Carbonate equilibria in hydrothermal systems: First ionization of carbonic acid in NaCl media to 300°C

The ionization quotients of aqueous carbon dioxide (carbonic acid) have been precisely determined in NaCl media to 5 m and from 50° to 300°C using potentiometric apparatus previously developed at Oak Ridge National Laboratory. The pressure coefficient was also determined to 250°C in the same media. These results have been combined with selected information in the literature and modeled in two ways to arrive at the best fits and to derive the thermodynamic parameters for the ionization reaction, including the equilibrium constant, activity coefficient quotients, and pressure coefficients. The variation with temperature of the two fundamental quantities $\text{Δ}\text{V}\text{?}{}^{\mathrm{o}}$ and $\text{Δ}\text{C}\text{?}{}^{\mathrm{o}}{}_{\mathrm{p}}$ were examined along the saturation vapor pressure curve and at constant density. The results demonstrated again that for reactions with minimal electrostriction changes the magnitudes and variations of $\text{Δ}\text{C}\text{?}{}^{\mathrm{o}}{}_{\mathrm{p}}$ and $\text{Δ}\text{V}\text{?}{}^{\mathrm{o}}$ with temperature are small and, in addition, $\text{Δ}\text{C}\text{?}{}_{\mathrm{p}}$ and $\text{Δ}\text{V}\text{?}$ are approximately independent of salt concentration.The results have also been applied to an examination of the solubility of calcite as a function of pH (in a given NaCl medium) for the neutral to acidic region both for systems with fixed CO₂ pressure and systems where the calcium ion concentration equals the concentration of carbon. The pH of saturated solutions of calcite with P_CO2 of 12 bars increases from 5.1 to 5.5 between 100° and 300°C.     

The effects of topographically-controlled thermal tides in the martian upper atmosphere as seen by the MGS accelerometer

Mars Global Surveyor accelerometer observations of the martian upper atmosphere revealed large variations in density with longitude during northern hemisphere spring at altitudes of 130-160 km, all latitudes, and mid-afternoon local solar times (LSTs). This zonal structure is due to tides from the surface. The zonal structure is stable on timescales of weeks, decays with increasing altitude above 130 km, and is dominated by wave-3 (average amplitude 22% of mean density) and wave-2 (18%) harmonics. The phases of these harmonics are constant with both altitude and latitude, though their amplitudes change significantly with latitude. Near the South Pole, the phase of the wave-2 harmonic changes by 90° with a change of half a martian solar day while the wave-3 phase stays constant, suggesting diurnal and semidiurnal behaviour, respectively. We use a simple application of classical tidal theory to identify the dominant tidal modes and obtain results consistent with those of General Circulation Models. Our method is less rigorous, but simpler, than the General Circulation Models and hence complements them. Topography has a strong influence on the zonal structure.     

Formation Of Coronal Mhd Shock Waves – I. The Basic Mechanism

The formation and evolution of a large amplitude MHD perturbation propagating perpendicular to the magnetic field in a perfectly conducting low plasma is studied. The perturbation is generated by an abrupt expansion of the source region. Explicit expressions for the time and the distance needed for the transformation of the perturbation's leading edge into a shock wave are derived. The results are applied to coronal conditions and the dynamic spectra of the radio emission excited by the shock are synthesized, reproducing metric and kilometric type II bursts. The features corresponding to the metric type II burst precursor and the moving type IV burst in the case of kilometric type II bursts are identified. A specific radio signature that is sometimes observed at the onset of a metric type II burst is found to appear immediately before the shock wave formation due to the associated growth of the magnetic field gradient. Time delays and starting frequencies of bursts' onsets are calculated and presented as a function of the impulsiveness of the source-region expansion, using different values of the ambient Alfvén velocity and various time profiles of the expansion velocity. The results are confronted with the observations of metric and kilometric type II solar radio bursts.     

Ecological-geochemical assessment of the state of the Volga source of water supply to Moscow

Long-term observational data (1992?C2009) on heavy metal (Cu, Zn, Pb, Cr, Ni, V, Mo, Co, Fe, and Mn) content of different links in the Ivankovo Reservoir ecosystem are used to consider the regularities in the distribution and behavior of heavy metals in the system anthropogenic pollution sources-reservoir and its drainage area, thus enabling the assessment of the pollution level of the Volga Source of water supply to Moscow.     

The Dergaon (H5) chondrite: Fall,classification, petrological and chemical characteristics,cosmogenic effects,and noble gas records

Abstract— A multiple fall of a stony meteorite occurred near the town of Dergaon in Assam, India, on March 2, 2001. Several fragments weighing <2 kg and a single large fragment weighing ～10 kg were recovered from the strewn field, which extended over several tens of square kilometers. Chemical, petrographic, and oxygen isotopic studies indicate it to be, in most aspects, a typical H5 chondrite, except the unusually low K content of ～340 ppm. A cosmic ray exposure of 9.7 Ma is inferred from the cosmogenic noble gas records. Activities of eleven cosmogenic radionuclides were measured. ²⁶Al and ²²Na activities as well as the ²²Na/²⁶Al activity ratio are close to the values expected on the basis of solar modulation of galactic cosmic rays. The low ⁶⁰Co activity (<1 dpm/kg) is indicative of a small preatmospheric size of the meteorite. Cosmic ray heavy nuclei track densities in olivine grains range from ～106 cm^?2 in samples from the largest fragment to approximately (4–9) × 105 cm^?2 in one of the smaller fragments. The combined track, radionuclide, and noble gas data suggest a preatmospheric radius of ～20 cm for the Dergaon meteorite.     

中国汽车工业──改革开放后的重整与国际化

大规模的重整和广泛的国际化是改革开放后中国汽车工业发展的两个主要特征。作者首先从企业组织结构、生产能力与品种结构、规模经济和空间分布等四个方面分析了近二十年来中国汽车工业重整的效果及所形成的行业特征;其次根据利用的外资和技术的来源以及涉及的技术形态分析了其国际化的程度及在世界汽车工业中的位置;最后总结了中国汽车工业面临的若干问题,并提出在散乱的格局和跨国公司竞争的双重压力下,中国汽车工业正处于成长的关键时期。     

磁场重联和日冕物质抛射

Basic processes of magnetic reconnection and observations of coronal mass ejection are introduced. A possible mechanism of CME caused by magnetic rcconnection in the current sheet of solar corona is suggested.     

From the Sun to the Earth: The 13 May 2005 Coronal Mass Ejection

We report the results of a multi-instrument, multi-technique, coordinated study of the solar eruptive event of 13 May 2005. We discuss the resultant Earth-directed (halo) coronal mass ejection (CME), and the effects on the terrestrial space environment and upper Earth atmosphere. The interplanetary CME (ICME) impacted the Earth’s magnetosphere and caused the most-intense geomagnetic storm of 2005 with a Disturbed Storm Time (Dst) index reaching ?263 nT at its peak. The terrestrial environment responded to the storm on a global scale. We have combined observations and measurements from coronal and interplanetary remote-sensing instruments, interplanetary and near-Earth in-situ measurements, remote-sensing observations and in-situ measurements of the terrestrial magnetosphere and ionosphere, along with coronal and heliospheric modelling. These analyses are used to trace the origin, development, propagation, terrestrial impact, and subsequent consequences of this event to obtain the most comprehensive view of a geo-effective solar eruption to date. This particular event is also part of a NASA-sponsored Living With a Star (LWS) study and an on-going US NSF-sponsored Solar, Heliospheric, and INterplanetary Environment (SHINE) community investigation.