Rare earth elements in tourmaline and chlorite from tin-bearing assemblages: Factors controlling fractionation of REE in hydrothermal systems

The REE distribution in minerals from tin-bearing ore-magmatic systems of the Russian Far East, including the Komsomolsk, Khingan, and Badzhal districts in the Amur region and the Kavalerovo, Lesozavodsk, Voznesenka, Furmanovo, and other districts in Primorsky krai, has been studied. The main attention was focused on tourmaline and chlorite; in addition, associated biotite, feldspar, apatite, fluorite, and carbonates were examined. The major factors affecting the REE distribution in the studied minerals are the temperature, Eh, and pH of the mineral-forming medium; crystal chemistry; partition coefficients of REE between fluid and minerals; and complexation that disturbs the coherent behavior of REE. Fluid evolution at different stages is characterized.     

The Seyfert 1 galaxy Ark 120. Spectral variability in 1992–2005

We have studied the variability of the Hβ line and the adjacent continuum in the spectrum of the Seyfert galaxy Ark 120, based on spectral observations of the galaxy’s nucleus obtained in the Crimea in 1992–2005, supplemented by published data for 1988–1996. Irregular variability on various timescales (years to days) can be accompanied by periodic brightness variations in both the continuum and the Hβ line, with a period of P ～ 430 days and an amplitude of Δm ～ 0.2 ^m in the continuum, which were traced for more than 13 cycles. In total, in 1988–2005, the flux variations in the line lag those in the continuum by 55 ± 9 days if calculated from the peak of the cross correlation function, or by 72 ± 7 days, if calculated from the centroid of the CCF. The delay is correlated with the continuum brightness, increasing when the continuum flux increases. The Hβ line profiles indicate both a high degree of diversity and the presence of features that recur after various extended time intervals. Analysis of the evolution of the differences between each individual normalized line profile and the mean normalized profile indicates systematic motion of excesses relative to the average profile from negative to positive radial velocities. In contrast, parts of the Hβ line with low radiation relative to the mean normalized profile evolve in the opposite direction (from the red to the blue Hβ wing). This pattern is also typical for the rotating broad-line region, if this region has the form of a disk. The rotation period exceeds 9000–10000 days, or 25–27 years. The size of the broad-line region calculated form this period corresponds to a reverberation time of no fewer than 30 days, consistent with the results of cross-correlation analysis.     

Surface complexation modeling of Cu(II) adsorption on mixtures of hydrous ferric oxide and kaolinite

Background  

The application of surface complexation models (SCMs) to natural sediments and soils is hindered by a lack of consistent models and data for large suites of metals and minerals of interest. Furthermore, the surface complexation approach has mostly been developed and tested for single solid systems. Few studies have extended the SCM approach to systems containing multiple solids.     

Comparison of dissolved and particulate arsenic distributions in shallow aquifers of Chakdaha, India, and Araihazar, Bangladesh

Background  

The origin of the spatial variability of dissolved As concentrations in shallow aquifers of the Bengal Basin remains poorly understood. To address this, we compare here transects of simultaneously-collected groundwater and aquifer solids perpendicular to the banks of the Hooghly River in Chakdaha, India, and the Old Brahmaputra River in Araihazar, Bangladesh.     

Crystal chemistry of selenates with mineral-like structures: V. Crystal structures of (H3O)2[(UO2)(SeO4)2(H2O)](H2O)2 and (H3O)2[(UO2)(SeO4)2(H2O)](H2O), new compounds with rhomboclase and goldichite topology

The crystal structures of two new compounds (H₃O)₂[(UO₂)(SeO₄)₂(H₂O)](H₂O)₂ (1, orthorhombic, Pnma, a = 14.0328(18), b = 11.6412(13), c = 8.2146(13) Å, V = 134.9(3) ų) and (H₃O)₂[(UO₂)(SeO₄)₂(H₂O)](H₂O) (2, monoclinic, P2₁/c, a = 7.8670(12), b = 7.5357(7), c = 21.386(3) Å, β = 101.484(12)°, V = 1242.5(3) ų) have been solved by direct methods and refined to R ₁ = 0.076 and 0.080, respectively. The structures of both compounds contain sheet complexes [(UO₂)(SeO₄)₂]^2? formed by cornershared [(UO₂)O₄(H₂O)] bipyramids and SeO₄ tetrahedrons. The sheets are parallel to the (100) plane in structure 1 and to (?102) in structure 2. The [(UO₂)(SeO₄)₂(H₂O)]^2? layers are linked by hydrogen bonds via interlayer groups H₂O and H₃O⁺. The sheet topologies in structures 1 and 2 are different and correspond to the topologies of octahedral and tetrahedral complexes in rhomboclase (H₂O₂)⁺[Fe(SO₄)₂(H₂O)₂] and goldichite K[Fe(SO₄)₂(H₂O)₂](H₂O)₂, respectively.     

Rotational and magnetic corrections to the g-mode frequencies in a one-dimensional MHD model

The central magnetic field and rotation of the solar radiative zone are responsible for corrections to the g-mode frequencies. Magnetogravitational spectra are calculated analytically in a simple one-dimensional MHD model that goes beyond the WKB approximation and avoid any cusp resonances that trap the wave within the radiative zone in the presence of a weak magnetic background. The calculations are compared with spacecraft observations of the 1% frequency shifts for candidate g-modes found in the SOHO GOLF experiment. The magnetic correction is the main contribution for a strong magnetic field satisfying the approximation used. It is shown that a constant magnetic field of 700 kG in the radiative zone provides the required frequency shift for the n = ?10 g-mode. The rotational correction, which is due to the Coriolis force in the one-dimensional model used, is much less than a percent (α_Ω ≤ 0.003).     

Numerical simulation of a stratigraphic model

A multi-lithology diffusive stratigraphic model is considered, which simulates at large scales in space and time the infill of sedimentary basins governed by the interaction between tectonics displacements, eustatic variations, sediment supply, and sediment transport laws. The model accounts for the mass conservation of each sediment lithology resulting in a mixed parabolic, hyperbolic system of partial differential equations (PDEs) for the lithology concentrations and the sediment thickness. It also takes into account a limit on the rock alteration velocity modeled as a unilaterality constraint. To obtain a robust, fast, and accurate simulation, fully and semi-implicit finite volume discre tization schemes are derived for which the existence of stable solutions is proved. Then, the set of nonlinear equations is solved using a Newton algorithm adapted to the unilaterality constraint, and preconditioning strategies are defined for the solution of the linear system at each Newton iteration. They are based on an algebraic approximate decoupling of the sediment thickness and the concentration variables as well as on a proper preconditioning of each variable. These algorithms are studied and compared in terms of robustness, scalability, and efficiency on two real basin test cases.     

Contributions of boron isotopes to understanding the hydrogeochemistry of the coastal detritic aquifer of Castellón Plain,Spain

The Castellón Plain alluvial aquifer, Spain, is intensively exploited to meet the demand for agricultural irrigation and industrial water supply. The geochemistry of its groundwater shows complex salinization in the northern and southern parts of the aquifer, with significant pollution from human origin in the central portion. Boron content and B isotope geochemistry are useful for distinguishing between various sources of pollution and their relative importance in different parts of this aquifer. Boron concentrations in the groundwater vary between 0.01 and 0.85 mg/L. In the more saline groundwaters, found at the northern and southern ends of the study area, the presence of B is linked to inputs from seawater and water with a calcium-magnesium sulphate facies, which feed the aquifer and clearly influence the chemistry of its waters. Evidence of B adsorption processes in some samples is shown by the low B/Cl ratios and the high values of δ¹¹B. In the central portion of the aquifer, the high B/Cl ratios and the strongly negative δ¹¹B are related to pollution of human origin.     

Evaluation of distributed recharge in an upland semi-arid karst system: the West Bank Mountain Aquifer,Middle East

Assessment of recharge in a structurally complex upland karst limestone aquifer situated in a semi-arid environment is difficult. Resort to surrogate indicators such as measurement of spring outflow and borehole discharge, is a common alternative, and attempts to apply conventional soil moisture deficit analysis may not adequately account for the intermittent spate conditions that arise in such environments. A modelling approach has been made using the West Bank Mountain Aquifer system in the Middle East as a trial. The model uses object oriented software which allows various objects to be switched on and off. Each of the main recharge processes identified in the West Bank is incorporated. The model allows either conventional soil moisture deficit analysis calculations or wetting threshold calculations to be made as appropriate, and accommodates both direct recharge and secondary recharge. Daily time steps enable recharge and runoff routing to be calculated for each node. Model runs have enabled a series of simulations for each of the three aquifer basins in the West Bank and for the whole of the West Bank. These provide recharge estimates comparable to those prepared by earlier workers by conventional means. The model is adaptable and has been successfully used in other environments.     

Artificial neural network and liquefaction susceptibility assessment: a case study using the 2001 Bhuj earthquake data,Gujarat, India

This study pertains to prediction of liquefaction susceptibility of unconsolidated sediments using artificial neural network (ANN) as a prediction model. The backpropagation neural network was trained, tested, and validated with 23 datasets comprising parameters such as cyclic resistance ratio (CRR), cyclic stress ratio (CSR), liquefaction severity index (LSI), and liquefaction sensitivity index (LSeI). The network was also trained to predict the CRR values from LSI, LSeI, and CSR values. The predicted results were comparable with the field data on CRR and liquefaction severity. Thus, this study indicates the potentiality of the ANN technique in mapping the liquefaction susceptibility of the area.