A field and theoretical analysis of garnet+chlorite+chloritoid+biotite assemblages from the tri-state (MA,CT, NY) area,USA

The prograde evolution of minerals in metapelites of a Barrovian sequence from the tri-state area (Massachusetts, Connecticut, New York) of the Taconic Range involves assemblages with garnet (Ga), chlorite (Ch), chloritoid (Ct), biotite (Bi) and staurolite (St). Detailed petrologic observations, mineral compositions and chemical zoning in garnet show: (1) garnet high in Mn and Fe but low in Mg is stable with chlorite at grades below those where chloritoid+biotite is found; (2) early formed garnet reacted partially to form Ct+Bi at intermediate grades; (3) at higher grades garnet (with low Mn)+chlorite is again produced, at the expense of chloritoid+biotite, suggesting a reversal in the continuous reaction involving the phases Ga, Ch, Ct and Bi. Thermodynamic modeling of the assemblage Ga+Ch+Ct+Bi±St in the MnKFMASH system reveals: (1) in the MnKFASH system the prograde reaction is Ga+Ch=Ct+Bi whereas in the KFMASH system the prograde reaction is the opposite: Ct+Bi=Ga+Ch; (2) the Ga–Ch–Ct–Bi–St invariant point in the KFMASH system occurs twice, at approximately 6.5 kbar, 545° C and 14.8 kbar, 580° C (although one of them may be metastable in a complex phase system); the appearance of the petrogenetic grid is markedly different from that of Albee, but similar to that of Spear and Cheney; (3) as a consequence, in the KFMASH system, chloritoid+biotite are stable over a wide range of P-T conditions whereas garnet+chlorite assemblages are restricted to a narrow band of P-T conditions; (4) MnO increases the stability field of Ga+Ch relative to both Ct+Bi at low temperatures, and St+Bi at high temperatures; (5) in natural samples the occurrence of Ct+Bi is controlled more by bulk Mg–Fe(-Mn) composition than P-T conditions. Specifically, Ct+Bi is restricted to bulk compositions with Fe/(Mg+Fe+Mn)>0.6. Rocks with Fe/(Mg+Fe+Mn)<0.5 are likely to display only chlorite+biotite at low grade. These observations are consistent with Wang and Spear and Spear and Cheney.     

New compositional and optical data for antimonian and bismuthian varieties of hemusite from Japan

Summary New compositional and optical data are reported for antimonian and antimonianbismuthian varieties of hemusite from epithermal Au-Ag-Cu deposits in Japan. The empirical formula for the antimonian variety, from the Iriki mine is: (Cu_5.83Fe_0.14Ag_0.01)_5.98Mo_1.03(Sn_0.54Sb_0.41Te_0.03Bi_0.02)_1.00(S_7.85Se_0.15)_8.00, and that of the Sb-Bi variety from the Kawazu mine is: (Cu_5.84Fe_0.14Ag_0.01)_5.99Mo_1.03(Sn_0.82Sb_0.11Bi_0.l0Te_0.04)_1.07(S_7.80Se_0.12)_7.92. The theoretical formula of hemusite is Cu⁺ ₄Cu²⁺ ₂MO⁴⁺Sn⁴⁺S₈, whilst the most probable formula of the Iriki hemusite is Cu⁺ _4.5CU²⁺ _1.5Mo⁴⁺Sn⁴⁺ _0.5Sb⁵⁺ _0.5S₈, with Sb⁵⁺ substituting for Sn⁴⁺ and forming (SbS₄)^3– tetrahedra as might be expected, given that the metal to sulphur ratio is 1, and given the sphalerite-like structure of the mineral. However Bi³⁺ cannot be so accommodated, resulting in a deficiency in (S + Se) for Kawazu hemusite. Reflectance spectra for both are compared with those of the tungsten analogue (compositional) of hemusite, kiddcreekite. The relationship between hemusitesensu stricto and these newly reported varieties is discussed in terms of simple and coupled chemical substitutions, and inferences are drawn on the valency of Sb, Bi, Mo and Cu in the hemusite structure.

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Neue chemische und optische Daten für antimon- und bismuthführende Varietäten von Hemusit aus Japan

Zusammenfassung Neue chemische und optische Daten für antimon- und bismuthführende Hemusite auf epithermalen Au-Ag-Cu Lagerstätten in Japan werden vorgelegt. Die empirische Formel für die antimon-führende Varietät aus der Iriki-Mine ist: (Cu_5.83Fe_0.14Ag_0.01)_5.98Mo_1.03(Sn_0.54Sb_0.41Te_0.03Bi_0.02)_1.00 (S_7.85Se_0.15)_8.00, und die der Sb-Bi Varietät aus der Kawazu Mine ist: (Cu_5.84Fe_0.14Ag_0.01)_5.99M0_1.03(Sn_0.82Sb_0.11Bi_0.l0Te_0.04)_1.07 (S_7.80Se_0.12)_7.92. Die theoretische Formel von Hemusit ist Cu⁺ ₄Cu²⁺ ₂Mo⁴⁺Sn⁴⁺S₈, während die wahrscheinlichere Formel für den Hemusit von Iriki Cu⁺ ₄Cu²⁺ _1.5Mo⁴⁺Sn⁴⁺ _0.5Sb⁵⁺ _0.5S₈, mit Sb⁵⁺ an der Stelle von Sn⁴⁺, das(SbS₄)^3– Tetraeder bildet, wie zu erwarten ist, unter der Voraussetzung, da das Metall zu Schwefelverhältnis 1 und die Struktur sphaleritähnlich ist. Bi³⁺ kann jedoch nicht in dieser Weise untergebracht werden, und das führt zu einem Mangel an (S + Se) für den Hemusit von Kawazu. Die Reflektions-Spektren beider Minerale werden mit denen des Wolfram-Equivalents von Hemusit (Kiddcreekit) verglichen. Die Beziehung zwischen Hemusitsensu stricto und diesen jetzt beschriebenen Varietäten wird auf der Basis einfacher und gekoppelter chemischer Substitution diskutiert. Auf dieser Basis werden Schlüsse auf die Valenz von Sb, Bi Mo und Cu in der Hemusit-Struktur gezogen.

     

Decomposition of Hudson estuary macrophytes: Photosynthetic pigment transformations and decay constants

Plant pigment decay constants were determined for four macrophytes collected from the Hudson Estuary.Typha angustifolia andScirpus fluviatilis were used as representatives of emergent aquatic vegetation (EAV), andPotamogeton sp. andVallisneria americana were used to represent submerged aquatic vegetation (SAV). Litter bags were maintained in an environmental chamber in the dark for 104 d. The fastest rate of total mass loss was in the SAVV. americana and slowest in the EAVT. angustifolia. Changes in carotenoid and chloropigment concentration resulting from microbial and meiofaunal heterotrophy in each of the macrophytes were quantified using reverse-phase, high-performance liquid chromatography (RP-HPLC) techniques. Chlorophyllc and the carotenoid, fucoxanthin, provided useful biomarkers in determining the presence of epiphytic diatom growth, which only occurred on the SAV. The highest concentrations of phaeophorbidea, commonly used as an indication of metazoan grazing, were found in the SAVV. americana. Low concentrations of phaeophorbidea in the SAVPotamogeton sp. indicate inefficient use of this SAV by meiofaunal grazers. Lutein decayed slower than all other carotenoids in both EAV and SAV. Microcosm studies such as this are necessary to further understand the mechanisms and kinetics of photosynthetic pigment transformations in natural systems.     

Laser radiation in active amplifying media treated as a transport problem: Transfer equation derived and exactly solved

The flow of laser radiation in a plane-parallel cylindrical slab of active amplifying medium with axial symmetry is treated as a problem in radiative transfer. The appropriate one-dimensional transfer equation describing the transfer of laser radiation has been derived by an appeal to Einstein'sA, B coefficients (describing the processes of stimulated line absorption, spontaneous line emission, and stimulated line emission sustained by population inversion in the medium) and considering the rate equations to completely establish the rational of the transfer equation obtained. The equation is then exactly solved and the angular distribution of the emergent laser beam intensity is obtained; its numerically computed values are given in tables and plotted in graphs showing the nature of peaks of the emerging laser beam intensity about the axis of the laser cylinder.     

Astrometric investigation with the Tautenburg Schmidt telescope

The observations and the plate reduction technique for the determination of positions and absolute proper motions which is used in Potsdam are described. Recent results have shown that an accuracy of about 0 _. 1 for positions and 0 _. ⁷ cent _. ^–1 for proper motions can be achieved both for bright (8^m–12^m) and faint (16^m–18^m) stars. Three astrometric programmes using the Tautenburg plates are presented.     

V792 Her=HD 155638: A totally eclipsing RS CVn binary

Photometry of HD 155638=V792 Her has been analyzed to determine the elements of this totally eclipsing RS CVn binary. The light variation outside eclipse was found to have a period of 27^d.07±0^d.07, which is slightly different from the 27^d.5384±0^d.0045 orbital period. Analysis of the eclipses was achieved by a modification of the Russell-Merrill technique. With the aid of radial velocity measures, absolute elements were obtained for the hot and cool stars, respectively;R _h=2.58R ,R _c=12.28R ,M _h=1.40M ,M _c=1.46M ,i=80^o.61 and velocity semi-amplitudesK _c=48.36 km s^–1±0.79 km s^–1, andK _h=50.50 km s^–1±0.33 km s^–1. The apparent magnitudes areV _h=9 ^m .73 andV _c=8 ^m .48. The distance to HD 155638 was estimated to be 310 parsecs.     

Diurnal photometric conditions at Teide observatory and long-term solar irradiance variations

Monochromatic extinction coefficients at four wavelengths have been obtained over a period of more than two years at the Observatorio del Teide (Izaña Tenerife) using a full disc, direct sunlight, quadruple photometer devoted to the detection of integral luminosity oscillations of the Sun. The mean extinction coefficients (0.13 at 500 nm) show a seasonal variation of about 15%, the best atmospheric conditions being in winter and autumn. Moreover, in anyone day the extinction coefficient in the afternoon is always lower than the one in the morning by 7%. A one-year period fluctuation, with an amplitude of 0.035 mag, has been identified in the instrumental magnitudes outside the atmosphere, and is interpreted as the variation produced by the different Sun-Earth distance from winter to summer. Finally, the study made to detect periodic time fluctuations in both, Sun's magnitude and extinction coefficients, has given null results at levels of 0.04 and 1.8%, respectively.     

Spectrophotometric observations of delta Capricorni

Spectrophotometric observations of the eclipsing binary system Capricorni, covering the wavelength interval 3300–7300 Å, have been presented. Comparison of the standard spectral scans of Cap with the spectral scans of the stars of known spectral types and luminosity classes taken from the Breger (1976) catalogue shows that, near the phase of secondary eclipse, Cap shows the spectral-luminosity type as A8-9III. This is in agreement with the photometric findings of Srivastava (1987b). H emission is not visible convincingly, however, some irregularities are apparent, at least in two scans, around the H region.     

Sub-iron to iron nuclei in low-energy (50–200 MeV nucl−1) cosmic rays as observed in the Skylab experiment

In this paper we present our most recent results on the sub-iron (Sc to Cr) to Fe nuclei abundance ratios in the low-energy cosmic rays of 50 to 250 MeV nucl.^–1 and their implications as observed in theSkylab experiment. In view of the importance of this ratio in determining the cosmic-ray pathlength in interstellar medium, we have obtained additional data in the same detector module and the results of final analysis are reported. Charge determinations in the Lexan detector were made from an average of about four independent measurements ofZ for each of the cosmic-ray events and the mean charge resolution is obtained asZ/Z0.2. From about 100 events of calcium to nickel in low-energy cosmic rays, sub-iron (Sc to Cr) to Fe–Co ratio is determined as 1.43±0.40 in 50–250 MeV nucl.^–1. This shows a large energy dependence of the ratio as compared to the value of 0.4–0.8 in 200–1000 MeV nucl.^–1 as measured by many investigators. The origin of this large enhancement of the ratios in low-energy cosmic rays is not known at present. Some possible suggestions are briefly mentioned.     

Identification of the interstellar cyanomethyl radical (CH2CN) in the molecular clouds TMC-1 and Sagittarius B2

We report the astronomical identification of the cyanomethyl radical, CH2CN, the heaviest nonlinear molecular radical to be identified in interstellar clouds. The complex fine and hyperfine structures of the lowest rotational transitions at about 20.12 and 40.24 GHz are resolved in TMC-1, where the abundance appears to be about 5 x 10(-9) relative to that of H2. This is significantly greater than the observed abundance of CH3CN (methyl cyanide) in TMC-1. In Sgr B2 the hyperfine structure is blended in the higher frequency transitions at 40, 80, and 100 GHz, although the spin-rotation doubling is clearly evident. Preliminary searches in other sources indicate that the distribution of CH2CN is similar to that for such carbon chain species as HC3N or C4H.