P–T conditions of mineralization in the Jonnagiri granitoid-hosted gold deposit, eastern Dharwar Craton, southern India: Constraints from fluid inclusions and chlorite thermometry

Gold mineralization at Jonnagiri, Dharwar Craton, southern India, is hosted in laminated quartz veins within sheared granodiorite that occur with other rock units, typical of Archean greenstone–granite ensembles. The proximal alteration assemblage comprises of muscovite, plagioclase, and chlorite with minor biotite (and carbonate), which is distinctive of low- to mid-greenschist facies. The laminated quartz veins that constitute the inner alteration zone, contain muscovite, chlorite, albite and calcite. Using various calibrations, chlorite compositions in the inner and proximal zones yielded comparable temperature ranges of 263 to 323 °C and 268 to 324 °C, respectively. Gold occurs in the laminated quartz veins both as free-milling native metal and enclosed within sulfides. Fluid inclusion microthermometry and Raman spectroscopy in quartz veins within the sheared granodiorite in the proximal zone and laminated auriferous quartz veins in inner zone reveal the existence of a metamorphogenic aqueous–gaseous (H₂O–CO₂–CH₄ + salt) fluid that underwent phase separation and gave rise to gaseous (CO₂–CH₄), low saline (~ 5 wt.% NaCl equiv.) aqueous fluids. Quartz veins within the mylonitized granodiorites and the laminated veins show broad similarity in fluid compositions and P–T regime. Although the estimated P–T range (1.39 to 2.57 kbar at 263 to 323 °C) compare well with the published P–T values of other orogenic gold deposits in general, considerable pressure fluctuation characterize gold mineralization at Jonnagiri. Factors such as fluid phase separation and fluid–rock interaction, along with a decrease in f(O₂), were collectively responsible for gold precipitation, from an initial low-saline metamorphogenic fluid. Comparison of the Jonnagiri ore fluid with other lode gold deposits in the Dharwar Craton and major granitoid-hosted gold deposits in Australia and Canada confirms that fluids of low saline aqueous–carbonic composition with metamorphic parentage played the most dominant role in the formation of the Archean lode gold systems.     

Harmonics of low-amplitude anisotropic wave trains in cosmic rays

The purpose of this work is to investigate the first three harmonics of low-amplitude anisotropic wave trains (LAEs) of cosmic ray intensity and their association with solar and heliospheric parameters. The significant behaviour of these events is that the amplitude remains low for the first harmonic and high for the second/third harmonics, whereas direction of the anisotropy shift is towards earlier hours for the first harmonic and towards later hours for the second/third harmonic compared to annual average anisotropy. The first two harmonics are found to correlate well with the solar activity cycle during these LAEs. The amplitude and the direction of the first two harmonics do not show any significant association with the polarity change of the Bx/By component of the interplanetary magnetic field during LAEs. However, the third harmonic (amplitude and phase) shows some positive correlation with the Bx and negative correlation with the By component. The occurrence of LAEs is dominant for the positive polarity of Bx and the negative polarity of By. The occurrence of LAEs is dominant during the period of average solar wind velocity but their occurrence during high-speed solar wind streams cannot be overlooked. The frequency of occurrence of these LAEs is more during co-rotating streams.The amplitude of first and second harmonic shows deviations for different values of geomagnetic activity index Ap. However, the amplitude of second harmonic and direction of all the three harmonics do not show any significant association with the Ap-index. The Ap-index consistently remains in the range 14?Kp?31 during these events.The amplitude of first and third harmonic and the direction of first harmonic show deviations for different values of proton density. However, the amplitude of the second harmonic and the direction of the second and third harmonics do not show any significant association with proton density. The occurrence of LAEs is dominant when proton density remains ?20. The cosmic ray intensity during LAEs has good anti-correlation with interplanetary magnetic field strength (B) and its Bx component, whereas it shows a good correlation with its By component. However, it shows significant anti-correlation with sunspot number, the product (R×V) and (R×B).     

Adsorption of Zinc using Tea Factory Waste: Kinetics,Equilibrium and Thermodynamics

In India, the annual production of tea is ca. 857,000 tonnes, which is 27.4% of the total world production. The amount of tea factory waste (TFW) produced per annum after processing is ca. 190,400 tonnes. TFW can be used as a low cost adsorbent for the removal of toxic metals from the aqueous phase. An investigation was carried out to study the feasibility of the use of TFW as an adsorbent for the removal of the heavy metal, zinc. Equilibrium, kinetic and thermodynamic studies were reported. The straight line plot of log (q_e–q) versus time t for the adsorption of zinc shows the validity of the Lagergren equation. The various steps involved in adsorbate transport from the solution to the surface of the adsorbent particles were dealt with by using a Weber‐Morris plot, q_e versus t^0.5 for the TFW. The rate controlling parameters, k_id,1 and k_id,2, were determined and it was found that the macro‐pore diffusion rate was much larger than micro‐pore diffusion rate. A batch sorption model, which assumes the pseudo‐second‐order mechanism, was used to predict the rate constant of sorption, the equilibrium sorption capacity and the initial sorption rate with the effect of initial zinc (II) ion concentration. Equilibrium data obtained from the experiments were analyzed with various isotherms, i. e., Freundlich, Langmuir, Redlich‐Peterson and Tempkin. The adsorption equilibrium was reached in 30 min and the adsorption data fitted well to all models. The maximum adsorption capacity of TFW for zinc (II) ions was determined to be 14.2 mg/g. The capacity of adsorption on Zn(II) increased with increasing temperatures and pH. The maximum uptake level of zinc was observed at pH of 4.2. The various thermodynamic parameters, i. e., ΔG°, ΔH° and ΔS°, were estimated. The thermodynamics of the zinc ion/TFW system indicated a spontaneous, endothermic and random nature of the process. The results showed that the TFW, which has low economical value, is a suitable adsorbent for the removal of zinc (II) ions from aqueous solutions.     

Coda Q Estimates in the Andaman Islands Using Local Earthquakes

The attenuation property of Andaman Island has been investigated analyzing coda waves from 57 local earthquakes in the magnitude range of 2.0–4.9, using the single backscattering model. These earthquakes waveforms, recorded on five broadband seismographs sited over the island from north to south during Nov. 2003 to March 2004, have been used to calculate the frequency dependent Coda Q (Q _c ) applying the time domain coda-decay method. The Coda Q, computed at central frequencies from (0.5–12) Hz and five-lapse time windows from 40 to 80 s, progressively increases from 105 f ^0.88 in the north Andaman to 135 f ^0.79 in the south Andaman with an average of 119 f ^0.80. The average Q _c values vary from 75 ± 42 at 0.5 Hz to 697 ± 54 at 12 Hz central frequency for 40 s lapse time window, while for 80 s lapse time window its variation is from 117 ± 38 at 0.5 Hz to 1256 ± 115 at 12 Hz. The Q _c estimated at different lapse times manifests a significant variation from 122f ^0.75 to 174f ^0.73, corresponding to lapse time window lengths of 40 and 80 s, respectively. The variation of Q _c with frequency, lapse time and also with the location of seismograph reflects the marked structural and compositional inhomogeneity with depth along the Andaman Islands. These observations are well correlated with the seismicity pattern and distinct high angle subduction beneath the island.     

Transverse Dispersion of a Kinetically Sorbing Solute

A recursion formulation for the transverse spreading of a solute is developed, and under conditions of steady flow in a stratified aquifer, the transport of a linearly sorbing solute undergoing nonequilibrium sorption is studied. The effect of spatial variability in the velocity field and the sorption kinetics are modeled to see the combined effect of the two processes on the spreading of the solute injected at a point in the aquifer. The main result of this work is a transport model based on a discrete formulation that includes local dispersion and leads to nonasymptotic behavior in the spreading of the plume in a direction normal to the mean flow velocity.     

Effects of convective scale downdrafts on the rainfall simulation in NCAR-CAM3

In this work, an attempt is made to systematically evaluate the effect of convective scale downdrafts on the model-simulated rainfall, in both aqua- and actual-planet frameworks, using the NCAR CAM3. From the aqua-planet simulations, it was found that there is a reduction in the total rainfall (TRF) with increase in the intensity of downdrafts, which is primarily attributed to the reduction in the deep convective component (DRF). However, with stronger downdrafts, the shallow convective and the large-scale components (SRF and LRF, respectively) are found to increase. The reduction in DRF is due to the increased evaporation of convective precipitation within the downdrafts. It is found that, with intense downdrafts, there is an increase in relative humidity throughout the troposphere, due to the combined effect of both moisture and temperature. There is an overall increase in specific humidity of the atmosphere with stronger downdrafts, excepting at around the 900-hPa level. In addition, there is a reduction in temperature throughout the troposphere, primarily due to the reduction in the overall temperature tendency due to moist processes and that due to the radiative processes. The changes in the radiative forcing are found to be primarily due to a significant increase in the low cloud fraction with strong downdrafts. In the actual-planet framework, it is seen that, with strong convective downdrafts, there is a reduction in TRF and DRF and a corresponding increase in SRF and LRF, similar to the results obtained from the aqua-planet simulations. The vertical structures of the thermodynamic variables (RH, q, and T) show similar sensitivity to the downdraft intensity as that seen in the aqua-planet framework. Sensitivity of frequency and intensity of model-simulated rainfall to the downdraft intensity was also analyzed, and it was seen that there were significant differences in the frequency distribution of rainfall. It was seen that, with an increase in downdraft intensity, there is an increase in the frequency of light rain (1–10?mm/day) for TRF with a corresponding reduction in all other rainfall bins. A similar behavior was seen for the DRF as well, while the SRF and LRF components showed an increase in rainfall accumulation in all the bins. In addition, the impact of convective downdrafts on the mean spatial pattern of rainfall is also analyzed, for the DJF and JJA periods (boreal winter and summer, respectively). For the DJF period, with strong downdrafts, it was seen that grossly over the whole domain, there were a reduction in DRF and an increase in SRF and LRF. In contrast, during JJA, although a major part of the domain showed a reduction in DRF, there were regions like western Arabian Sea and the Somali coast with increase in DRF with intense downdrafts. The SRF and LRF components, however, show a spatially homogeneous increase over almost the entire domain with increase in downdraft intensity.     

The evolution of the Palim granite in the Bastar tin province, Central India

Summary The Palim granite, hosted by the metasedimentary country rocks in the Bastar tin province, is a heterogeneous pluton that comprises hornblende granite, biotite granite and two-mica granite. Spherical inhomogeneous surmicaceous enclaves occur within the granites with coarse grained cores of muscovite mantled by finer muscovite-quartz-biotite (± sillimanite) rims. Geochemical features imply that the granites are highly evolved and geochemically distinct. Petrographic and geochemical considerations point towards a transition from metaluminous I-type hornblende-bearing granite in the south to peraluminous volatile-enriched S-type like lithologies (biotite and two-mica granites) towards north. Modeling of highly incompatible elements such as Nb and Cs, implies 31 to 33% assimilated fractional crystallization of a melt with an initial composition close to that of the hornblende granite to form the two-mica granite. Hornblende geobarometry, plagioclase-hornblende thermometry (in hornblende granite) and phengite barometry (in two-mica granite), yield P-T estimates of 5–7 kb/725°–760 °C, and 6 kb/700 °C, respectively. The study further implies that a genetic link exists between granite magmatism and the formation of tin pegmatites in the region. The preponderance of peripheral pegmatites to the north-east of the Palim granite is regarded a result of outward crystal-melt fractionation and tectonic tilting of the pluton. Received October 21, 1999; revised version accepted December 12, 2000