Fluid inclusion and cathodoluminescence studies on fluorite from the Kerio valley, Kenya

The Kerio valley lies between the Elgeyo escarpment and the Tugen hills which mark the western margin of the Kenya rift valley. The main fluorite deposits are located in the southern part of the valley at Kimwarer, Choff and Kamnaon.Three types of inclusion fillings were identified: Liquid+Vapour, Liquid+Daughter Minerals and Liquid. The L+V type is dominant. Inclusions occur as clusters, trails along the crystal growth zones and as isolated ones. Low salinities, apparently lower than the 5% wt. NaCl equivalent, were established. Homogenization temperatures suggest that fluorite mineralization took place at different stages and at temperatures between 120 and 180 °C. Isolated readings above 180°C may be referring to the original inclusions in limestone. These measurements and the absence of CO₂ in the inclusions, as well as the occurrence of vugs and crustifications with fluorite, suggest that mineralization took place at relatively shallow depths.Emission spectrum lines representing Eu²⁺, Dy³⁺, Tb³⁺ and Sm³⁺ in fluorite were identified. Sm³⁺ was detected only in the pinkish luminescence of veined fluorite, whereas the pinkish zone in banded fluorite contains Tb³⁺. Eu²⁺ which gives the strongest emission lines in the blue part of the visible spectrum, apparently is responsible for the strong blue cathodoluminescence (CL) in fluorite. The dominance of Eu²⁺ peaks further points to the fact that fluorite mineralization in the Kerio valley took place in an environment that was enriched in Lanthanide Rare Earth Elements (LREE). The presence of rare earths and radioactive elements in fluorite points towards their enrichment in the environment of fluorite mineralization. A juvenile origin of mineral forming solutions is proposed.Two generations of fluorite were established: allotriomorphic fluorite, forming the matrix, and the idiomorphic variety, occurring either in barite or in druzes in early fluorite. Barite in turn forms idiomorphic crystals in allotriomorphic fluorite. Relics of calcite occur in both K-feldspars and in early fluorite. Oxides and hydroxides of Fe, Mn, Ti and Al commonly occur in open spaces in fluorite. Of significance is the presence of gold in fluorite. Fluorite mineralization is of hydrothermal origin in the post-Miocene era and was formed as a result of metasomatic replacement of marble and open space fillings.     

Deep convective cloud scales and direct adjustment of upper troposphere moisture in TWP environment

Summary A conceptually simple model based on cloud geometry is proposed to explain direct adjustment of moisture by convective clouds. The model is tested using deep convective cloud geometry and changes in upper tropospheric humidity in the Tropical Western Pacific (TWP) during TOGACOARE. The model and the data emphasize the importance of clouds larger than a General Circulation Model (GCM) grid box in drying the upper topospheric environment and in sub grid scale clouds in moistening the upper topospheric environment. The convective cloud sizes and changes in moisture are shown to be linked to precipitation rates. The change from clouds that moisten to clouds that dry the environment occurs when the average cloud size in 6.8×10⁴ km² or rain rate of 2.1 mm hr^–1. In a study of moisture change in the sub cloud layer due to convection, Barnes and Garstang (1982) demonstrated that precipitation rates greater than 2 mm hr^–1 resulted in drying. The critical rain rates above which environmental drying occurs is similar for both upper tropospheric regions and the sub cloud. The similarity of the rain rates indicates that the model concepts maybe used to explain direct adjustment of moisture under a variety of conditions.With 12 Figures     

Calibration of the high-pressure cohesive strength meter (CSM)

Coastal erosion is an immense economic and social problem that has been receiving increased attention in recent years. A number of devices have been developed to determine the sediment stability in coastal areas: laboratory and field flumes; a range of different erosion devices; shear vanes and fall cone penetrometers. The cohesive strength meter (CSM) erosion device was developed to determine in situ the temporal and spatial variations in the erosion threshold of muddy intertidal sediments. Technological developments have enabled considerable improvements to be made to the original design over the last 15 years.     

Paleomagnetism of the Cambro-Ordovician McClure Mountain alkalic complex,Colorado

The Middle to Late Cambrian loop in the North American apparent polar wander path (APWP) has been variously attributed to tectonic rotations, remagnetizations and primary magnetizations. Although no primary thermal remanent magnetizations or primary detrital remanent magnetizations have as yet been demonstrated, the temporally self-consistent nature of the loop has been used as an argument for primary magnetizations. We have studied535 ± 5Ma nepheline syenites and syenites of the McClure Mountain alkalic complex, as well as495 ± 10Ma red trachyte dikes which intruded the complex, in an effort to find a primary TRM. Because Zijderveld analysis yielded consistent results for only one trachyte dike, remagnetization great-circle analysis was employed, giving a pole for the trachyte dikes at the tip of the loop (43°N, 114°E), while the syenites and nepheline synenites gave a pole at the base of the loop (18°N, 142°E). The magnetic carrier in the trachytes is hematite which apparently formed during a pervasive hydrothermal alteration. KAr whole rock dating of the trachytes suggests a Pennsylvanian age for the alteration, and thus a late Paleozoic remagnetization of the trachytes. Thus, the low-latitude Cambrian pole is confirmed, but we find no evidence in this study to support the primary nature of the Cambrian APWP.     

Solitary wave generation dynamics at Luzon Strait

A high resolution modeling study is undertaken, with a 2.5-dimensional nonhydrostatic model, of the generation of internal waves induced by tidal motion over the ridges in Luzon Strait. The model is forced by the barotropic tidal components K1, M2, and O1. These tidal components, along with the initial density field, were extracted from data and models. As the barotropic tide moves over the Luzon Strait sills, there is a conversion of barotropic tidal energy into baroclinic tidal energy. Depressions are generated that propagate towards the Asian Seas International Acoustics Experiment (ASIAEX) test site on the Chinese continental shelf. Nonlinear effects steepen the depressions, frequency and amplitude dispersion set in, and disintegration into large amplitude solitary waves occurs. The effects of varying the initial density field, tidal component magnitudes, as well as adding a steady background current to represent the occasional excursions of the Kuroshio Current into the strait, are considered.Depressions are generated at each of the two sills in Luzon Strait which radiate away, steepening and evolving into internal solitary wave trains. Baroclinic fluxes of available potential energy, kinetic energy and linear are calculated for various parameter combinations. The solitary wave trains produced in the simulations generally consist of large amplitude wave trains alternating with small amplitude wave trains. During strong tidal flow, Kelvin–Helmholtz type instabilities can develop over the taller double-humped sill. The solitary waves propagating towards the ASIAEX test site have been observed to reach amplitudes of 120–250 m, depending on the tidal strength. ASIAEX observations indicate amplitudes up to 150 m and the Windy Island Experiment (WISE) measurements contain magnitudes over 200 m. The model results yield solitary wave amplitudes of 70–300 m and half widths of 0.60–3.25 km, depending on parameter values. These are in the range of observations. Measurements by Klymak et al. (2006), in the South China Sea, exhibit amplitudes of 170 m, half widths of 3 km and phase speeds of 2.9 m s^?1. Model predictions indicate that the solitary waves making up the wave packet each experience different background currents with strong near surface shear.The energy in the leading soliton of the large amplitude wave trains ranges between 1.8 and 9.0 GJ m^?1. The smaller value, produced using barotropic tidal currents based on the Oregon State University data base, is the same as the energy estimated to be in a solitary wave observed by Klymak et al. (2006). Estimates of the conversion of barotropic tidal energy into radiating internal wave energy yield conversion rates ranging between 3.6% and 8.3%.     

Relationship between the effective diffusion coefficient of soil radon and groundwater recharge in semi-arid areas

Herein, the relationship between soil radon behavior and groundwater recharge in the town of Hosha, a semi-arid area of Jordan is explored. The annual rainfall average in this area is between 60–100 mm year⁻¹. Soil radon concentration levels, using CR-39 detectors, have been measured at several depths. Nine sampling sites on a hill slope, in the summer and winter 2006 were chosen. Other soil parameters such as moisture, soil type and porosity were also measured. Correlation between the latter and the calculated effective diffusion coefficients, based on a linear approximation, was done in order to explore water movement. A weak correlation between the soil radon concentration and water recharge in this particular semi-arid area is observed. The results show that water recharge takes place vertically, i.e., water moves downward and in one of the nine sampling sites this movement seems to be more rapid compared to the other sites.     

Searches for very high energy gamma rays from blazars with CANGAROO-III telescope in 2005-2009

We have searched for very high energy (VHE) gamma rays from four blazars using the CANGAROO-III imaging atmospheric Cherenkov telescope. We report the results of the observations of H 2356-309, PKS 2155-304, PKS 0537-441, and 3C 279, performed from 2005 to 2009, applying a new analysis to suppress the effects of the position dependence of Cherenkov images in the field of view. No significant VHE gamma ray emission was detected from any of the four blazars. The GeV gamma-ray spectra of these objects were obtained by analyzing Fermi/LAT archival data. Wide range (radio to VHE gamma-ray bands) spectral energy distributions (SEDs) including CANGAROO-III upper limits, GeV gamma-ray spectra, and archival data, even though they are non-simultaneous, are discussed using a one-zone synchrotron self-Compton (SSC) model in combination with a external Compton (EC) radiation. The HBLs (H 2356-309 and PKS 2155-304) can be explained by a simple SSC model, and PKS 0537-441 and 3C 279 are well modeled by a combination of SSC and EC model. We find a consistency with the blazar sequence in terms of strength of magnetic field and component size.     

Grain-scale variations in trace element composition of fluid-altered zircon,Acasta Gneiss Complex,northwestern Canada

SEM back-scattered electron images of zircon separates from a 2.9 Ga granitic dyke from the Acasta Gneiss Complex, Slave Province, reveal primary igneous oscillatory zoning which is transgressively overprinted by irregular alteration domains. Electron microprobe analyses show that altered zircon domains are depleted in Zr and Si relative to unaltered zircon while retaining a constant Zr/Si ratio. SIMS trace element analyses indicate that LREE are preferentially enriched in the altered domains. Altered zircon contains elevated concentrations of Ba (up to 580 ppm), Ca (up to 2% weight of the element) and common Pb (>50 ppb). The presence of LREE, Ca, Ba and common Pb in the zircons is interpreted to be the result of secondary alteration by an aqueous fluid, and not by primary incorporation during crystallization. We propose that the alteration-related elements are located in amorphous zircon domains.     

Synthesis and characterization of zeolite X obtained from kaolin for adsorption of Zn（Ⅱ）

This study deals with the synthesis and characterization of low-silica zeolite X, from calcined Kalabsha kaolin, for adsorption of Zn(Ⅱ) ions from aqueous solution. The synthesis processes is performed under hydrothermal treatment in alkaline solutions. The obtained zeolite samples are characterized using X-ray diffraction, grain size distribution, surface area, and SEM. The critical molar ratios of both SiO2/Al2O3 and K2O/Na2O are about 2.9 and 0.16, respectively. Those ratios are needed to give individual low silica zeolite X in a minimum reaction time. The adsorption capacity of the synthesized products is determined by adsorption of Zn(Ⅱ) ions from solution. The results suggest that the zeolite obtained could be converted to a beneficial product, which will be used in future as an ion exchanger in removing heavy metals from wastewaters.