, abgelagert wurde. Trotz Faltung, Bruchtektonik and niedriggradiger Metamorphose zeigen die Brockman-Vulkanite einen hervorragenden Erhaltungszustand primärer vulkanologischer Erscheinungen. Diese urnfassen auch Kissenlaven und KissenBreckzien, die eine vorwiegend subaquatische Ablagerung in ruhigem Wasser erkennen lassen. Die Art der Eruptionsprodukte and das Magmavolumen zeigen, daß die Trachytdominierten Vulkanite von einem kleinen Schildvulkan stammer, wahrscheinlich in einem Becken in einer Rift-Situation im seichten marinen Milieu. Die tektonische Situation war intraplate, aber unterscheidet sich von den meisten tertiären bis rezenten trachytischen Vulkan-Komplexen, die hauptsächlich subaerisch sind, auf einer relativ mächtigen kontinentalen Kruste aufsitzen, and keine post-eruptive orogene Entwicklung zeigen. Seltene-Metalle-Lagerstatten des Brockman-Typs rind durch die Erhaltung subaquatischer-Vulkanite unterhalb einer machtigen sedimentdren Abfolge gekennzeichnet; welters durch frühe Eruptionsprodukte, die an inkompatiblen Elementen angereichert sind, auf die dann weniger differenzierte Magmen folgten, und schließlich durch einen feinkörnigen Mineralbestand, der vor Umwandlungsprozessen betroffen war. Es besteht die Möglichkeit der Entdeckung analoger Lagerstätten, besonders in frühproterozoischen mobilen Gürteln und in tertidren intraplate Schildvulkan Provinzen.

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Mesoproterozoic Fraser Complex: Geochemical evidence for multiple subduction‐related sources of lower crustal rocks in the Albany‐Fraser Orogen,Western Australia

The 1300 Ma Fraser Complex in the Albany‐Fraser Orogen of Western Australia is a thrust stack of mainly gabbroic rocks metamorphosed to granulite facies. This package of fault‐bounded units was elevated from a deep crustal level onto the margin of the Yilgarn Craton during continental collision between the Mawson and Yilgarn Cratons. Incompatible trace‐element distributions demand at least three mantle sources. Primitive‐mantle‐normalised incompatible‐element distributions show strong negative Ta–Nb anomalies, typical of subduction‐derived magmas. Three lines of evidence indicate that the mafic magmas did not acquire these anomalies by assimilation of crustal rocks: (i) major‐element compositions do not allow appreciable contamination with felsic material; (ii) Ni contents of many mafic rocks are too high for a significant contribution from a felsic assimilant; and (iii) Sr and Nd isotopic data support a largely juvenile source for the magmas that produced the Fraser Complex. Hence, the Ta–Nb anomalies are interpreted to reflect subduction‐related magmatic sources. On multielement diagrams, depletions in Sr, Eu, P, and Ti can be explained by fractional crystallisation, whereas Th and Rb depletions in many of the Fraser Complex rocks probably reflect losses during granulite‐facies metamorphism. These results suggest that the lower crust in this region at 1300 Ma was dominantly of arc origin, and there is no evidence to support mantle plume components. The Fraser Complex is interpreted as remnants of oceanic arcs that were swept together and tectonically interleaved with the margin of the Mawson Craton just before, or during, collision with the Yilgarn Craton at 1300 Ma.     

Ecohydrographic constraints on biodiversity and distribution of phytoplankton and zooplankton in coral reefs of the Red Sea,Saudi Arabia

An integral concept of ecological research is the constraint of biodiversity along latitudinal and environmental gradients. The Red Sea features a natural example of a latitudinal gradient of salinity, temperature and nutrient richness. Coral reefs along the Red Sea coasts are supported with allochthonous resources such as oceanic and neritic phytoplankton and zooplankton; however, relatively little is known about how the ecohydrography correlates with plankton biodiversity and abundance. In this article we present the biodiversity of phytoplankton and zooplankton in Red Sea coral reefs. Oceanographic data (temperature, salinity), water samples for nutrient analysis, particulate organic matter, phytoplankton and zooplankton, the latter with special reference to Copepoda (Crustacea), were collected at nine coral reefs over ~1500 km distance along the Red Sea coast of Saudi Arabia. The trophic state of ambient waters [as indicated by chlorophyll a (Chl a)] changed from strong oligotrophy in the north to mesotrophy in the south and was associated with increasing biomasses of Bacillariophyceae, picoeukaryotes and Synechococcus as indicated by pigment fingerprinting (CHEMTAX) and flow cytometry. Net‐phytoplankton microscopy revealed a Trichodesmium erythraeum (Cyanobacteria) bloom north of the Farasan Islands. Several potentially harmful algae, including Dinophysis miles and Gonyaulax spinifera (Dinophyceae), were encountered in larger numbers in the vicinity of the aquaculture facilities at Al Lith. Changes in zooplankton abundance were mainly correlated to the phytoplankton biomass following the latitudinal gradient. The largest zooplankton abundance was observed at the Farasan Archipelago, despite high abundances of copepodites, veligers (Gastropoda larvae) and Chaetognatha at Al Lith. Although the community composition changed over latitude, biodiversity indices of phytoplankton and zooplankton did not exhibit a systematic pattern. As this study constitutes the first current account of the plankton biodiversity in Red Sea coral reefs at a large spatial scale, the results will be informative for ecosystem‐based management along the coastline of Saudi Arabia.     

From the geological to the numerical model in the analysis of gravity-induced slope deformations: An example from the Central Apennines (Italy)

This paper presents the findings from a study on gravity-induced slope deformations along the northern slope of Mt. Nuria (Rieti-Italy). The slope extends from the village of Pendenza to the San Vittorino plain and hosts the Peschiera River springs, i.e. the most important springs of the Central Apennines (average discharge: about 18 m³/s).

Detailed geological-geomorphological and geomechanical surveys, supported by a site stress-strain monitoring system and laboratory tests, led us to define the main evolutionary features of the studied phenomena. Based on the collected data, a “geological-evolutionary model” was developed with a view to identifying a spatio-temporal correlation between relief forms, jointing of the rock mass and its stress conditions. The geological-evolutionary model was expected to improve numerical simulations and to test our assumptions.

The numerical model also allowed us to simulate changes in the stress-strain conditions of the rock mass and correlate them with jointing, seepage, as well as with site-detected and site-monitored forms and deformations. In particular, significant relations between seepage, tensile stresses within the rock mass, karst solution and collapse of cavities were identified.     

Conditioning mean steady state flow on hydraulic head and conductivity through geostatistical inversion

Nonlocal moment equations allow one to render deterministically optimum predictions of flow in randomly heterogeneous media and to assess predictive uncertainty conditional on measured values of medium properties. We present a geostatistical inverse algorithm for steady-state flow that makes it possible to further condition such predictions and assessments on measured values of hydraulic head (and/or flux). Our algorithm is based on recursive finite-element approximations of exact first and second conditional moment equations. Hydraulic conductivity is parameterized via universal kriging based on unknown values at pilot points and (optionally) measured values at other discrete locations. Optimum unbiased inverse estimates of natural log hydraulic conductivity, head and flux are obtained by minimizing a residual criterion using the Levenberg-Marquardt algorithm. We illustrate the method for superimposed mean uniform and convergent flows in a bounded two-dimensional domain. Our examples illustrate how conductivity and head data act separately or jointly to reduce parameter estimation errors and model predictive uncertainty.This work is supported in part by NSF/ITR Grant EAR-0110289. The first author was additionally supported by scholarships from CONACYT and Instituto de Investigaciones Electricas of Mexico. Additional support was provided by the European Commission under Contract EVK1-CT-1999-00041 (W-SAHaRA-Stochastic Analysis of Well Head Protection and Risk Assessment).     

Deep ocean fluxes and their link to surface ocean processes and the biological pump

Intense studies of upper and deep ocean processes were carried out in the Northwestern Indian Ocean (Arabian Sea) within the framework of JGOFS and related projects in order to improve our understanding of the marine carbon cycle and the ocean’s role as a reservoir for atmospheric CO₂. The results show a pronounced monsoon-driven seasonality with enhanced organic carbon fluxes into the deep-sea during the SW Monsoon and during the early and late NE Monsoon north of 10°N. The productivity is mainly regulated by inputs of nutrients from subsurface waters into the euphotic zone via upwelling and mixed layer-deepening. Deep mixing introduces light limitation by carrying photoautotrophic organisms below the euphotic zone during the peak of the NE Monsoon. Nevertheless, deep mixing and strong upwelling during the SW Monsoon provide an ecological advantage for diatoms over other photoautotrophic organisms by increasing the silica concentrations in the euphotic zone. When silica concentrations fall below 2 μmol l⁻¹, diatoms lose their dominance in the plankton community. During diatom-dominated blooms, the biological pathway of uptake of CO₂ (the biological pump) appears to be more efficient than during blooms of other organisms, as indicated by organic carbon to carbonate carbon (rain) ratios. Due to the seasonal alternation of diatom and non-diatom dominated exports, spatial variations of the annual mean rain ratios are hardly discernible along the main JGOFS transect.Data-based estimates of the annual mean impact of the biological pump on the fCO₂ in the surface water suggest that the biological pump reduces the increase of fCO₂ in the surface water caused by intrusion of CO₂-enriched subsurface water by 50–70%. The remaining 30 to 50% are attributed to CO₂ emissions into the atmosphere. Rain ratios up to 60% higher in river-influenced areas off Pakistan and in the Bay of Bengal than in the open Arabian Sea imply that riverine silica inputs can further enhance the impact of the biological pump on the fCO₂ in the surface water by supporting diatom blooms. Consequently, it is assumed that reduced river discharges caused by the damming of major rivers increase CO₂ emission by lowering silica inputs to the Arabian Sea; this mechanism probably operates in other regions of the world ocean also.     

Sample treatment with focused ultrasound and bath sonication as a powerful tool for the evaluation of cadmium pollution in estuarine waters

A new sample treatment was developed for the determination of dissolved cadmium in Tagus estuarine waters, based on focused ultrasound in conjunction with small volumes in the extraction steps for Cd pre-concentration. Cadmium was first pre-concentrated using a classical approach (APDC as the complexing agent and MIBK as the organic phase) and then back-extracted into HNO₃ with the aid of focused ultrasound, which reduced the acid concentration by more than one order of magnitude (from 4 to 0.1 mol L^− 3). This sample treatment was accomplished in less than 5 min, using low sample volume (20 mL), and low-volume, low-concentration reagents. The pre-concentration factor used in this work was 25, but different sample/organic volume ratios may be used in order to increase that value. The limit of detection and the limit of quantification in Tagus water samples were 0.03 nmol L^− 1 and 0.1 nmol L^− 3, respectively. Recoveries from spiked Tagus water were higher than 90%. The procedure was validated using the reference estuarine water NRC-SLEW-3. In the solubilization of Cd particulate, bath ultrasonication was used in conjunction with HNO₃ + HCl, followed by H₂O₂, which took about 2 instead of the usual 12 h (cooling included) when high-pressure microwave digestion is used.     

Theoretical wind wave frequency spectra in deep water——Ⅰ. Form of spectrum

In this part ot the paper theoretical wind-wave spectra nave been derived oy (I) expressing the spectrum in series composed of exponential terms; (2) assuming that the spectrum satisfies a high order linear ordinary differential equation; (3) introducing proper parameters in the spectrum; and (4) making use of some known charateristics of wind-wave spectrum, for instance, the law governing the equilibrium range. The spectrum obtained contains the zero order moment of the spectrum m0, the peak frequency ω0 and the ratio R =ω/ω0 (ω being the mean zero-crossing frequency) as parameters. The shape of the nondimensional spectrum S(ω) = ω0S(ω)/m0(ω=ω/ω0) changes with R and theoretically reduces to a Dirac delta function δ(ω-1) when R = 1. A spectrum of simplified form is given for practical uses, in which R is replaced by a peakness factor P=S(1).