Physical,chemical, and biological conditions associated with the early stages of the Lake Michigan vernal thermal front

An investigation of the thermal front in southeastern Lake Michigan during April 1988 revealed a dynamic physical, chemical, and biological environment. The front was observed approximately 4 km from the coast as a distinct gradient separating cold open-lake waters from warmer nearshore waters. Surface isotherms near the front were generally parallel to one another but skewed with respect to shore. Comparison between April 22 and 29 showed that the surface isothern pattern was modulated by wind stress. The pattern from April 29 showed signs of flow instabilities with horizontal scales of 1 km to 5 km. Surface drifter trajectories provided estimates of horizontal convergence at the fron which varied from 7×10^?6 s^?1 to 20×10^?6 s^?1. Inferred rates of downwelling, which ranged from 9.5 m d^?1 to 20.7 m d^?1, were sufficient to move a water parcel from the surface to the bottom in 2 to 6 d at the front. Convergent circulation was observed on both sampling dates despite contrasts in wind stress. Concentrations of chloride, soluble silica, and chlorophyll, which were always higher inshore, were 5% to 82% larger than offshore mean values. The aquatic environment just inshore of the thermal front was characterized by chlorphyll concentrations which exceeded 5.0 μg 1^?1 while concentrations offshore were between 1.0 μg 1^?1 and 2.0 μg 1^?1. A relatively uniform vertical structure in chlorophyll concentrations in the frontal zone was consistent with the observed convergence and inferred downwelling near the front.     

Gelification of victorian tertiary soft brown coal wood. II. Changes in chemical structure associated with variation in the degree of gelification

The gross chemical structures of xylites and gelified soft brown coal woods, Latrobe Valley, Victoria, Australia, as determined by solid state nuclear magnetic resonance spectroscopy, are compared with those of present-day wood-derived materials prepared from an angiosperm, Eucalyptus regnans, and a gymnosperm (conifer), Pinus radiata. Also examined are the changes in the gross chemical structures of soft brown coal woods with increase in their degree of gelification and the relationship between these changes and variations in their chemical composition and microscopic appearance.The Victorian xylites exhibit greater affinities with the present-day gymnosperm than the present-day angiosperm. The progressive removal of cellulose with increasing degree of gelification can be equated with an increase in huminite reflectance, elimination of humotelinite autofluorescence and changes in the relative proportions of the humotelinite submacerals. The lignin structure of xylite is also modified during the gelification process, including the progressive loss of methoxyl groups and evidence of minor oxidation.     

High latitude river runoff in a doubled CO2 climate

A global atmospheric model is used to calculate the monthly river flow for nine of the world's major high latitude rivers for the present climate and for a doubled CO₂ climate. The model has a horizontal resolution of 4° × 5°, but the model's runoff from each grid box is quartered and added to the appropriate river drainage basin on a 2° × 2.5° resolution. A routing scheme is used to move runoff from a grid box to its neighboring downstream grid box and ultimately to the mouth of the river. In a model simulation in which atmospheric carbon dioxide is doubled, mean annual precipitation and river flow increase for all of these rivers, increased outflow at the river mouths begins earlier in the spring, and the maximum outflow occurs approximately one month sooner due to an earlier snow melt season. In the doubled CO₂ climate, snow mass decreases for the Yukon and Mackenzie rivers in North America and for rivers in northwestern Asia, but snow mass increases for rivers in northeastern Asia.     

O, S, Sr, and Pb isotope variations in volcanic rocks from the Northern Mariana Islands: implications for crustal recycling in intra-oceanic arcs

Quaternary lavas from the Northern Mariana Islands have respective O- and S-isotope ranges ofδ¹⁸O = +5.7 to +6.6 (‰ SMOW) andδ³⁴S = +2.0to+20.7 (‰ CDT). Chemically evolved andesites and dacites with meanδ¹⁸O = +6.3 ± 0.2 are slightly enriched in¹⁸O with respect to unfractionated basalts of<53%SiO₂ with meanδ¹⁸O = +6.0 ± 0.1. This¹⁸O enrichment can be explained in terms of differentiation of parental mafic magmas havingδ¹⁸O values between +5.7 to +6.2‰ through closed-system crystal fractionation because the lavas from all nine islands of the arc define a coherentδ¹⁸OSiO₂ trend. The S-isotope composition of oxidized magmas is not modified extensively through the degassing of SO₂; therefore, the meanδ³⁴S value of ca. +11‰ for the Mariana lavas is considered to be representative of their source region.The enrichment of¹⁸O and³⁴S in Mariana Arc parental magmas relative to ocean floor basalts withδ¹⁸O ca. + 5.7‰ andδ³⁴S = ca.0.3‰ is attributed to the recycling of¹⁸O- and³⁴S-rich crustal components (sediment withδ¹⁸O = ca. + 25‰ and seawater sulfate withδ³⁴S = ca. +20‰ into the upper mantle source region for these arc magmas. This interpretation is consistent with enrichments of radiogenic Sr and Pb in the same lavas relative to ocean-floor basalts erupted either side of the arc, which are presumed to share a common upper mantle source. This enrichment is considered to reflect the mixing of two components, one having a typical upper mantle composition and the other having a more radiogenic character similar to that of western Pacific pelagic sediments.     

Evidence of multiple late-Wisconsin floods from glacial Lake Missoula in Badger Coulee,Washington

Catastrophic floods from glacial Lake Missoula entered the Pasco Basin in south-central Washington and backflooded its marginal valleys. Badger Coulee, one such valley, contains beds of fine-grained slackwater sediment deposited by these floods. The slackwater sediment contains two ash layers of the Mount St. Helens set S tephra, about 13,000 yr old. The ash was deposited on a ground surface developed atop slackwater sediment deposited during preash flooding. Evidence of the former ground surface includes the reworked ash, inferred trace fossils, stream and debris-flow deposits, slopewash and/or eolian sediment, and colluvium at the ash horizon. These features and the ash were buried by slackwater sediment deposited during postash flooding. Nonflood, subaerial deposits are not present atop other beds. Instead, beds commonly are reversely graded across “contacts,” suggesting that multiple beds were continuously deposited. The exposed beds thus record at least two late-Wisconsin floods, one preash, the other postash. The pre- and postash floods may be correlative with earlier-reported floods thought to have occurred 17,500-14,000 and 14,000–13,000 yr B.P., respectively.     

Exploitation of relaxation in cross-polarization nuclear magnetic resonance spectroscopy of fossil fuels

The judicious choice of dipolar dephasing times or carbon magnetization holding times has been shown to improve resolution in solid state nuclear magnetic resonance (NMR) spectra of complex materials. Signals from protonated and alkylated aromatic carbons are reduced to enhance resolution of aromatic oxygenated groups. Rapidly rotating methyl groups can be resolved from other aliphatic carbon types. These techniques were used to investigate the structure of a brown coal, xylite fractions of a brown coal, a bituminous coal, an oil shale and a solvent-refined coal. The results allow estimates of the fraction of aromatic carbon that is protonated in coal to be made, and demonstrate that methyl groups in coal rotate rapidly at room temperature.     

Fluctuations in US Freezing Rain Days

Freezing rain occurrences during a 50-year period, 1949/1950–1998/1999, derived from carefully examined records of 161 first-order stations distributed across the United States, were assessed for temporal fluctuations and trends. Classification of station fluctuations based on five 10-year periods revealed five unique distribution types in areas east of the Rockies. One of these five distributions, for stations located in the western Great Plains, experienced its greatest 10-year value at the end of the 50-year period. The other four regional distributions experienced their highest 10-year value in either of the first two 10-year periods. Nationally, the 10-year period when the greatest number of stations experienced their maximum value was 1949/1950–1958/1959, while the period when the greatest number of stations experienced their minimum value fell near the end of the 50-year record (1979/1980–1988/1989). The 50-year linear trends defined one region, the western Great Plains, with increasing values, while three areas of decreasing trend were identified; the Great Lakes, the eastern Ohio River valley, and southern New England. These analyses also indicate the need to examine and consider such time–space changes in the frequency of climate variables at various spatial scales when assessing weather risks and developing climate change scenarios.     

Stratospheric warming effects on the tropical mesospheric temperature field

Temperature observations at 20–90 km height and 5–15°N during the winter of 1992–1993, 1993–1994 and 2003–2004, from the Wind Imaging Interferometer (WINDII) and Microwave Limb Sounder (MLS) experiments on the Upper Atmosphere Research Satellite (UARS) satellite and the Sounding the Atmosphere using Broadband Emission Radiometry (SABER) experiment on the Thermosphere, Ionosphere, Mesosphere Energetics and Dynamics (TIMED) satellite are analyzed together with MF radar winds and UK Meteorological Office (UKMO) assimilated fields. Mesospheric cooling is observed at the time of stratospheric warming at the tropics correlative with stratospheric warming events at middle and high latitudes. Planetary waves m=1 with periods of 4–5, 6–8, 10 and 12–18 days are found to dominate the period. Westward 7- and 16-day waves at the tropics appear enhanced by stationary planetary waves during sudden stratospheric warming events.     

Jökulhlaup-related Ice Fracture and Supraglacial Water Release During the November 1996 Jökulhlaup, Skeiðarárjökull, Iceland

During the initial stages of the November 1996 jökulhlaup at Skeiðarárjökull, Iceland, floodwaters burst onto the glacier surface via a series of fractures. This supraglacial drainage led to the formation of a number of distinct ice surface depressions, one of which is investigated in detail. The morphology and structural characteristics of this feature are described, as well as the sedimentology of an associated assemblage of debris-filled fractures. This work suggests that debris-charged subglacial floodwaters travelled up to the glacier surface, where supraglacial flow occurred initially via an extensive network of fractures, orientated parallel to the glacier margin. Supraglacial discharge became progressively more focused into a series of discrete outlets, leading to the mechanical erosion of a number of depressions on the glacier surface. The associated transfer of subglacially derived floodwaters to high levels within the glacier resulted in the rapid entrainment of large volumes of sediment which may influence the patterns, processes and products of ice-marginal sedimentation in the future.