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971.
Groundwaters from crystalline and metamorphic rocks (hardrocks) and from Quaternary deposits, i.e., alluvial and glacial deposits (softrocks) from the counties of Nord-Trøndelag and Sør-Trøndelag were analyzed for major and minor elements and ions including fluoride. The median concentration of F– in water from the hardrock aquifers is 0.28 mg/l (14.7 eq/l) in contrast to water from softrock aquifers in which it is found to be 0.05 mg/1 (2.6 eq/l). More importantly, ca. 15% of the locations where water was abstracted from hardrock wells contain 1.5 mg/l (78.9 eq/l) F– or more. Thus, 15% of all hardrock wells returned F– results that are at or above the maximum recommended value for drinking water. Of the softrock wells, none are above 1 mg/l. Geologists would normally expect higher F–contents in groundwaters derived from acid rocks, e.g., in granitic or gneissic areas. When comparing the host lithology with the observed F–contents, however, no clear relationship between F– content and lithology is visible. The highest observed F– values actually occur in gneissic host rocks. However, wells drilled in amphibolites/greenstones, mica schists, calcareous rocks, and sedimentary rocks all returned some analytical results above 1.5 mg/l F–. These results suggest that all hardrock wells drilled should be tested for F– and the users informed about the results and advised to take any necessary precautions. When applying the recently proposed Norwegian drinking water limits to our data, 51% of all softrock well waters and 56% of all hardrock well waters are unfit for consumption without prior treatment, although we analyzed only for about half of the proposed elements/parameters. This result seriously questions the concept of fixed action levels—many of them with totally unproven health implications—for so many parameters/elements for hardrock groundwaters. 相似文献
972.
Abdallah I. Husein Malkawi Robert Y. Liang Jamal H. Nusairat Azm S. Al-Homoud 《Natural Hazards》1995,12(2):139-151
Earthquake hazard maps for Syria are presented in this paper. The Peak Ground Acceleration (PGA) and the Modified Mercalli Intensity (MMI) on bedrock, both with 90% probability of not being exceeded during a life time of 50, 100 and 200 years, respectively are developed. The probabilistic PGA and MMI values are evaluated assuming linear sources (faults) as potential sources of future earthquakes. A new attenuation relationship for this region is developed. Ten distinctive faults of potential earthquakes are identified in and around Syria. The pertinent parameters of each fault, such as theb-parameter in the Gutenberg-Richter formula, the annual rate
4 and the upper bound magnitudem
1 are determined from two sets of seismic data: the historical earthquakes and the instrumentally recorded earthquake data (AD 1900–1992). The seismic hazard maps developed are intended for preliminary analysis of new designs and seismic check of existing civil engineering structures. 相似文献
973.
Kick 'em Jenny is the only known currently active submarine volcano in the Lesser Antilles. The volcano has erupted at least 10 times since first being discovered in 1939 and the summit has shoaled from a depth of 232 m in 1962 to its present-day depth of 150 m. Kick 'em Jenny is located in a province of explosive volcanism, has a known history of explosive eruptions and erupts magma of an explosive type. Future eruptions are likely to become increasingly more violent as the effect of the overlying water pressure becomes less. A preliminary study (Smith and Shepherd, 1993) suggests that Kick 'em Jenny is a prime candidate for tsunamigenic eruptions on a potentially hazardous scale, possibly affecting the whole of the eastern Caribbean region.The classic approach to problems of water waves generated by sudden disturbances of the free surface makes use of the Cauchy-Poisson-Lamb theory. A large number of theoretical developments to this theory have been made for specific forms of surface disturbance. A development by Unoki and Nakano (1953a, b) considers both two- and three-dimensional Cauchy-Poisson waves generated by finite initial elevations and impulses applied to a free surface of infinitely deep water. Unoki and Nakano's results compared well to the wave systems recorded following submarine eruptions of the Myojinsho Reef volcano in 1952–53.Given the similarity of the two situations, Unoki and Nakano's theory is applied to Kick 'em Jenny to provide estimates of potential Cauchy-Poisson wave heights throughout the eastern Caribbean for a range of eruption magnitudes. The results show that, although the waves generated are unlikely to pose much of a threat to the eastern Caribbean as a whole, they should be considered a hazard to the islands immediately adjacent to the volcano including Grenada, the Grenadines, and St Vincent. 相似文献
974.
The Oso Bay, Texas, sediments from nine sites were analyzed by GC-MS for organics to measure contamination in the bay. In most of the sites sediments contained tetrachloroethene (87–1433 g/kg), bis (2-ethylhexyl)phthalate (40–193 g/kg), and aliphatic hydrocarbons, C8-C13 (720–2491 g/kg). Sources of these contaminants include a landfill, military facilities, and municipal and industrial discharges. Size analysis of the sediments indicates they contain a high percentage of muddy sand (50–75 percent), which suggests that Oso Bay consists of common bay margin sediments. 相似文献
975.
DASGUPTA SOMNATH; SENGUPTA PULAK; EHL JUERGEN; RAITH M.; BARDHAN S. 《Journal of Petrology》1995,36(2):435-461
Spinel granulites, with or without sapphirine, occur as lensesin garnetiferous quartzofeldspathic gneisses (leptynites) nearGokavaram in the Eastern Ghats Belt, India. Spinel granulitesare mineralogically heterogeneous and six mineral associationsoccur in closely spaced domains. These are (I) spinelquartzcordierite,(II) spinelquartzcordieritegarnetorthopyroxenesillimanite,(III) spinelcordieriteorthopyroxenesillimanite,(IV) spinelquartzsapphirinesillimanitegarnet,(V) spinelquartz-sapphirinegarnet and (IV) rhombohedral(FeTi) oxidecordieriteorthopyroxenesillimanite.Common to all the associations are a porphyroblastic garnet(containing an internal schistosify defined by biotite, sillimaniteand quartz), perthite and plagioclase. Spinel contains variableamounts of exsolved magnetite and is distinctly Zn rich in thesapphirine-absent associations. XMg in the coexisting phasesdecreases in the order cordieritebiotitesapphirineorthopyroxenespinelgarnet(FeTi)oxides. Textural criteria and compositional characteristicsof the phases document several retrograde mineral reactionswhich occurred subsequent to prograde dehydration melting reactionsinvolving biotite, sillimanite, quartz, plagioclase and spinel.The following retrograde mineral reactions are deduced: (1)spinel + quartz cordierite, (2) spinel + quartz garnet + sillimanite,(3) garnet + quartz cordierite + orthopyroxene, (4) garnet+ quartz + sillimanite cordierite, (5) spinel + cordierite orthopyroxene + sillimanite, (6) spinel + sillimanite + quartz sapphirine, (7) spinel + sapphirine + quartz garnet + sillimanite,and (8) spinel + quartz sapphirine + garnet. A partial petrogeneticgrid for the system FeOMgOAl2O3SiO2K2OH2Oat high fo2, has been constructed and the effects of ZnO andFe2O3 on this grid have been explored Combining available experimentaland natural occurrence data, the high fo2 invariant points inthe partial grid have been located in PT space. Geothermobarometricdata and consideration of the deduced mineral reactions in thepetrogenetic grid show that the spinel granulites evolved throughan anticlockwise PT trajectory reaching peak metamorphicconditions >9 kbar and 950C, followed by near-isobaric cooling(dT/dP = 150C/kbar). This was superimposed by an event of near-isothermaldecompression (dT/dP = 15C/kbar). The studied spinel granulites,therefore, preserve relic prograde mineral associations andreaction textures despite being metamorphosed at very high temperatures,and bear evidence of polymetamorphism. KEY WORDS: spinel granulite; Eastern Ghats; India; polymetamorphism; geothermometry; geobarometry
Corresponding author 相似文献
976.
The nature of the solubility of water as [4H]Si defects in quartz, and their role in providing a source of molecular water on heating, is investigated. Existing ab inito energy calculations on the incorporation of water in quartz are used to show that energetically 4H for Si substitution is likely to constitute the most prevalent mode of water uptake on the atomic scale in quartz under equilibrium conditions, and that the planar defects previously observed by a number of different authors by electron microscopy in wet quartz are likely to be planar rafts of aggregated [4H]Si defects which are formed on supersaturation. These new conclusions call into question the previous identification of the planar defects as high pressure water clusters and require that their role in the production of molecular water in the context of recent theories of hydrolytic weakening be re-assessed. Accordingly the existing ab initio results have been used to establish the characteristics of the phase diagram for the system quartz-water in the temperature and pressure range of interest in hydrolytic weakening. Additional electron-optical experiments on wet quartz show that, on annealing at temperature in the electron microscope, similar planar defects develop in wet quartz by a diffusion process. In the context of existing theories of hydrolytic weakening it is now proposed that the conversion of [4H]Si defects to molecular water, where this is dictated by the equilibrium phase diagram, leads to a relatively large increase in volume and to the appearance of the bubbles of free water and the nucleation of associated prismatic dislocation loops of Burgers vector b=1/3 a $\langle 11\bar 20\rangle $ as previously observed. Ultimately the development of these loops leads to dislocation-induced plasticity. 相似文献
977.
The concentrations of Ni, Cu, Zn, Ga, Ge, and Se in five, fine-grained chondrule rims in the highly unequilibrated CO3 chondrite ALH A77307 (3.0) have been determined for the first time by synchrotron X-ray fluorescence (SXRF) microprobe at Brookhaven National Laboratory. These elements are especially useful for tracing the role of condensation and evaporation processes which occurred at moderate temperatures in the solar nebula. Understanding the distribution of moderately volatile elements between matrix and chondrules is extremely important for evaluating the different models for the volatile depletions in chondritic meteorites. The data show that the trace element chemistry of rims on different chondrules is remarkably similar, consistent with data obtained for the major and minor elements by electron microprobe. These results support the idea that rims are not genetically related to individual chondrules, but all sampled the same reservoir of homogeneously mixed dust. Of the trace elements analyzed, Zn and Ga show depletions relative to CI chondrite values, but in comparison with bulk CO chondrites all the elements are enriched by approximately 1.5 to 3.5 x CO. The abundance patterns for moderately volatile elements in ALH A77307 chondrule rims closely mimic those observed in the bulk chondrite, indicating that matrix is the major reservoir for these elements. The close matching of the patterns for the volatile depleted bulk chondrite and enriched matrix is especially striking for Na, which is anomalously depleted in ALH A77307 in comparison with average CO chondrite abundances. The depletion in Na is probably attributable to the effects of leaching in Antarctica. With the exception of Na, the volatile elements show a relatively smooth decrease in abundance as a function of condensation temperature, indicating that their behavior is largely controlled by their volatility. 相似文献
978.
A Strontium and Neodymium Isotopic Investigation of the Fongen--Hyllingen Layered Intrusion, Norway 总被引:1,自引:0,他引:1
The FongenHyllingen Intrusion, situated 60 km SE of Trondheim,Norway, is a synorogenic layered mafic intrusion of Caledonianage . The intrusion is divided into four evolutionary stages based on cryptic variations: StageIa basal reversal; Stage IIunchanged mineral chemistryor slight normal evolution; Stage IIIa gradual regression;Stage IV a strong normal fractionation trend Magma replenishmentdominated during most of the crystallization, i.e. during StagesI, II and III Replenishing magma was more dense than resident,evolved magma, and continuing influx eventually caused a compositionallystratified magma column to form. Cryptic lateral variation isan important feature in the southern part of the complex andformed by in situ crystallization from a stratified magma alongan inclined floor, where modal layering formed parallel to thecrystallization front. Initial Sr- and Nd-isotopic ratios inthe cumulates vary as a result of assimilation of country rockand subsequent mixing between uncontaminated, replenishing magmaand contaminated, resident magma. The parental magma had a moderatelydepleted isotope composition, relative to Bulk Earth, with Nd=584and Sri=070308, whereas the main contaminant was a partialmelt of metapelitic country rock with Nd=-874 and Sri=07195(Sri is the initial 87Sr/86Sr). Sri in the analysed cumulatewhole-rock samples ranges from 070308 to 070535 and initialNd ranges from. 158 to 584. There is a strong correlationbetween mineralogical composition and isotopic trends in mostof the cumulates: the most primitive samples are the least contaminated,as reflected by relatively high ed and low Sr,, and more evolvedsamples have progressively lower eNi and higher Sry A gradualregression of several hundred metres thickness characterizesStage III; stratigraphically upwards mineral compositions becomemore primitive and isotope compositions more depleted (higherNd and lower Sri), implying a process of. progressive mixing-inof replenishing, primitive and uncontaminated magma. Magma influxin Stage III took place by fountaining, whereas magma additionwas more tranquil in the earlier stages. The fountaining influxentrained resident, relatively evolved and contaminated magma,resulting in a hybrid magma which ponded at the floor. Duringprolonged magma addition with concomitant crystallization, thelowermost magma layer was replaced by progressively more primitivehybrid magma, creating a gradual regression in the crystallizingcumulate sequence. A detailed two-dimensional study revealslateral variations in mineral compositions both at the baseand top of Stage III, whereas lateral variations in Sr- andNd-isotopic compositions are present at the top, but not atthe base. This implies that the lowest crystallizing part ofthe magma column was essentially isotopically homogeneous, butcompositionally stratified, before influx in Stage III. Isotopicgradients in the magma were strong close to the roof, wheremost of the assimilation occurred, and decreased downwards,merging into isotopically homogeneous magma. This stratifiedsystem was destroyed by turbulent mixing between replenishingand resident magma during fountaining influx in Stage III, anda new stratification was established with both an isotopic anda compositional gradient. After the final influx, crystallizationcontinued in an essentially closed system, in which the remainingmagma column eventually became homogenized, as magma layersmixed when their densities converged owing to release of buoyant,residual liquid during fractional crystallization.
Corresponding author 相似文献
979.
The carbon and oxygen isotopic composition of Fe-carbonate ore and its calcitic to dolomitic Devonian host rocks at the Steirischer Erzberg siderite deposit (Greywacke zone, Upper Austroalpine Unit) were determined in order to constrain the source and nature of the Fe-rich mineralizing fluid. The
18O-values obtained for various Fe-carbonate generations and the carbonate host lie within a similar range between + 14.6 and + 21.6 (V-SMOW). No good correlation exists between the relative ages of the carbonate phases and their O isotopic composition. The variation in
18O-values is due to metamorphic recrystallization with locally variable fluid/rock ratios. The average
13C-value of the carbonate host is +0.5 ± 1.2 (PDB) which corresponds well to worldwide Phanerozoic marine carbonate values. The first Fecarbonate generation has slightly lower
13C-values, on average -1.4 ± 0.8 (PDB). Recrystallization of both the carbonate host minerals and the ankerite/siderite led to significantly lower
13C-values of -4.2 ± 0.6 and-4.7 ± 0.7, respectively. Within the basal breccia of the post-Hercynian transgression series matrix calcite/ dolomite shows an average
13C-value of -2.9 ± 0.7, and matrix siderite/ankerite an average value of-4.1 ± 0.4. These data, together with Sr isotope data published previously, strongly support a late-diagenetic or epigenetic first Fe-mineralization from convecting formation waters. They ascended along extension faults and were driven by an increased heat flow caused by crustal thinning during a Devonian rifting phase that initiated the separation of the Noric terrane from Africa. A potential source of the Fe could have been the underlying Ordovician acid volcanics. Regional metamorphism related to collision tectonics in the Late Carboniferous (Hercynian) and later during the Alpine orogeny, caused intensive recrystallization and partial mobilization of the various carbonate phases. 相似文献
980.
Gold-silver mineralization in the Nelson area of southern Nevada was controlled by structures associated with intrusion of an east-west oriented pluton. Flatlying breccias formed during intrusion have allowed passive flooding of highly permeable zones and deposition of mineralized quartz and calcite. Steep fractures were formed in the pluton and immediate country rock during cooling, and later reactivated by north-south extension. These fractures have channelled fluids, and some have been the sites of hydrothermal eruptions which produced further brecciation and deposition of mineralized quartzcalcite veins. The mineralizing fluid was water which was boiling at or near 100 °C. The calcite deposited by this water has
13C = –5.4 to –7.1, and
18O = +5.8 to +11.3, and the water was probably meteoric in origin. Mineralization had an epithermal style, with strong local structural control, rather than deep-sourced regional detachment-related hydrothermal origin. 相似文献