Dimensional analysis of two-phase flow including a rate-dependent capillary pressure–saturation relationship

The macroscopic modelling of two-phase flow processes in subsurface hydrosystems or industrial applications on the Darcy scale usually requires a constitutive relationship between capillary pressure and saturation, the P_c(S_w) relationship. Traditionally, it is assumed that a unique relation between P_c and S_w exists independently of the flow conditions as long as hysteretic effects can be neglected. Recently, this assumption has been questioned and alternative formulations have been suggested. For example, the extended P_c(S_w) relationship by Hassanizadeh and Gray [Hassanizadeh SM, Gray WG. Mechanics and thermodynamics of multiphase flow in porous media including interphase boundaries. Adv Water Resources 1990;13(4):169–86] proposes that the difference between the phase pressures to the equilibrium capillary pressure is a linear function of the rate of change of saturation, thereby introducing a constant of proportionality, the coefficient τ. It is desirable to identify cases where the extended relationship needs to be considered. Consequently, a dimensional analysis is performed on the basis of the two-phase balance equations. In addition to the well-known capillary and gravitational number, the dimensional analysis yields a new dimensionless number. The dynamic number Dy quantifies the ratio of dynamic capillary to viscous forces. Relating the dynamic to the capillary as well as the gravitational number gives the new numbers DyC and DyG, respectively. For given sets of fluid and porous medium parameters, the dimensionless numbers Dy and DyC are interpreted as functions of the characteristic length and flow velocity. The simulation of an imbibition process provides insight into the interpretation of the characteristic length scale. The most promising choice for this length scale seems to be the front width. We conclude that consideration of the extended P_c(S_w) relationship may be important for porous media with high permeability, small entry pressure and high coefficient τ when systems with a small characteristic length (e.g. steep front) and small characteristic time scale are under investigation.     

Measuring and monitoring persistent organic pollutants in the context of risk assessment

Due to growing concerns regarding persistent organic pollutants (POPs) in the environment, extensive studies and monitoring programs have been carried out in the last two decades to determine their concentrations in water, sediment, and more recently, in biota. An extensive review and analysis of the existing literature shows that whilst the vast majority of these efforts either attempt to compare (a) spatial changes (to identify "hot spots"), or (b) temporal changes to detect deterioration/improvement occurring in the environment, most studies could not provide sufficient statistical power to estimate concentrations of POPs in the environment and detect spatial and temporal changes. Despite various national POPs standards having been established, there has been a surprising paucity of emphasis in establishing accurate threshold concentrations that indicate potential significant threats to ecosystems and public health. Although most monitoring programs attempt to check compliance through reference to certain "environmental quality objectives", it should be pointed out that many of these established standards are typically associated with a large degree of uncertainty and rely on a large number of assumptions, some of which may be arbitrary. Non-compliance should trigger concern, so that the problem can be tracked down and rectified, but non-compliance must not be interpreted in a simplistic and mechanical way. Contaminants occurring in the physical environment may not necessarily be biologically available, and even when they are bioavailable, they may not necessarily elicit adverse biological effects at the individual or population levels. As such, we here argue that routine monitoring and reporting of abiotic and biotic POPs concentrations could be of limited use, unless such data can be related directly to the assessment of public health and ecological risks. Risk can be inferred from the ratio of predicted environmental concentration (PEC) and the predicted no effect concentration (PNEC). Currently, the paucity of data does not allow accurate estimation of PNEC, and future endeavors should therefore, be devoted to determine the threshold concentrations of POPs that can cause undesirable biological effects on sensitive receivers and important biological components in the receiving environment (e.g. keystone species, populations with high energy flow values, etc.), to enable derivation of PNECs based on solid scientific evidence and reduce uncertainty. Using the threshold body burden of POPs required to elicit damages of lysosomal integrity in the green mussel (Perna virvidis) as an example, we illustrate how measurement of POPs in body tissue could be used in predicting environmental risk in a meaningful way.     

Interactive effects of hypoxia and polybrominated diphenyl ethers (PBDEs) on microbial community assembly in surface marine sediments

Hypoxia alters the oxidation–reduction balance and the biogeochemical processes in sediments, but little is known about its impacts on the microbial community that is responsible for such processes. In this study, we investigated the effects of hypoxia and the ubiquitously dispersed flame-retardant BDE47 on the bacterial communities in marine surface sediments during a 28-days microcosm experiment. Both hypoxia and BDE47 alone significantly altered the bacterial community and reduced the species and genetic diversity. UniFrac analysis revealed that BDE47 selected certain bacterial species and resulted in major community shifts, whereas hypoxia changed the relative abundances of taxa, suggesting slower but nonetheless significant community shifts. These two stressors targeted mostly different taxa, but they both favored Bacteroidetes and suppressed Gammaproteobacteria. Importantly, the impacts of BDE47 on bacterial communities were different under hypoxic and normoxic conditions, highlighting the need to consider risk assessments for BDE47 in a broader context of interaction with hypoxia.     

Digital elevation models derived from airborne laser scanning point clouds: appropriate spatial resolutions for multi‐temporal characterization and quantification of geomorphological processes

Digital terrain models (DTMs) are a standard data source for a variety of applications. DTM differencing is also widely used for detection and quantification of topographic changes. While several investigations have been made on the accuracy of DTMs, calculated from different kinds of input data, little has been published on the error of DTM differencing, specifically for the quantification of geomorphological processes. In this study, an extensive, multi‐temporal set of airborne laser scanning (ALS) data is used to investigate the accuracy of topographic change calculations in a high alpine environment, caused by different geomorphic processes. Differences from DTMs with cell sizes ranging from 0.25 m to 10 m were calculated and compared to very accurate point‐to‐point calculations for a variety of processes and in nearby stable areas which show no significant surface changes. The representativeness of the DTM differences is then compared to the terrain slope and surface roughness of the investigated areas to show the influence of these parameters on the errors in the differences. Those errors are then taken into account for analyses of the applicability of different cell sizes for the investigation of geomorphic processes with different magnitudes and over different time periods. The analyses show that the error of DTM differences increases with lower point densities and higher roughness and slope values. The higher the error, the greater the differences between two elevation datasets have to be in order to quantify certain morphodynamic processes. Lower point densities and higher roughness and slope values require greater process rates or longer time intervals in order to obtain valid results. Copyright © 2013 John Wiley & Sons, Ltd.     

Floods and floodplain changes of the River Morava,the Strážnické Pomoraví region (Czech Republic) over the past 130 years

Abstract

The development of the River Morava floodplain has been influenced by several natural and anthropogenic factors. This paper focuses on variations in flood activity and channel changes of the River Morava in the region of Strá?nické Pomoraví (southeastern Czech Republic). Floods are analysed in terms of measured peak water stages, H_k (Rohatec, 1886–1920) and peak discharges Q_k (Rohatec/Strá?nice, 1921–2010) evaluated with respect to their N-year return period (H _N or Q_N ). The frequency of floods with Q_k ≥ Q ₂ reaches a significant maximum in March, followed by July. According to flood series compiled from 1881 onwards, their frequency peaked in the 1961–1970 decade with the most severe events occurring in July 1997 (Q ₁₀₀), March 2006 and June 2010 (Q ₅₀). During the study period the natural dynamics of the original anabranching channel patterns were significantly modified by human intervention, such as the abandonment of some anabranching channels, channel straightening, enlargement of the main channel, flood-dike construction, and the creation of the Ba?a shipping channel. These changes resulted in decreased frequency and a reduction in the extent of floodplain inundations compared to the period prior to channel modifications in the 1930s.

Citation Brázdil, R., Má?ka, Z., ?ezní?ková, L., Soukalová, E., Dobrovolný, P. & Matys Grygar, T. (2011) Floods and floodplain changes of the River Morava, the Strá?nické Pomoraví region (Czech Republic) over the past 130 years. Hydrol. Sci. J. 56(7), 1166–1185.     

Stable isotopes as a useful tool for revealing the environmental fate and trophic effect of open-sea-cage fish farm wastes on marine benthic organisms with different feeding guilds

Environmental fate of fish farm wastes (FFW) released from an open-sea-cage farm at Kat O, Hong Kong was examined by measuring carbon and nitrogen stable isotope (SI) ratios in selected benthic organisms collected along a 2000 m transect from the farm. Our results showed that FFW significantly influenced the energy utilization profile of consumers near the fish farm. Although nitrogen enrichment effect on δ15N was anticipated in biota near the farm, the predicted patterns did not consistently occur in all feeding guilds. Two species of suspension-feeders, which relied on naturally δ15N-depleted sources, were δ15N-enriched near the fish farm. In contrast, both species of benthic grazer and deposit-feeder, which relied on naturally δ15N-enriched algal sources, were δ15N-depleted under the influence of FFW. The SI signatures of biota can, therefore, serve as feasible biomarkers for FFW discharges only when the trophic structure of the receiving environment is fully elucidated.     

Permeability dependence of streaming potential coefficient in porous media

In theory, the streaming potential coefficient depends not only on the zeta potential but also on the permeability of the rocks that partially determines the surface conductivity of the rocks. However, in practice, it is hard to show the permeability dependence of streaming potential coefficients because of the variation of zeta potential from sample to sample. To study permeability dependence of streaming potential, including the effects of the variation of the zeta potential and surface conductance due to the difference in mineral compositions between samples, we perform measurements on 12 consolidated samples, including natural and artificial samples saturated with 7 different NaCl solutions to determine the streaming potential coefficients. The results have shown that the streaming potential coefficients strongly depend on the permeability of the samples for low fluid conductivity. When the fluid conductivity is larger than than 0.50 S/m for the natural samples or 0.25 S/m for the artificial ceramic samples, the streaming potential coefficient is independent of permeability. This behavior is quantitatively explained by a theoretical model.     

Die Felchen des Alpnachersees

In eutrophic Lake Alpnach, several forms of whitefish (Coregonus spp.) are found which show different growth rates. In recent years, immature whitefish of the fastgrowing form (local name: ‘Felchen’, here called ‘Grossfelchen’) have been caught in the nets used for fishing the slowgrowing form (local name: ‘Albeli’, here called ‘Kleinfelchen’). The aim of this study was to identify the different forms of coregonids and to determine their growth rate, age of first maturation, and relative frequency in the catch with gill nets of different mesh sizes. While the separation of the different forms on the basis of meristic characters proved unsatisfactory, the growth during the first year of life was found best suited for this purpose. For the whitefish fishery in Lake Alpnach, the fastgrowing form is regarded as the most important one. Due to eutrophication, the whitefish now show a considerably faster growth than about 40 years ago. In addition, they mature at a younger age than before. The consequences of these findings for the management of the whitefish stocks in Lake Alpnach are discussed.      

An Approximation of Inner Boundary Conditions for Wells Intersecting Highly Conductive Structures

Inner boundary conditions describe the interaction of groundwater wells with the surrounding aquifer during pumping and are associated with well-skin damage that limits water production and water derived from wellbore storage. Pumping test evaluations of wells during immediate and early time flow require assignment of inner boundary conditions. Originally, these concepts were developed for vertical well screens, and later transferred to wellbores intersecting highly conductive structures, such as preferential flow zones in fractured and karstic systems. Conceptual models for pumping test analysis in complex bedrock geology are often simplified. Classic analytical solutions generally lump or ignore conditions that limit or enhance well productivity along the well screen at the onset of pumping. Numerical solutions can represent well drawdowns in complex geological settings, such as karst systems, more precisely than many analytical solutions by accounting for additional physical processes and avoiding assumptions and simplifications. Suitable numerical tools for flow simulations in karst are discrete pipe-continuum models that account for various physical processes such as the transient hydraulics of wellbores intersecting highly conductive structures during pumping.     

The composition of settling particles in Lake Zürich

Settling particles in the Lake Zürich were collected at different depths. Water samples and particles have been analyzed for heavy metals and for organic matter elements. Samples were investigated by transmission electron microscopy, scanning electron microscopy, energy dispersive X ray and X ray. The elemental composition of the settling particles was found to be almost constant. Special remarks are made on iron and phosphate and on manganese. Manganese oxidizing microorganisms were found near the bottom of the lake.