Reservoirs of atmospheric chlorine: Prospects for HOCl revisted

We have re-examined the prospects of HOCl as an inert reservoir for atmospheric chlorine in the light of new theoretical calculations and available experimental measurements of its photodissociation cross-sections. The theoretical calculations and most recent laboratory studies imply that the broad maxima 3200 Å observed in two other experimental spectra may not belong to HOCl. On the basis of this implication HOCl could have a long lifetime against photodissociation in the stratosphere, and could, thereby, become a reservoir for atmospheric chlorine comparable to ClONO₂ or even HCl. In this capacity HOCl could reduce the predicted ozone destruction due to any given level of total chlorine burden. We have also examined the difficulties in laboratory measurements of the HOCl absorption spectrum with particular emphasis on identifying the impurities which may be present in the experimental system. It appears that specialized new experiments are needed to clearly establish the nature and strength of HOCl absorption in the neighbourhood of 3200 Å. Some refinements in the theoretical calculations also seem desirable. In view of the difficulties involved in the laboratory determination of HOCl photodissociation cross-sections, it is suggested that a search for possible stratospheric HOCl by atmospheric spectroscopists would be worthwhile.     

Adiabatic plasma convection in a dipole field: Variation of plasma bulk parameters with L

We here investigate the motion of particles in a dipole magnetic field under the assumption of conservation of the first two adiabatic invariants. The results are then combined with Liouville's theorem to obtain the variation of the distribution function, and hence the plasma bulk parameters with L-shell. A comparison of the numerical results with recently published analytical approximations is made. Finally, the results are used to describe the structure of the ring current plasma in the outer radiatoin zone, the effects of the Alfvén layers being quantitatively evaluated for a simple electric field model.     

The T Tauri star RU Lupi and its circumstellar surrounding

From simultaneous spectroscopic and photometric observations of the T Tauri star RU Lup, which was followed for nine consecutive nights, it was found that most if not all of the light variations observed on this star were caused by variable circumstellar extinction. The character and the time-scale of the variations imply that the variations are due to dust concentrations of stellar dimension crossing the line of sight to the star. The implications of this interpretation and its possible bearing on problems of protoplanetary systems are discussed.     

Observations of Venus water vapor over the disk of Venus: The 1972–1974 data using the H2O lines at 8197 Å and 8176 Å

The Venus water vapor line at 8197.71 Å has been monitored at several positions on the disk of Venus and at phase angles between 21° and 162°. Variations in the abundance have been found with spatial location, phase angle and time. During the 1972–1974 period, the total two-way absorption has varied from less than 1 to 77 μm of water vapor. The dependence on phase angle indicates 20 to 50 μm over the disk between 30° and 110° and small, but detectable amounts present during the rest of the observations. The spatial distribution with respect to the intensity equator is uniform with no location on the disk having systematically a higher or lower abundance. Comparisons made between the water vapor abundandances and the CO₂ abundances determined from near-simultaneous observations of CO₂ bands at the same positions on the disk of Venus show no correlation for the majority of the samples.     

The atmosphere of Io from Pioneer 10 radio occultation measurements

The occultation of the Pioneer 10 spacecraft by Io (JI) provided an opportunity to obtain two S-band radio occultation measurements of its atmosphere. The dayside entry measurements revealed an ionosphere having a peak density of about 6 × 10⁴ elcm^?3 at an altitude of about 100 km. The topside scale height indicates a plasma temperature of about 406 K if it is composed of Na⁺ and 495 K if N₂⁺ is principal ion. A thinner and less dense ionosphere was observed on the exit (night side), having a peak density of 9 × 10³ elcm^?3 at an altitude of 50 km. The topside plasma temperature is 160 K for N₂^? and 131 K for Na⁺. If the ionosphere is produced by photoionization in a manner analogous to the ionospheres of the terrestrial planets, the density of neutral particles at the surface of Io is less than 10¹¹?10¹² cm³, corresponding to a surface pressure of less than 10^?8 to 10^?9 bars. Two measurements of its radius were also obtained yielding a value of 1830 km for the entry and 192 km for the exit. The discrepancy between these values may indicate an ephemeris uncertainty of about 45 km. The two measurements yield an average radius of 1875 km, which is not in agreement with the results of the Beta Scorpii stellar occultation.     

The absorption of soft X-rays from the Crab nebula

The X-ray spectrum of the Crab nebula has been determined in the energy range 0.5 10 keV using thin window proportional counters carried aboard a Centaur IIA rocket launched from TERLS, India. The spectrum can be well represented by a power law with an exponent?2.1 beyond 2 keV. The absorption of the soft X-ray component below 2 keV is clearly seen in the experiment. Attempts to understand quantitatively the spectral features in terms of interstellar absorption lead to a column density of hydrogen in the iirection of the Crab nebula of 3.5×10²¹ H atoms cm^?2, if we adopt a revised version of the interstellar absorption coefficients of Brown and Gould to include the contributions of heavier elements, especially of iron. This value of density is a factor of 2 higher than the density obtained from 21 cm radio observations, but falls well within the range of values for atomic and total hydrogen deducible from UV measurements with satellites and the measured visual extinction coefficients for the Crab nebula. It is concluded that it is not necessary to consider anomalous abundance of elements like carbon or neon either in the source or in the interstellar medium as suggested by some authors. The absorption of X-rays in the interstellar dust in the light of current dust models is presented.     

The quadratic Zeeman effect in the Caii H and K lines

The effects of a large magnetic field on the H and K lines of Caii are investigated incorporating both the linear and quadratic Zeeman effects for fields in the range 10⁶–10⁸ G. For these fields the linear term is the dominant one, resulting in a Paschen-Back effect with a smaller quadratic Zeeman shift superimposed on all components. Due to the partial cancellation of the quadratic effect between the upper and lower states of the lines, a much smaller quadratic Zeeman shift occurs than in the lines of other atoms previously studied at similar fields.