Density measurements of liquid Fe–Si alloys at high pressure using the sink–float method

The compositional dependence on the density of liquid Fe alloys under high pressure is important for estimating the amount of light elements in the Earth’s outer core. Here, we report on the density of liquid Fe–Si at 4 GPa and 1,923 K measured using the sink–float method and our investigation on the effect of the Si content on the density of the liquid. Our experiments show that the density of liquid Fe–Si decreases from 7.43 to 2.71 g/cm³ non-linearly with increasing Si content (0–100 at%). The molar volume of liquid Fe–Si calculated from the measured density gradually decreases in the compositional range 0–50 at% Si, and increases in the range 50–100 at% Si. It should be noted that the estimated molar volume of the alloys shows a negative volume of mixing between Fe and Si. This behaviour is similar to Fe–S liquid (Nishida et al. in Phys Chem Miner 35:417–423, 2008). However, the excess molar volume of mixing for the liquid Fe–Si is smaller than that of liquid Fe–S. The light element contents in the outer core estimated previously may be an underestimation if we take into account the possible negative value of the excess mixing volume of iron–light element alloys in the outer core.     

Decrease in anthropogenic nutrients and its effect on the C/N/P molar ratio of suspended particulate matter in hypertrophic Dokai Bay (Japan) in summer

Biologically important nutrient concentrations in Dokai Bay have declined as a result of reductions in anthropogenic inputs of total nitrogen and total phosphorus. A decrease in nutrient concentrations affects phytoplankton growth, thereby changing the biochemical characteristics of autochthonous particulate matter. We therefore investigated changes in the C/N/P molar ratio of suspended particulate matter (SPM) in the summer, when phytoplankton growth is vigorous, before environmental quality standards (EQSs) were attained (1995–1998) and afterward (2006–2009). We found that the ratio of particulate organic nitrogen (PON) to particulate phosphorus (PP) changed in conjunction with changes in the ratio of dissolved inorganic nitrogen to dissolved inorganic phosphorus (DIP) that resulted from reductions in nutrient loading. Furthermore, we suggest that because the DIP concentration in seawater was high before EQSs were attained, inorganic phosphorus was possibly adsorbed onto SPM. After the attainment of EQSs, however, the DIP concentration fell, and PON/PP was high. Phosphorus limitation of phytoplankton growth in the mouth of the bay may explain the high PON/PP ratios after EQS attainment.     

The influence of environmental variability on silicate exchange rates between sediment and water in a shallow-water coastal ecosystem,the Seto Inland Sea,Japan

Silicate regeneration was determined in a shallow-water coastal ecosystem (Shido Bay, the Seto Inland Sea, Japan) during 1999-2000. The present study was carried out directly by core incubation and by determining gradients of dissolved silicate (DSi) in the pore water. Incubated fluxes ranged from 25.5 to 132.6 mgSim(-2)d(-1), and were 1.6-21.6 times greater than diffusive fluxes (5.4-43.3 mgSim(-2)d(-1)). The disparity between fluxes measured by core incubation and modeling pore water indicated that other physical, chemical or biological processes, in addition to diffusion of DSi from below, contribute to DSi fluxes measured during the incubation of undisturbed cores. A regression analysis revealed that water temperature and salinity explained 24% and 23%, respectively, of season to season variability in incubated fluxes. Microphytobenthos was responsible for 37% of the variability in measured rate of DSi fluxes, with greatly reducing DSi release rates due to their own DSi demand. Moreover, the inverse relationship between the DSi fluxes and biogenic silica (Bio-Si) concentrations in the surface sediment, suggested that about 41% of the variability in the DSi fluxes were explained by Bio-Si concentrations in the surface sediment. As a result, Shido Bay showed silicate regeneration of incubated cores to be a consequence of Bio-Si dissolution depending on microphytobenthos, temperature and salinity, while diffusive fluxes appeared to be limited by DSi in the pore water. An annual average of DSi flux (68.7+/-32.9 mgSim(-2)d(-1)) from the sediments to the water column corresponds to 38% of DSi, required for primary production by phytoplankton in Shido Bay.     

The paradox of smooth and abrupt bends in two-dimensional in-plane shear-crack mechanics

It is pointed out, in the context of the boundary integral equation method (BIEM), that, in the mechanics of 2-D curved in-plane shear cracks, a smooth curve, along which the crack orientation changes continuously, and an abrupt kink, across which it changes discontinuously, are not equivalent to each other. The discrepancy is illustrated by numerical results, and a set of conceptual models is used to demonstrate analytically how the equations that govern the crack mechanics have inherently distinct forms depending on whether the crack orientation changes continuously or abruptly across a bend, as long as one abides by the principles of linear elasticity theory. This has serious implications for the numerical treatment of a curved crack, which can be modelled as a chain of finite elements that are connected either smoothly or at abrupt kinks, the two methods producing different numerical outcomes. No similar paradox arises in the cases of anti-plane shear or open in-plane cracks.     

In situ stress measurements in a borehole close to the Nojima Fault

Abstract In situ stress was measured close to the fault associated with the 1995 Kobe Earthquake (Hyogo-ken Nanbu earthquake; January 1995; M 7.2) using the hydraulic fracturing method. The measurements were made approximately 2 years after the earthquake. The measured points were approximately 40 m from the fault plane at depths of about 1500 m. The maximum and the minimum horizontal compressive stresses were 45 MPa and 31 MPa, respectively. The maximum compressive stress and the maximum shear stress are very small in comparison with those of other seismically active areas. The azimuth of the maximum horizontal compressive stress was estimated from the observed azimuths of well bore breakouts at depths between 1400 m and 1600 m and was found to be N135° (clockwise). The maximum stress axis is perpendicular to the fault strike, N45°. These features are interpreted in terms of a small frictional coefficient of the fault. The shear stress on the fault was released and dropped almost to zero during the earthquake and it has not yet recovered. Zero shear stress on the fault plane resulted from the perpendicular orientation of one of the principal stress to the fault plane.     

Distribution of fault rocks in the fracture zone of the Nojima Fault at a depth of 1140 m: Observations from the Hirabayashi NIED drill core

Abstract Characteristics of deformation and alteration of the 1140 m deep fracture zone of the Nojima Fault are described based on mesoscopic (to the naked eye) and microscopic (by both optical and scanning electron microscopes) observations of the Hirabayashi National Research Institute for Earth Science and Disaster Prevention (NIED) drill core. Three types of fault rocks; that is, fault breccia, fault gouge and cataclasite, appear in the central part of the fault zone and two types of weakly deformed and/or altered rocks; that is, weakly deformed and altered granodiorite and altered granodiorite, are located in the outside of the central part of the fault zone (damaged zone). Cataclasite appears occasionally in the damaged zone. Six distinct, thin foliated fault gouge zones, which dip to the south-east, appear clearly in the very central part of the fracture zone. Slickenlines plunging to the north-east are observed on the surface of the newest gouge. Based on the observations of XZ thin sections, these slickenlines and the newest gouge have the same kinematics as the 1995 Hyogo-ken Nanbu earthquake (Kobe earthquake), which was dextral-reverse slip. Scanning electron microscopy observations of the freeze-dried fault gouge show that a large amount of void space is maintained locally, which might play an important role as a path for fluid migration and the existence of either heterogeneity of pore fluid pressure or strain localization.     

Classification of Japanese rivers by heavy metals in bottom mud

Bottom mud was collected from the upper and lower reaches of 92 rivers in Japan to determine the distribution of 0.5N-HCI-soluble heavy metals. The average concentrations of Cu, Zn, Pb, and Cd in the mud from the lower reaches were from two to three times higher than those in the upper reaches. Japanese rivers were classified according to the degree of heavy metal pollution by using the values of 0.5N-HCI-soluble metals in the lower reaches of rivers. The content of 0.5N-HCI-soluble heavy metals in the mud of the upper reaches was used as the standard value. The classification of rivers was made by a cluster analysis according to Euclidian distance. As a result, rivers in Japan could be classified into three groups based on the degree of metal pollution, and the classification was in agreement with the pollution index.     

Online hybrid test by internet linkage of distributed test‐analysis domains

Online hybrid tests (called the online tests), particularly when combined with substructuring techniques, are able to conduct large‐scale tests. An extension of this technique is to combine multiple loading tests conducted in remote locations and to integrate the tests with large numerical analysis codes. In this study, a new Internet online test system is developed in which a physical test is conducted in one place, the associated numerical analysis is performed in a remote location, and the two locations communicate over the Internet. To implement the system, a technique that links test and analysis domains located at different places is proposed, and an Internet data exchange interface is devised to allow data communication across Internet. A practical method that utilizes standard protocols implemented by operating systems for sharing files and folders is adopted to ensure stable and robust communication between remotely located servers that commonly protect themselves by strict firewalls. To combine the online test with a finite element program formulated in an incremental form and adopting an implicit integration scheme, a tangent stiffness prediction procedure is proposed. In this procedure, a tangent stiffness is estimated based on a few previous steps of experimental data. Using the system devised, tests on a base‐isolated structure were carried out. Here, the base‐isolation layer was taken as the tested part and tested in Kyoto University, Japan, and the superstructure was modelled by means of a finite element program and analysed in a computer located in Osaka University. A series of physical Internet online tests were carried out, with the integration time interval and the method of tangent stiffness prediction as the major parameters. The tests demonstrated that the Internet communication was very stable and robust, without malfunctions. The proposed method of stiffness prediction was effective even when the experimental hysteresis curves exhibited complex behaviour, thereby ensuring accurate simulation for the earthquake response of the entire structure. Copyright © 2005 John Wiley & Sons, Ltd.