THE RESEARCH ON THE DISTRIBUTION AND FORMS OF HEAVY METALS IN THE XIANGJIANG RIVER SEDIMENTS

In this paper, the contents and various forms of Cd, Cu, Zn and Pb in the sediments of the Xiangjiang River have been investigated. The presentation of this paper focuses on the various forms and characteristics of the heavy metals in the column sediments at Xiawan Port of Zhuzhou, which has been severely polluted by a metallurgical plant.The forms of the heavy metals discussed in this paper are: The concentration of the exchangeable forms of Cd, Cu, Zn and Pb, in the forms of carbonates and Fe/ Mn oxide in water, the combination of Cu with organic matter and form, and the proportion of the residue form at each section have been studied.     

大中小震与抗震设防标准

讨论二级抗震设计与超越概率标准、概率法与综合概率法给出的3个水平的地震动的关系. 通过危险性分析的实际例子,讨论了50年超越概率2%、10%和63%的地震动,即大震、中震和小震的相对大小关系,并提出抗震设防标准的确定方法.      

Kokchetavite: a new potassium-feldspar polymorph from the Kokchetav ultrahigh-pressure terrane

Kokchetavite, a new polymorph of K-feldspar (KAlSi₃O₈), has been identified as micrometer-size inclusions in clinopyroxene and garnet in a garnet-pyroxene rock from the Kokchetav ultrahigh-pressure terrane, Kazakhstan. Kokchetavite has a hexagonal structure with a =5.27(1) Å, c=7.82(1) Å, V=188.09 ų, Z=1, and is found to be associated with phengite + /-cristobalite (or quartz) + siliceous glass ± phlogopite/titanite/calcite/zircon, occurring as multi-phase inclusions in clinopyroxene and garnet. It is concluded that kokchetavite could not be an exsolution phase in host minerals. Instead, it might be metastably precipitated from an infiltrated K-rich melt during rock exhumation. Alternatively, although less likely, kokchetavite might be derived from dehydration of K-cymrite, which, in turn, was formed at high pressures. In either case, kokchetavite is a metastable polymorph of K-feldspar.     

塔里木盆地晚泥盆世-早石炭世东河砂岩沉积相

东河砂岩是塔里木盆地主要的勘探目的层和产油层之一。经过多年艰苦勘探和多学科综合研究,现已认识到东河砂岩为晚泥盆世晚期至早石炭世早期海平面上升背景下沉积的一套海侵底砂（砾）岩,在盆地范围内是一个明显的穿时沉积体。东河砂岩以滨浅海相陆源碎屑沉积占优势,局部发育海陆过渡相陆源碎屑沉积。根据盆地内100多口井资料的岩石学特征、沉积特征以及其它指相标志的综合分析,在东河砂岩中识别出滨岸、河口湾、辫状河三角洲以及冲积扇等不同的沉积相类型,其中高能碎屑滨岸相最重要,分布最广。东河砂岩沉积早期和中期,盆地主要为高能碎屑滨岸相和碎屑陆棚相沉积,末期海侵达到最大,盆地内为碳酸盐台地沉积,而轮南及盆地北部一带受物源区的影响,出现混积滨岸和碎屑滨岸沉积。东河砂岩明显具有填平补齐的沉积特征,其砂体厚度在缓坡处减薄、陡坡处增厚、遇孤岛减薄或尖灭,这些沉积特征为形成东河砂岩非构造圈闭奠定了良好的地质基础。满加尔、轮南、塔中、玛扎塔格以及草湖地区都有可能找到该类油气藏（田）,展示了东河砂岩非构造圈闭的良好勘探前景。     

2011年夏季南大洋普里兹湾颗粒态生物硅的分布与变化特征

利用中国第27次南极科学考察期间获得的颗粒物样品,对南大洋普里兹湾海域水体中颗粒态生物硅的含量及分布特征进行了初步研究,分析了该海域颗粒态生物硅与营养盐、浮游植物以及颗粒有机碳之间的关系,同时结合历史数据对比了颗粒态生物硅的年际变化情况。研究结果显示：在2011年夏季普里兹湾表层水体中颗粒态生物硅含量在0.76-19.72μmol/ dm3之间变化,平均为6.06±4.55μmol/ dm3。在表层水体中的分布趋势是67°S以南的湾内区域颗粒态生物硅含量明显高于67°S以北的湾外区域,最大值出现在普里兹湾陆架区。在垂向分布上,P3断面水体中颗粒态生物硅含量随深度增加而减少。根据不同年份即24,25,26,27次南极科学考察期间获取的数据对比分析显示,颗粒态生物硅含量虽存在一定的年际差异,但是在普里兹湾的分布趋势基本一致。颗粒态生物硅含量的变化特征与硅酸盐相反与叶绿素a、颗粒有机碳相似。     

南大洋海冰影像地图投影变换与瓦片切割应用研究

南大洋海冰分布是南极考察过程中影响破冰船航行的重要因素,也是南极研究的重要内容之一。目前国际上不同机构发布的南大洋海冰分布图,大多是球面投影,不能直接用于主流的瓦片地图发布。将极方位立体投影海冰图转换为目前主流的网络墨卡托投影地图,并利用合适的图像重采样方法,按照不同级别比例尺进行瓦片切割和编号存储,最终实现海冰影像地图的发布共享是本文的主要研究内容。笔者对不同的图像重采样方法进行了比较,分析了最邻近点采样方法、双线性内插和双三次卷积重采样方法的优劣,针对本文的研究优选双线性内插方法进行影像地图瓦片的切割,并最终叠加融合在Google地图上,实现了Google底图、准实时海冰影像图与破冰船走航位置的集成显示,为雪龙船的冰区航行提供了重要的数据支撑。     

Human-induced change in sedimentary trace metals and phosphorus in Chaohu Lake,China, over the past half-millennium

We present a sedimentary geochemical record of human perturbation in the watershed and related changes in trace metals (Cr, Ni, Zn and Pb), phosphorus and abundant rock-forming elements (Al, Fe, K, Mg, etc.) in Chaohu Lake over the past 500 years, a period spanning historical agricultural expansion and modern economic development. The record exhibited a stable terrestrial detrital input to Chaohu Lake before ca. 1540 AD, a period with less human perturbation of the watershed, which resulted in low and constant values of trace metals and phosphorus (TP) concentrations as well as Al, Fe, K, Mg, fine silt (<16 μm), the chemical index of alteration (CIA) and K/Na ratio. Two periods of successive marked increases in Al, Fe, K, Mg, fine silt, chemical index of alteration (CIA) and K/Na ratio occurred after ca. 1540 AD and 1950 AD. The former period apparently resulted from enhanced well-weathered topsoil erosion in the watershed related to the expansion of arable land, and the latter resulted from further enhancement of human perturbation in the watershed during the modern period. Concentrations of trace metals and TP were positively correlated with that of the rock-forming elements and fine silt. Trace metal pollution was limited during 1540–1950 AD, according to the low enrichment factors (EFs = 0.8–1.1), when an increase in trace metal concentrations was also linked to changes in detrital input. In addition to detrital regulation, pollution also contributed to an increase in TP concentrations (average EF 1.4) during 1540–1950 AD and the average accumulation rate of anthropogenic phosphorus was 87.3 mg m⁻² a⁻¹. Anthropogenic phosphorus increased further and Pb and Zn pollution also occurred after 1950 AD, reaching maximum values after 1980 AD, when the average accumulation rates of anthropogenic Zn, Pb and phosphorus (mainly in the form of NaOH-P) were 242.2, 43.3 and 811.8 mg m⁻² a⁻¹, respectively. The increase in phosphorus pollution in recent decades is probably from the domestic sewage sources of Hefei City and non-point sources related to agricultural utilization of commercial fertilizer, whereas Zn and Pb pollution is probably derived mainly from industrial sources of Hefei City, as deduced from their spatial variations in the sediments of the river mouths.     

黄土高原一次β中尺度大暴雨特征及成因分析

利用NCEP／NCAR逐日6h分析资料和常规观测资料,分析了2011年2月25日一28日山西连续降雪天气过程（以下简称2．25降雪）。①2．25降雪过程经历了三个阶段：2月25日为回流降雪阶段,26日一27日为倒槽冷锋与回流降雪共同影响降雪阶段,28日为低空切变线影响降雪阶段。②2．25降雪过程涵盖了华北地区大到暴雪的三个类型：回流类降雪、倒槽冷锋类降雪、低空切变线类降雪。③通过温湿场分析得出,对于低空切变线类降雪,对流层中层的湿核对降雪的开始有一定的指示意义。降雪未开始之前对流层中层有湿核,随着时间的推移,湿核向低层扩展,整个对流层中低层变为高湿区,降雪开始。当对流层中层变为干区,并向低层扩展,降雪过程结束。对于回流类降雪,低层回流对回流降雪起到冷垫的作用。④通过涡度场分析得出,对流层低层的负绝对涡度中心对其东侧的降水有指示意义,如果其东侧对流层低层配合有正涡度核,降雪强度较大,维持时间较长。⑤地面层出现的负绝对涡度中心说明近地面层有小高压系统的存在,这是因为低层回流冷垫作用形成的孤立小高压体。⑥28日降雪维持机制是条件性对称不稳定。     

天津武清地区云凝结核变化特征

利用2009年11—12月在天津武清气象局测量的云凝结核(CCN:Cloud Condensation Nuclei)浓度资料以及气溶胶数谱分布的观测资料,分析了武清地区在不同过饱和度(0.1%～1.0%)下云凝结核浓度及活化率的变化特征。结果表明:武清地区冬季CCN数浓度变化范围很大,过饱和度1%时,浓度变化范围为4000～32000cm-3,且浓度受风速影响明显,风速2级以下CCN数浓度很高,过饱和度1%时,其平均浓度可达16000cm-3,但对于4级风速以上CCN平均浓度为4000cm-3左右;在过饱和度0.1%～0.4%间CCN浓度变化较大,过饱和度每增加0.1%,CCN浓度增加值平均约为过饱和度0.4%～1.0%间浓度增量的5倍。低过饱和度(0.1%、0.2%)下,活化率受风速影响明显,1级风速下的CCN活化率约为4级风速下的3倍,但在过饱和度1%时活化率则相差不大。CCN浓度的日变化呈双峰型,峰值时刻为北京时间08:00和18:00左右,活化率的日变化则呈双谷型,这主要是受局地排放影响的结果。利用指数函数拟合各风速下CCN浓度过饱和度谱,表明该地谱型为典型的大陆型。     

采用SilviScan-3TM研究木材性质的方法及其在气候变化研究中的应用

系统介绍了利用SilviScan-3TM测量细胞结构、木材密度、微纤丝角和划分年轮界线的方法,并以祁连山青海云杉为例,分析青海云杉6个木材性质参数(年轮细胞直径、年轮细胞壁厚、年轮宽度、年轮密度、年轮微纤丝角、年轮弹性模量)与气候因子的关系,以期为利用多个树轮参数研究气候提供参考。结果表明:6个木材性质参数与月平均气温和月降水量都有显著相关的月份,但显著相关的时间段不同,并且微纤丝角和细胞结构参数中包含的气候信息强于常用的年轮宽度和年轮密度。SilviScan-3TM测量木材性质参数的优越性体现在:测量精度高、速度快,能在同一个试样上测量多个参数并能精确定年。