Role of barotropic mechanism in the development of a monsoon depression: A MONEX study

The role of barotropic processes in the development of a monsoon depression, formed on 5 July 1979 during MONEX observational period, is studied by considering it as a quasi-geostrophic divergent barotropic instability problem of zonal flow of 3 July 1979 at 700 mb level. Numerical solutions are obtained by initial value approach. The preferred wave has a wavelength of 2750 km, an e-folding time of 4.3 days, a period of 6.5 days and an eastward phase speed of 4.9 ms^–1. Structure of preferred wave is found to be in good agreement with the observed horizontal structure of the depression at 700 mb. Poleward momentum transports are found to predominate over equatorward transports.Parts of this paper were presented at the National Symposium on Early Results of MONEX-1979. 9–12 March 1981, in New Delhi, India.     

The electrokinetic properties and flotation behaviour of apatite and calcite in the presence of dodecylamine chloride

Electrokinetic and flotation studies on apatites and calcite show that under certain conditions these minerals are floatable with dodecylamine chloride (DDACl) and the possible mode of DDACl adsorption is due to Coulombic and Van der Waals forces. The results indicate hemi-micelle formation of dodecylamine ions and suggest involvement of neutral molecular amine in the hemi-micelle structure, the critical hemi-micelle concentration being influenced by the nature of charge at the mineral surface.     

Effect of parallel electric field on electrostatic ion-cyclotron instability in anisotropic plasma in the presence of ion beam and general distribution function—Particle aspect analysis

Dispersion relation, resonant energy transferred, growth rate and marginal instability criteria for the electrostatic ion-cyclotron wave with general loss-cone distribution in low-β anisotropic, homogeneous plasma in the auroral acceleration region are discussed by investigating the trajectories of the charged particles. Effects of the parallel electric field, ion beam velocity, steepness of the loss-cone distribution and temperature anisotropy on resonant energy transferred and growth rate of the instability are discussed. It is found that the effect of the parallel electric field is to stabilize the wave and enhance the transverse acceleration of ions whereas the effect of steepness of loss-cone, ion beam velocity and the temperature anisotropy is to enhance the growth rate and decrease the transverse acceleration of ions. The steepness of the loss-cone also introduces a peak in the growth rate which shifts towards the lower side of the perpendicular wave number with the increasing steepness of the loss-cone.     

High- and low-affinity binding sites for Cd on the bacterial cell walls of Bacillus subtilis and Shewanella oneidensis

Bulk Cd adsorption isotherm experiments, thermodynamic equilibrium modeling, and Cd K edge EXAFS were used to constrain the mechanisms of proton and Cd adsorption to bacterial cells of the commonly occurring Gram-positive and Gram-negative bacteria, Bacillus subtilis and Shewanella oneidensis, respectively. Potentiometric titrations were used to characterize the functional group reactivity of the S. oneidensis cells, and we model the titration data using the same type of non-electrostatic surface complexation approach as was applied to titrations of B. subtilis suspensions by Fein et al. (2005). Similar to the results for B. subtilis, the S. oneidensis cells exhibit buffering behavior from approximately pH 3-9 that requires the presence of four distinct sites, with pK_a values of 3.3 ± 0.2, 4.8 ± 0.2, 6.7 ± 0.4, and 9.4 ± 0.5, and site concentrations of 8.9(±2.6) × 10⁻⁵, 1.3(±0.2) × 10⁻⁴, 5.9(±3.3) × 10⁻⁵, and 1.1(±0.6) × 10⁻⁴ moles/g bacteria (wet mass), respectively. The bulk Cd isotherm adsorption data for both species, conducted at pH 5.9 as a function of Cd concentration at a fixed biomass concentration, were best modeled by reactions with a Cd:site stoichiometry of 1:1. EXAFS data were collected for both bacterial species as a function of Cd concentration at pH 5.9 and 10 g/L bacteria. The EXAFS results show that the same types of binding sites are responsible for Cd sorption to both bacterial species at all Cd loadings tested (1-200 ppm). Carboxyl sites are responsible for the binding at intermediate Cd loadings. Phosphoryl ligands are more important than carboxyl ligands for Cd binding at high Cd loadings. For the lowest Cd loadings studied here, a sulfhydryl site was found to dominate the bound Cd budgets for both species, in addition to the carboxyl and phosphoryl sites that dominate the higher loadings. The EXAFS results suggest that both Gram-positive and Gram-negative bacterial cell walls have a low concentration of very high-affinity sulfhydryl sites which become masked by the more abundant carboxyl and phosphoryl sites at higher metal:bacteria ratios. This study demonstrates that metal loading plays a vital role in determining the important metal-binding reactions that occur on bacterial cell walls, and that high affinity, low-density sites can be revealed by spectroscopy of biomass samples. Such sites may control the fate and transport of metals in realistic geologic settings, where metal concentrations are low.     

Ocean model derived global surface circulation and Vertical velocity

In this article, the authors examine Sea surface temperature (SST), Sea surface circulation (SSC) and Vertical velocity (VV) fields from simulation of 25 layers coarse resolution Modular ocean model (MOM version 3.0) with prescribed wind forcing for the region 74.25°S to 65°N, 180°W-180°E. It is found that distribution of SST simulated by the model shows its consistency with the observed climatology. However, simulated SST in the areas of Arabian Sea, Bay of Bengal, Indonesian Throughflow (ITF) region and east of North America near equator exhibit slight warming with respect to observation, which may be due to model deficiency and forcing problems. Circulation features suggest that one of the strongest current viz. Antarctic circumpolar current (ACC) along with other major current systems viz. Gulf stream current, North and South Pacific current, Agulhas current, Labrador current, Canary current, etc are captured well by the model. In the Indian Ocean and other ocean basins, current patterns are well captured by the model simulation. Intense upwelling as well as downwelling areas is marked in the horizontal distribution of VV, which is as expected. VV show quasi-stagnant and convergent regions suggesting that floating materials may be accumulated during January/July in the real ocean and wind driven circulation may act as an important contribution for such transport of floating materials in these regions. An attempt has also been made to understand the fluctuations of the SST in NINO 3.4 region during the period of model simulation using SST anomalies.     

Geochemical signatures of Mesoproterozoic siliciclastic rocks of the Kaimur Group of the Vindhyan Supergroup,Central India

The Upper Kaimur Group of the Vindhyan Supergroup in Central India, primarily consists of three rock types-DhandraulSandstone, Scarp Sandstone and Bijaigarh Shale. Mineralogically and geochemically, they are quartz arenite, sublitharenite to litharenite and litharenite to shale in composition, respectively. The A-CN-K ternary plot and CIA and ICV values suggest that the similar source rocks suffered severe chemical weathering, under a hot-humid climate in an acidic environment with higher P _{CO 2}, which facilitated high sediment influx in the absence of land plants. Various geochemical discriminants, elemental ratios like K₂O/Na₂O, Al₂O₃/TiO₂, SiO₂/MgO, La/Sc, Th/Sc, Th/Cr, Gd_N/Yb_N and pronounced negative Eu anomalies indicate the rocks to be of post-Archean Proterozoic granitic source, with a minor contribution of granodioritic input, in a passive margin setting. The sediments of the Upper Kaimur Group were probably deposited in the interglacial period in between the Paleoproterozoic and Neoproterozoic glacial epochs.     

An artificial neural network-based snow cover predictive modeling in the higher Himalayas

With trends indicating increase in temperature and decrease in winter precipitation, a significant negative trend in snow-covered areas has been identified in the last decade in the Himalayas. This requires a quantitative analysis of the snow cover in the higher Himalayas. In this study, a nonlinear autoregressive exogenous model, an artificial neural network （ANN）, was deployed to predict the snow cover in the Kaligandaki river basin for the next 30 years. Observed climatic data, and snow covered area was used to train and test the model that captures the gross features of snow under the current climate scenario. The range of the likely effects of climate change on seasonal snow was assessed in the Himalayas using downscaled temperature and precipitation change projection from - HadCM3, a global circulation model to project future climate scenario, under the AIB emission scenario, which describes a future world of very rapid economic growth with balance use between fossil and non-fossil energy sources. The results show that there is a reduction of 9% to 46% of snow cover in different elevation zones during the considered time period, i.e., 2Oll to 2040. The 4700 m to 52oo m elevation zone is the most affected area and the area higher than 5200 m is the least affected. Overall, however, it is clear from the analysis that seasonal snow in the Kaligandaki basin is likely to be subject to substantialchanges due to the impact of climate change.     

Application of dried plant biomass as novel low-cost adsorbent for removal of cadmium from aqueous solution

Heavy metals are a threat to human health and ecosystem. These days, great deal of attention is being given to green technologies for purification of water contaminated with heavy metal ions. Biosorption is one among such emerging technologies, which utilizes naturally occurring waste materials to sequester heavy metals from wastewater. Cadmium has hazardous impact on living beings; therefore, its removal through green and economical process is an important task. The aim of the present study was to utilize the locally available Portulaca oleracea plant biomass as an adsorbent for cadmium removal from aqueous solution. The biomass was obtained after drying and grinding the portulaca leaves and stem. No chemical treatment was done on the adsorbent so that it remained green in a true sense. Batch experiments were performed at room temperature. The critical parameters studied were effects of pH, contact time, initial metal ion concentration and adsorbent dose on the adsorption of cadmium. The maximum adsorption was found to be 72 %. The kinetic data were found to best fit the pseudo-second-order equation. High adsorption rates were obtained in the initial 45 min, and adsorption equilibrium was then gradually achieved in about 100 min. Adsorption increased with increase in pH for a range 2 and 6. The equilibrium adsorption results closely followed both the Langmuir and Freundlich isotherms. The values of constants were calculated from isotherms. Results indicated that portulaca plant biomass could be developed as a potential material to be used in green water treatment devices for removal of metal ions.     

Effect of metal content on chlorophyll fluorescence and chlorophyll degradation in lichen Pyxine cocoes (Sw.) Nyl.: a case study from Uttar Pradesh,India

The major aim of the present study is to identify the relationship of physiological parameters of the photosynthetic system with the elemental content of the naturally growing lichen Pyxine cocoes. The epiphytic foliose lichen P. cocoes was used as biomonitoring indicator and effect of atmospheric pollutants on physiological integrity was examined. Potential quantum yield of Photosystem II (fluorescence ratio Fv/Fm), chlorophyll degradation ratio and quantitative estimation of Al, As, Cd, Cr, Cu, Pb, Fe and Zn contained in the lichen thallus were ascertained. Statistical analysis revealed significantly positive correlations between Fv/Fm and element contents (Al and Cr). The chlorophyll degradation as well as alteration in the pigment content was found to be the most sensitive parameters to assess the vitality of lichen thallus against polluted environment. The species accumulated higher amounts of elements (Al, As, Cu, Fe and Zn) in the polluted sites as compared to the non polluted sites. It was also evident from this study that vehicular emission played a significant role in the release of elements as pollutants in the surrounding environment. The effectiveness of this lichen could be further investigated by comparing this species with other biomonitors.     

Remote Sensing based assessment of glacial lake growth on Milam glacier,Goriganga basin,Kumaon Himalaya

The climate change of the twentieth century had an evident effect on glacier environments of the Himalaya. Temporal images of Indian Remote Sensing satellites provide an opportunity to monitor the recession of glacier and development of glacial lakes in the Himalayan cryosphere with a cost to time benefit ratio. The recession of Milam glacier and subsequent growth of a proglacial lake near the snout was analysed using Resourcesat-1 and Resourcesat-2 data. The recession of 480 m during 2004 to 2011 and growth of 47 epiglacial ponds over Milam glacier shows the glacier is in a state of imbalance and losing the ice by downwasting.