Targeting the impactors: siderophile element signatures of lunar impact melts from Serenitatis

Highly siderophile element compositions of lunar impact melt breccias provide a unique record of the asteroid population responsible for large cratering events in the inner Solar System. Melt breccias associated with the 3.89 Ga Serenitatis impact basin resolve at least two separate impact events. KREEP-rich melt breccias representing the Apollo 17 poikilitic suite are enriched in highly siderophile elements (3.6-15.8 ppb Ir) with CI-normalized patterns that are elevated in Re, Ru and Pd relative to Ir and Pt. The restricted range of lithophile element compositions combined with the coherent siderophile element signatures indicate formation of these breccias in a single impact event involving an EH chondrite asteroid, probably as melt sheet deposits from the Serenitatis Basin. One exceptional sample, a split from melt breccia 77035, has a distinctive lithophile element composition and a siderophile element signature more like that of ordinary chondrites, indicating a discrete impact event. The recognition of multiple impact events, and the clear signatures of specific types of meteoritic impactors in the Apollo 17 melt breccias, shows that the lunar crust was not comprehensively reworked by prior impacts from 3.9 to 4.5 Ga, an observation more consistent with a late cataclysm than a smoothly declining accretionary flux. Late accretion of enstatite chondrites during a 3.8-4.0 Ga cataclysm may have contributed to siderophile element heterogeneity on the Earth, but would not have made a significant contribution to the volatile budget of the Earth or oxidation of the terrestrial mantle. Siderophile element patterns of Apollo 17 poikilitic breccias become more fractionated with decreasing concentrations, trending away from known meteorite compositions to higher Re/Ir and Pd/Pt ratios. The compositions of these breccias may be explained by a two-stage impact melting process involving: (1) deep penetration of the Serenitatis impactor into meteorite-free lower crust, followed by (2) incorporation of upper crustal lithologies moderately contaminated by prior meteoritic infall into the melt sheet. Trends to higher Re/Ir with decreasing siderophile element concentrations may indicate an endogenous lunar crustal component, or a non-chondritic late accretionary veneer in the pre-Serenitatis upper crust.     

Differentiation of an andesine-type anorthosite: The San Gabriel Suite

The San Gabriel anorthosite is an andesine-type anorthosite and has been investigated in order to test a model which postulates that the parental magmas of such anorthosites are andesite. Plagioclase in the anorthosites ranges from An₅₅ (mol per cent) to An₃₅ with a mode at An₄₉, in the diorites from An₅₂ to An₂₄ (mode An₃₆), and in the monzonites/ quartz-monzonites from An₂₇ to An₉ (mode An₂₁). No hiatus occurs in the compositional spectrum, suggesting that the sequence is derived from a common parent, with anorthosite accumulating first and quartz-monzonite last. The parent magma is constrained by having plagioclase of about An₅₅ on the liquidus, and by producing an oversaturated residual liquid. The sequence is in accord with published experimental observations on the fractional crystallization of a synthetic quartz-diorite (andesite), and is compatible with a model for the differentiation of andesine-type anorthosites from andesitic magmas.     

Land Use Diversification in the Elite Residential Sector of Quito,Ecuador*

It is generally assumed that older mansions in the elite residential sector of Latin American cities filter down to the middle classes once their residents migrate to modern suburban homes. Five land use maps compiled between 1975 and 1999 show that the elite residential sector of Quito (Mariscal Sucre) experienced a much more complex fate. Diffusion of nonresidential land uses from the city center and its associated spine transformed the residential neighborhood into a vibrant upper‐scale business district. Sophisticated businesses subsequently moved on to modern suburban facilities, but Mariscal Sucre became a major hub for business, nocturnal entertainment, and tourism. Diversification of land use in Mariscal Sucre confirms the Crowley hypothesis of complexity in Latin American urban land use patterns ( Crowley 1995 ).     

Age‐dating a star‐burst with GEMINI/CIRPASS observations of the core of M83

We present preliminary results from a set of near‐IR integral field spectroscopic observations of the central, star‐burst, regions of the barred spiral galaxy M83, obtained with CIRPASS on Gemini‐S. We present maps in the Paβ and [FeII] 1.257 μm emission lines which appear surprisingly different. We outline the procedure in which we will use Paβ emission line strengths and measures of CO absorption to determine the relative and absolute ages of individual star‐forming knots in the central kpc region of M83. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Palaeoecological,archaeological and historical data and the making of Devon landscapes. I. The Blackdown Hills

This paper presents the first systematic study of the vegetation history of a range of low hills in SW England, UK, lying between more researched fenlands and uplands. After the palaeoecological sites were located bespoke archaeological, historical and documentary studies of the surrounding landscape were undertaken specifically to inform palynological interpretation at each site. The region has a distinctive archaeology with late Mesolithic tool scatters, some evidence of early Neolithic agriculture, many Bronze Age funerary monuments and Romano‐British iron‐working. Historical studies have suggested that the present landscape pattern is largely early Medieval. However, the pollen evidence suggests a significantly different Holocene vegetation history in comparison with other areas in lowland England, with evidence of incomplete forest clearance in later‐Prehistory (Bronze?Iron Age). Woodland persistence on steep, but poorly drained, slopes, was probably due to the unsuitability of these areas for mixed farming. Instead they may have been under woodland management (e.g. coppicing) associated with the iron‐working industry. Data from two of the sites also suggest that later Iron Age and Romano‐British impact may have been geographically restricted. The documented Medieval land management that maintained the patchwork of small fields, woods and heathlands had its origins in later Prehistory, but there is also evidence of landscape change in the 6th–9th centuries AD. We conclude that the Blackdown Hills area was one of many ‘distinctive subregions’, which due to a combination of edaphic, topographic and cultural factors could qualify as an eco‐cultural region or ‘pays’. It is argued that the use of such eco‐culturally distinctive regions or pays can provide a spatial and archaeological framework for palaeoecology, which has implications for landscape research, designation and heritage management.     

Vanished diamondiferous cratonic root beneath the Southern Superior province: evidence from diamond inclusions in the Wawa metaconglomerate

We studied diamonds from a 2.697–2.700 Ga Wawa metaconglomerate (Southern Superior craton) and identified mineral inclusions of high-Cr, low-Ca pyrope garnet, low-Ti Mg-chromite, olivine (Fo₉₃), and orthopyroxene (En₉₄). The diamonds have δ¹³C of ?2.5 to ?4.0 ‰ and derive from the spinel-garnet and garnet facia of harzburgite. Geothermobarometry on non-touching, coexisting garnet-olivine and garnet-orthopyroxene pairs constrains the maximum geothermal gradient of 41 mW/m² for the Neoarchean and a minimum lithosphere thickness of 190 km. The depleted harzburgitic paragenesis equilibrated at a relatively cold geotherm suggests the presence of a pre-2.7 Ga diamondiferous cratonic root beneath the northern Wawa terrane or the Opatica terrane of the Southern Superior craton, i.e., beneath terranes identified as sources for the metaconglomerate diamonds. Geophysical surveys, geothermal data, and petrology of mantle xenoliths emplaced in the Proterozoic-Mesozoic trace evolution of the mantle thermal regime and composition from the Archean to present. The root was thinned down to 150 km by the Jurassic, when the mantle was heated to 41–42 mW/m². The diamondiferous root destruction was accompanied by more significant heating and was complete by 1.1 Ga in areas adjacent to the Midcontinent Rift. The geometry of the current high-velocity root and spatial correlations with boundaries of crustal terranes that docked to the nuclei of the Superior protocraton in the Neoarchean suggest that the root destruction in the Southern Superior may have been associated with tectonic erosion, craton amalgamation, and ensuing ingress of asthenospheric fluids.     

A distinct variant of high-titanium mare basalt from the Van Serg core,Apollo 17 landing site

Abstract— A fragment of basalt picked from the drive tube collected at Van Serg crater at the Apollo 17 landing site has a bulk chemistry more primitive than that of other high-titanium mare basalt groups collected at the site. The sample has a fine-grained olivine phyric, subophitic texture that is distinct from that of other high-titanium basalt samples. The grain size and texture suggest that the sample has a composition close to that of a magma. The crystallization sequence, with appearance of oxide minerals later than in other groups, and other petrographic features such as more-calcic plagioclase and early pigeonite rather than augite, are consistent with this sample representing a distinct variant of Apollo 17 high-titanium basalts. It is not related through closed-system igneous processes to any of the other mare basalt groups identified among Apollo 17 samples. Its characters emphasize the complexity of contemporaneous magma processes on the Moon and the heterogeneity of that part of the mantle that was melted.     

Avoidance of crude-oil contaminated sediment by the Australian seastar, Patiriella exigua (Echinodermata: Asteroidea)

This study attempted to determine whether Patiriella exigua, an Australian seastar, could detect and/or avoid oiled sediment when given an equal choice of unoiled sediment. The sediment was spiked once to produce one of three concentrations of oiled sediment used in the test chambers versus unoiled sediment. Behavioral observations were repeated over a 32 day period to test the effects of aging the oiled sediment. Results show that Patiriella exigua was capable of detecting oiled sediment and/or an oiled environment. Seastars avoided oiled sediment, with significantly higher numbers choosing either to reside on the clean sediment (p<0.05) or to travel up the glass sides of the tanks (p<0.001). Avoidance of oiled sediment increased with increasing sediment oil concentrations. Aging the oiled sediment decreased the oil content of the sediment and increased the number of seastars able to inhabit it (p<0.001). A potential narcotic effect of exposure to oiled sediment was observed.