Redshifts and intrinsic time

We examine the hypothesis of the connection between quasars and galaxies from the point of view of the theory of nonlinear dynamics of highly complex systems. It is found that complexity and nonlinearity of systems which are informationally disconnected may lead to different intrinsic time-scales of the systems. Systems with different intrinsic time-scales age at different rates. This kind of aging can be measured by observing their different redshifts. On interpreting strongly differing redshifts of astrophysically closely related objects as informational redshifts, we are in the position to determine their maturity ratios which are measures of the different nonlinear stages of the objects on the cosmological time-scale.     

Geometry of the September 1971 eruptive fissure at Kilauea volcano,Hawaii

A three-dimensional model has been used to estimate the location and dimensions of the eruptive fissure for the 24–29 September 1971 eruption along the southwest rift zone of Kilauea volcano, Hawaii. The model is an inclined rectangular sheet embedded in an elastic half-space with constant displacement on the plane of the sheet. The set of best model parameters suggests that the sheet is vertical, extends from a depth of about 2 km to the surface, and has a length of about 14 km. Because this sheet intersects the surface where eruptive vents and extensive ground cracking formed during the eruption, this sheet probably represents the conduit for erupted lava. The amount of displacement perpendicular to the sheet is about 1.9 m, in the middle range of values measured for the amount of opening across the September 1971 eruptive fissure. The thickness of the eruptive fissure associated with the January 1983 east rift zone eruption was determined in an earlier paper to be 3.6 m, about twice the thickness determined here for the September 1971 eruption. Because the lengths (12 km for 1983 and 14 km for 1971) and heights (about 2 km) of the sheet models derived for the January 1983 and September 1971 rift zone eruptions are nearly identical, the greater thickness for the January 1983 eruptive fissure implies that the magma pressure was about a factor of two greater to form the January 1983 eruptive fissure. Because the September 1971 and January 1983 eruptive fissures extent to depths of only a few kilometers, the region of greatest compressive stress produced along the volcano's flank by either of these eruptive fissures would also be within a few kilometers of the surface. Previous work has shown that rift eruptions and intrusions contribute to the buildup of compressive stress along Kilauea's south flank and that this buildup is released by increased seismicity along the south flank. Because south flank earthquakes occur at significantly greater depths, i.e., from 5 to 13 km, than the vertical extent of the 1971 and 1983 eruptiv fissures, the depth of emplacement of these eruptive fissures cannot be the main factor in controlling the hypocentral depths of south flank earthquakes. Two possible explanations for the occurrence of south flank earthquakes in the depth range of 5–13 km are (1) a deeper pressure source, possibly related to deeper magma storage within the rift zone, and (2) a lowstrength region located between 5 and 13 km beneath Kilauea's south flank, possibly at the interface between oceanic sediments and the base of the Hawaiian volcanics.     

Radiation-induced defects in quartz. II. Single-crystal W-band EPR study of a natural citrine quartz

Single-crystal electron paramagnetic resonance (EPR) spectra of a natural citrine quartz without any artificial irradiation, measured at W-band frequencies (∼94 GHz) and temperatures of 77, 110 and 298 K, allow better characterization of three previously-reported Centers (#6, #7 and B) and discovery of three new defects (B′, C′ and G′). The W-band EPR spectra reveal that Centers #6 and #7 do not reside on twofold symmetry axes, contrary to results from a previous X-band EPR study. The W-band spectra also show that the previously reported Center B is a mixture of two defects (B and B′) with similar g matrices but different-sized ²⁷Al hyperfine structures. Center C′ has similar principal g values to the previously reported Center C but is distinct from the latter by a larger ²⁷Al hyperfine structure with splittings from 0.10 to 0.22 mT. Also, Center G′ has a similar g matrix to the previously reported Center G but a different ²⁷Al hyperfine structure with splittings from 0.41 to 0.53 mT. These spin-Hamiltonian parameters, together with observed thermal properties and microwave-power dependence, suggest that Centers #6 and #7 probably represent O₂³⁻ type defects. Centers B and B′ are probably superoxide radicals (O₂⁻) with the unpaired spin localized on the same pair of oxygen atoms around a missing Si atom but linked to a substitutional Al³⁺ ion each at different neighboring tetrahedral sites. Similarly, Centers G and G′ are most likely superoxide radicals with the unpaired spin localized on another pair of oxygen atoms around a missing Si atom and linked to a substitutional Al³⁺ ion each at different neighboring tetrahedral sites. Center C′ is probably an ozonide radical associated with a missing Si atom and linked to a substitutional Al³⁺ ion at the neighboring tetrahedral site. This study exemplifies the value of  high-frequency EPR for discrimination of  similar defect centers and determination of  small local structural distortions that are often difficult to resolve in conventional  X- and Q-band EPR studies.     

Windstorm of the eighteenth century in the Czech Lands: course,extent, impacts

Theoretical and Applied Climatology - This paper addresses the course, extent, and impacts of a windstorm that occurred on 20–21 December 1740, in the Czech Lands. The analysis is based on...     

History of earthquakes and vertical ground movement in Campi Flegrei caldera, Southern Italy: comparison of precursory events to the A.D. 1538 eruption of Monte Nuovo and of activity since 1968

The record of felt earthquakes around Naples Bay in southern Italy is probably complete since the mid-15th century. According to this record, intense earthquake swarms originating beneath Campi Flegrei, an explosive caldera located along the north coast of Naples Bay, have occurred only twice: (1) before the only historical eruption in Campi Flegrei in 1538; and (2) from mid-1983 to December 1984. Earthquake activity during the earlier period, which began at least a few years, and possibly as many as 30 years, before the 1538 eruption, damaged many buildings in the city of Pozzuoli, located near the center of Campi Flegrei. Minor seismic activity, which consisted of only a few felt earthquakes, occurred from 1970 to 1971. The second period of intense earthquake swarms lasted from mid-1983 to 1984, again damaging many buildings in Pozzuoli. Two periods of uplift along the shoreline within Campi Flegrei have also been noted since the mid-15th century: (1) during the few decades before the 1538 eruption; and (2) as two distinct episodes since 1968. Uplift of a few meters probably occurred a few decades before the 1538 eruption; uplift of as much as 3.0 m has occurred in Pozzuoli since 1968.These similarities strongly suggest that, for the first time in 440 years, the same process that caused intense local earthquake swarms and uplift in the early 1500's and led to an eruption in 1538, has again occurred beneath Campi Flegrei. Though no major seismicity or uplift has occurred since December 1984, because of the large amount of extensional strain accumulated during the past two decades, if a third episode of seismicity and rapid uplift occurs, it may lead to an eruption within several months after the resumption of activity.     

Early diagenetic influences on iron transformations in a freshwater lake sediment

Iron transformations in a calcium carbonate rich fresh-water sediment were studied by analyzing the relevant constituents of both interstitial water and solid matter. Analysis of interstitial water shows that the observed redox sequence NO⁻₃/NH⁺₄, MnO₂/Mn(II), FeOOH/Fe(II), SO²⁻₄/S(−II) is roughly in agreement with that predicted by the Gibbs Free Energy for the corresponding reactions. In contrast to marine sediments, these redox transitions occur in the uppermost sediments, i.e., at depths of 0–4 cm.

Deeper in the sedimentary sequence, the depth profile for dissolved iron exhibits a steady non-linear increase up to 400 μmol dm⁻³. In this anoxic zone, according to thermodynamic predictions, iron (II)-minerals such as iron sulfide, siderite, and vivianite should precipitate while Fe(III) oxides should be completely dissolved. However, microscopic analysis showed that Fe(III) oxides were present throughout the studied sediment. Furthermore, scanning electron microscope/energy dispersive spectroscopy analysis suggests the presence of iron sulfide could be verified but not that of siderite or vivianite. These observations indicate kinetic control of iron transformations.

We have investigated the importance of kinetic control of iron distribution in anoxic sediments using a diagenetic model for dissolved iron(II). A rough estimate of time scales for dissolution and precipitation rates was made by imposing limiting boundary conditions. Using the calculated rate constant, we established that more than 1000 years would be required for the complete dissolution of Fe(III) oxides, which is agreement with our observations and experimental data from the literature. Calculated precipitation rates of Fe(II) for a given mineral phase such as siderite yield a maximum value of 3 μg_(FeCO3) g⁻¹_{(dry sediment)} yr⁻¹. Such low rates would explain the absence of siderite and vivianite.

Finally, it can be inferred from the Mn_T/Fe_T ratio in the sediments that this ratio depends on the redox conditions of the sediment-water interface at the time of deposition. Thus, this ratio can be used as “paleo-redox indicator” in lacustrine sediments.     

Correlations among the reflectances of vitrinite, chitinozoans, graptolites and scolecodonts

Paleozoic marine sequences sampled in outcrops and wells of northeastern Gaspe Peninsula (Quebec Appalachians) yield kerogen composed in part of vitrinite and zooclasts (chitinozoans, scolecodonts and graptolites) on which reflectance measurements were made.The comparison between means of random measurements show that reflectance of chitinozoans is similar to that of telinite (vitrinite with a cellular texture) and that the reflectance of scolecodonts is significantly lower than that of telinite in the lower range of studied values. At higher reflectivities differences decrease but, at the end of the condensate gas zone reflectancea are not yet identical. As shown by previous studies, reflectance of graptolites is slightly less than that of telinite.Pyrobitumen reflectance is related to the lithology of the host-rock and no generalized correlation can be established between the reflectance of pyrobitumen and that of vitrinite.     

Age and evolution of scheelite-hosting rocks in the Felbertal deposit (Eastern Alps): U-Pb geochronology of zircon and titanite

U-Pb isotope analyses of zircon and titanite extracted from different rocks of the Felbertal scheelite deposit yield the following information: (1) An age of 593±22 Ma (2) is obtained for zircon crystallization in the scheelite-bearing matrix of an eruption breccia in the western ore field. (2) Discordant zircons from an elongated, up to 8 m thick scheelite-rich quartzite body in the eastern ore field give an upper intercept age of 544±5 Ma. This quartzite contains a laminated, fine-grained scheelite mineralization. (3) Zircons from a small granitoid intrusion of the western ore field reveal an age of 336±16 Ma, and concordant titanites document an age of 282±2 Ma for Variscan amphibolite facies metamorphism. Both events, granitoid intrusion and later metamorphism caused ore re-mobilization, including the formation of yellowish fluorescent (molybdo-) scheelite porphyroblasts. (4) For a narrow lamprop-1hyric dike in the western ore field, a concordant titanite age of 283±7 Ma is obtained. This age is identical with the titanites from the amphibolite facies metamorphic intrusion. Tiny scheelite grains were tapped by the dike from pre-existing scheelite mineralizations in the truncated host rocks. (5) Alpine metamorphism at 31±4 Ma did not exceed lowermost amphibolite facies conditions, and it caused scheelite re-mobilization on a minor scale only, producing bluish fluorescent porphyroblasts in quartz veinlets and veins, as well as bluish fluorescent scheelite rims around older scheelite grains. Moreover, crosscutting Alpine fissure fillings show bluish fluorescent, inclusion-free scheelite. (6) The preservation of Variscan titanites, the absence of Alpine titanite growth, and the large degree of Variscan scheelite re-mobilization demonstrate that amphibolite facies metamorphism in the Felbertal area has a Variscan age. This result clearly documents Variscan tectono-metamorphism to be the dominant event, instead of the hitherto surmised Alpine metamorphism. This multi-stage evolution of the Felbertal ore bodies corroborates the view that tungsten deposits are conditioned by several succeeding thermal events, leading to a series of stages that ultimately produce high-grade scheelite concentrations. These high-grade ores predominately occur along shear zones of different age, accompanied by the formation of large volumes of low-grade scheelite mineralizations along host rock foliations and quartz veinlets and veins.     

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