The pioneer work of Bernard Kübler and Martin Frey in very low-grade metamorphic terranes: paleo-geothermal potential of variation in Kübler-Index/organic matter reflectance correlations. A review

Low-temperature metamorphic petrology occupies the P?CT field between sedimentary and metamorphic petrology. Two important pillars of low-temperature metamorphism are coal petrology and clay mineralogy. When low temperature petrology was established bridging a hiatus between the two classical geological disciplines of sedimentary geology and metamorphic petrology, geologists faced a need for the usage of different terminology tenets. Martin Frey and Bernard Kübler were two pioneers in low-grade metamorphic petrology. They focused their research on clarifying the relationships of clay mineralogy and organic petrology to metamorphic pressure (P) and temperature (T) conditions. The ultimate aim of M. Frey and B. Kübler was to establish a correlation between clay indices and organic parameters for different geodynamic setting and therefore for various pressure?Ctemperature (P?CT) conditions occurring in low grade metamorphic terranes. For this purpose, a special attention was addressed to the correlation between the Kübler-Index (KI) and vitrinite reflectance (VR). All these efforts are dedicated to estimate the P?CT conditions and thus to gain insight into the geodynamic evolution of low-grade metamorphic terranes. B. Kübler and M. Frey honored here concentrated their studies to the Helvetic Central Alps area. The very low-grade Helvetic domain is therefore of basic interest of this paper. Ensuing the extensive compilation of data from the Helvetic domain, a reinterpretation of Kübler and Frey??s research is presented in the light of last decade??s scientific progress. A comprehensive dataset available enables to discriminate many factors influencing the Kübler-Index and organic-matter reflectance alongside to time, temperature and pressure. The correlation is restricted to the KI and organic matter reflectance (mostly VR) because most of the studies used both methods. Organic matter reflectance (OMR) includes data from vitrinite reflectance and bituminite reflectance measurements. Geodynamics has important control on the KI/VR (OMR) correlation. Tectonic units having a similar geodynamic evolution are featured by the comparable KI/OMR trends, related to the particular paleo-geothermal conditions. Obviously the KI/OMR correlations provide a mean to characterise geothermal gradients and metamorphic very-low-grade pressure?Ctemperature conditions. In terranes where high deformations rates are reported, exceeding the high anchizone conditions, strain promotes the kinetic effects of temperature and pressure on the KI versus OMR ratio.     

Market instruments and the neoliberalisation of land management in rural Australia

Increasing penetration by the market into the governing of agri-environments, and the use of market-oriented approaches in an attempt to produce more sustainable outcomes, is a characteristic feature of what scholars have called the ‘neoliberalisation of nature’. While accepting that neoliberal forms of governing tend to extend market relations into new domains, a number of scholars have argued that they may at the same time create spaces of resistance, open up progressive political possibilities, or incorporate alternative rationalities of governing. This literature has so far focused primarily on the policy and/or programme level with limited connection made to the growing body of research that explores landholder responses to specific market instruments. We address this gap by focusing on a market instrument – Wimmera Habitat Tender – in the State of Victoria, Australia, which aims to provide incentives for farmers in managing native vegetation. This case study explores how a specific tender-based market instrument seeks to construct natural resource managers as neoliberal subjects, as well as the complex ways in which farmers contest or resist the neoliberal governing of their agri-environmental practices. Through our analysis we contend that closer scrutiny of how the techniques underpinning market-based environmental instruments are taken up or resisted contributes to a more robust understanding of the environmental possibilities created by market instruments, as well as the challenges involved in attempts to neoliberalise nature.     

Hydrological and catchment controls on event-scale dissolved organic carbon dynamics in boreal headwater streams

Hydrological events transport large proportions of annual or seasonal dissolved organic carbon (DOC) loads from catchments to streams. The timing, magnitude and intensity of these events are very sensitive to changes in temperature and precipitation patterns, particularly across the boreal region where snowpacks are declining and summer droughts are increasing. It is important to understand how landscape characteristics modulate event-scale DOC dynamics in order to scale up predictions from sites across regions, and to understand how climatic changes will influence DOC dynamics across the boreal forest. The goal of this study was to assess variability in DOC concentrations in boreal headwater streams across catchments with varying physiographic characteristics (e.g., size, proportion of wetland) during a range of hydrological events (e.g., spring snowmelt, summer/fall storm events). From 2016 to 2017, continuous discharge and sub-daily chemistry grab samples were collected from three adjacent study catchments located at the International Institute for Sustainable Development-Experimental Lakes Area in northwestern Ontario, Canada. Catchment differences were more apparent in summer and fall events and less apparent during early spring melt events. Hysteresis analysis suggested that DOC sources were proximal to the stream for all events at a catchment dominated by a large wetland near the outlet, but distal from the stream at the catchments that lacked significant wetland coverage during the summer and fall. Wetland coverage also influenced responses of DOC export to antecedent moisture; at the wetland-dominated catchment, there were consistent negative relationships between DOC concentrations and antecedent moisture, while at the catchments without large wetlands, the relationships were positive or not significant. These results emphasize the utility of sub-daily sampling for inferring catchment DOC transport processes, and the importance of considering catchment-specific factors when predicting event-scale DOC behaviour.     

Frequency analysis of annual maximum suspended sediment concentrations in Abiod wadi,Biskra (Algeria)

Sediment transport processes in the Mediterranean semi‐arid areas have interested a great number of hydrologists and statisticians. Frequency analysis (FA) procedures are commonly applied for several hydrological events such as floods and droughts. However, in general, FA is not widely applied to treat suspended sediment concentration (SSC), especially in semi‐arid regions. In the present study, an FA was performed on SSC data from 1979 to 1991 observed upstream from the Foum El Gherza dam, which is located at Biskra in the South–East of Algeria. This dam is problematic in terms of silting. Therefore, this study is mainly motivated by providing an FA model and risk evaluation in order to assist dam managers to better evaluate the potential of silting resulting from SSC transport to the reservoir. Probability distributions commonly used in hydrology were tested to SSC data recorded at the M'chounech station on Abiod wadi located upstream the dam. All the FA steps were considered; including classical techniques (e.g. goodness‐of‐fit tests, statistical criteria) as well as recently developed tools (tail distribution classification). Their application led to the selection of the lognormal distribution (LN2) to fit the considered data, and hence an accurate risk assessment could be obtained. Because of the presence of a slight trend, non‐stationary models are also considered in the present study. Copyright © 2013 John Wiley & Sons, Ltd.     

Effects of magnesium ions on near-equilibrium calcite dissolution: Step kinetics and morphology

Dissolution kinetics at the aqueous solution-calcite interface at 50 °C were investigated using in situ atomic force microscopy (AFM) to reveal the influence of magnesium concentration and solution saturation state on calcite dissolution kinetics and surface morphology. Under near-equilibrium conditions, dissolved Mg²⁺ displayed negligible inhibitory effects on calcite dissolution even at concentrations of . Upon the introduction of , the solution saturation state with respect to calcite, , acted as a “switch” for magnesium inhibition whereby no significant changes in step kinetics were observed at Ω_calcite<0.2, whereas a sudden inhibition from Mg²⁺ was activated at Ω_calcite?0.2. The presence of the Ω-switch in dissolution kinetics indicates the presence of critical undersaturation in accordance with thermodynamic principles. The etch pits formed in solutions with exhibited a unique distorted rhombic profile, different from those formed in Mg-free solutions and in de-ionized water. Such unique etch pit morphology may be associated with the anisotropy in net detachment rates of counter-propagating kink sites upon the addition of Mg²⁺.     

Paleoenvironmental implications of taxonomic variation among δN values of chloropigments

Natural variations in the ratios of nitrogen isotopes in biomass reflect variations in nutrient sources utilized for growth. In order to use δ¹⁵N values of chloropigments of photosynthetic organisms to determine the corresponding δ¹⁵N values of biomass - and by extension, surface waters - the isotopic offset between chlorophyll and biomass must be constrained. Here we examine this offset in various geologically-relevant taxa, grown using nutrient sources that may approximate ocean conditions at different times in Earth’s history. Phytoplankton in this study include cyanobacteria (diazotrophic and non-diazotrophic), eukaryotic algae (red and green), and anoxygenic photosynthetic bacteria (Proteobacteria), as well as environmental samples from sulfidic lake water. Cultures were grown using N₂, NO₃⁻, and NH₄⁺ as nitrogen sources, and were examined under different light regimes and growth conditions. We find surprisingly high variability in the isotopic difference (δ¹⁵N_biomass − δ¹⁵N_{chloropigment}) for prokaryotes, with average values for species ranging from −12.2‰ to +11.7‰. We define this difference as ε_por, a term that encompasses diagenetic porphyrins and chlorins, as well as chlorophyll. Negative values of ε_por reflect chloropigments that are ¹⁵N-enriched relative to biomass. Notably, this enrichment appears to occur only in cyanobacteria. The average value of ε_por for freshwater cyanobacterial species is −9.8 ± 1.8‰, while for marine cyanobacteria it is −0.9 ± 1.3‰. These isotopic effects group environmentally but not phylogenetically, e.g., ε_por values for freshwater Chroococcales resemble those of freshwater Nostocales but differ from those of marine Chroococcales. Our measured values of ε_por for eukaryotic algae (range = 4.7-8.7‰) are similar to previous reports for pure cultures. For all taxa studied, values of ε_por do not depend on the type of nitrogen substrate used for growth. The observed environmental control of ε_por suggests that values of ε_por could be useful for determining the fractional burial of eukaryotic vs. cyanobacterial organic matter in the sedimentary record.     

Investing in low-carbon transitions: energy finance as an adaptive market

The amount of capital required to transition energy systems to low-carbon futures is very large, yet analysis of energy systems change has been curiously quiet on the role of capital markets in financing energy transitions. This is surprising given the huge role finance and investment must play in facilitating transformative change. We argue this has been due to a lack of suitable theory to supplant neoclassical notions of capital markets and innovation finance. This research draws on the notion from Planetary economics: Energy, climate change and the three domains of sustainable development, by Grubb and colleagues, that planetary economics is defined by three ‘domains’, which describe behavioural, neoclassical, and evolutionary aspects of energy and climate policy analysis. We identify first- and second-domain theories of finance that are well established, but argue that third-domain approaches, relating to evolutionary systems change, have lacked a compatible theory of capital markets. Based on an analysis of electricity market reform and renewable energy finance in the UK, the ‘adaptive market hypothesis' is presented as a suitable framework with which to analyse energy systems finance. Armed with an understanding of financial markets as adaptive, scholars and policy makers can ask new questions about the role of capital markets in energy systems transitions.

Policy relevance

This article explores the role of financial markets in capitalising low-carbon energy systems and long-term change. The authors demonstrate that much energy and climate policy assumes financial markets are efficient, meaning they will reliably capitalise low-carbon transitions if a rational return is created by subsidy regimes or other market mechanisms. The authors show that the market for renewable energy finance does not conform to the efficient markets hypothesis, and is more in line with an ‘adaptive’ markets understanding. Climate and energy policy makers that design policy, strategy, and regulation on the assumption of efficient financial markets will not pay attention to structural and behavioural constraints on investment; they risk falling short of the investment levels needed for long-term systems change. In short, by thinking of financial markets as adaptive, the range of policy responses to enable low-carbon investment can be much broader.     

A Multi-wavelength Analysis of Active Regions and Sunspots by Comparison of Automatic Detection Algorithms

Since the Solar Dynamics Observatory (SDO) began recording ≈?1 TB of data per day, there has been an increased need to automatically extract features and events for further analysis. Here we compare the overall detection performance, correlations between extracted properties, and usability for feature tracking of four solar feature-detection algorithms: the Solar Monitor Active Region Tracker (SMART) detects active regions in line-of-sight magnetograms; the Automated Solar Activity Prediction code (ASAP) detects sunspots and pores in white-light continuum images; the Sunspot Tracking And Recognition Algorithm (STARA) detects sunspots in white-light continuum images; the Spatial Possibilistic Clustering Algorithm (SPoCA) automatically segments solar EUV images into active regions (AR), coronal holes (CH), and quiet Sun (QS). One month of data from the Solar and Heliospheric Observatory (SOHO)/Michelson Doppler Imager (MDI) and SOHO/Extreme Ultraviolet Imaging Telescope (EIT) instruments during 12 May?–?23 June 2003 is analysed. The overall detection performance of each algorithm is benchmarked against National Oceanic and Atmospheric Administration (NOAA) and Solar Influences Data Analysis Center (SIDC) catalogues using various feature properties such as total sunspot area, which shows good agreement, and the number of features detected, which shows poor agreement. Principal Component Analysis indicates a clear distinction between photospheric properties, which are highly correlated to the first component and account for 52.86% of variability in the data set, and coronal properties, which are moderately correlated to both the first and second principal components. Finally, case studies of NOAA 10377 and 10365 are conducted to determine algorithm stability for tracking the evolution of individual features. We find that magnetic flux and total sunspot area are the best indicators of active-region emergence. Additionally, for NOAA 10365, it is shown that the onset of flaring occurs during both periods of magnetic-flux emergence and complexity development.