Analytical evaluation of structural component limit state probabilities

Probabilistic seismic assessment requires extensive computational effort resulting from variability both in input ground motions and mechanical properties. Nonetheless, such methodologies are of considerable importance, namely for pre-earthquake disaster planning or development of retrofitting programs. A framework for the analytical definition of closed form expressions for exceedance probabilities of structural component limit states, defined by limit values of structural response parameters, is proposed herein. The definition of these expressions is based on the probabilistic representation of the ground motion intensity and on the establishment of suitable expressions characterizing the evolution of structural demand with increasing earthquake intensity. Distinction is made between deformation-based and force-based structural parameters in the definition of such relations. Within the proposed framework, the limit states are defined by single deterministic thresholds of structural response quantities at the component level, as defined in structural codes. Different approaches are also discussed to account for the randomness of the mechanical properties and ground motion input within the proposed methodology. An application of the assessment of different limit state probabilities of members from a reinforced concrete building is presented, for which limit states and limit state capacities are defined according to the upcoming Part 3 of the Eurocode 8. Although the presented application only deals with member chord rotation and shear force limit state probabilities, the proposed methodology can be generalized to other deformation-based and force-based structural parameters.     

Kinematics of Interacting ICMEs and Related Forbush Decrease: Case Study

We study heliospheric propagation and some space weather aspects of three Earth-directed interplanetary coronal mass ejections (ICMEs), successively launched from the active region AR 11158 in the period 13?–?15 February 2011. From the analysis of the ICME kinematics, morphological evolution, and in situ observations, we infer that the three ICMEs interacted on their way to Earth, arriving together at 1 AU as a single interplanetary disturbance. Detailed analysis of the in situ data reveals complex internal structure of the disturbance, where signatures of the three initially independent ICMEs could be recognized. The analysis also reveals compression and heating of the middle ICME, as well as ongoing magnetic reconnection between the leading and the middle ICME. We present evidence showing that the propagation of these two, initially slower ICMEs, was boosted by the fastest, third ICME. Finally, we employ the ground-based cosmic ray observations, to show that this complex disturbance produced a single cosmic ray event, i.e., a simple Forbush decrease (FD). The results presented provide a better understanding of the ICME interactions and reveal effects that should be taken into account in forecasting of the arrival of such compound structures.     

Synchrotron-based X-ray study of iron oxide transformations in terraces from the Tinto-Odiel river system: Influence on arsenic mobility

Simultaneous analysis of micro-X-ray diffraction (μ-XRD) and micro-X-ray fluorescence (μ-XRF) based on synchrotron light sources, and electron microprobe (EMP) analyses, were performed on iron terrace samples taken from Tinto-Odiel river system from the Iberian Pyrite Belt (IBP, SW Iberian Peninsula). Iron terraces are formed during the oxidation and precipitation of dissolved iron along the riverbeds impacted by acid mine drainage (AMD). This paper includes the study of actively-forming current terraces and fossil terraces isolated from the stream courses due to the river migration over time. The results of the study of current terrace samples from AMD-affected streams of two IPB abandoned mines (Tinto Santa Rosa and Cueva de la Mora) showed that fresh precipitates at the surface are composed primarily of metastable schwertmannite, which is gradually transformed at depth over short-time scales into goethite. Sediments of ancient terraces are composed mainly of goethite, which most likely originated from the re-crystallization of a precursor schwertmannite. However, at century-time scale, goethite partially re-crystallizes to hematite due to diagenetic processes. The transformation rate of goethite into hematite is negatively correlated with grain size and the crystallinity of goethite. Moreover, this transformation is accompanied by an increase in grain size and a decrease in surface area of hematite, and a concomitant decrease in arsenic trapped in the solid. This increase in the arsenic mobility during the diagenetic maturation should be considered in the development of conceptual and analytical models describing long-term fate, transport and bioavailability of arsenic in environmental systems.     

Influence of sieving time on the efficiency and accuracy of grain‐size analysis of beach and dune sands

Grain size is a fundamental property of sediments and is commonly used to describe sedimentary facies and classify sedimentary environments. Among the various conventional techniques utilized to determine grain‐size frequency distributions, sieving is the most widely applied procedure. The accuracy of such analyses is, among other factors, strongly dependent on the sieving time. However, despite a substantial amount of research in this field, optimal sieving times for different types of sediments have, to date, not been established. In this article, the influence of sieving time on grain‐size analyses of medium‐grained microtidal and mesotidal beach and dune sands has been determined. To assess the precision of important textural parameters, such as median grain size, sorting, skewness and kurtosis, an error analysis was carried out for different sieving times (2, 5, 10, 15 and 20 minutes). After calibrating the analytical and sampling methodologies, significant deviations were registered when sieving time was less than 10 minutes. However, such deviations were very small and grain‐size distributions remained almost identical for sieving times of 10 minutes and longer, relative errors being as low as 0% in some cases.     

Measuring the impact of pollution on property prices in Madrid: objective versus subjective pollution indicators in spatial models

Much work has been done in the context of the hedonic price theory to estimate the impact of air quality on housing prices. Research has employed objective measures of air quality, but only slightly confirms the hedonic theory in the best of cases: the implicit price function relating housing prices to air pollution will, ceteris paribus, be negatively sloped. This paper compares the performance of a spatial Durbin model when using both objective and subjective measures of pollution. On the one hand, we design an Air Pollution Indicator based on measured pollution as the objective measure of pollution. On the other hand, the subjective measure of pollution employed to characterize neighborhoods is the percentage of residents who declare that the neighborhood has serious pollution problems, the percentage being referred to as residents’ perception of pollution. For comparison purposes, the empirical part of this research focuses on Madrid (Spain). The study employs a proprietary database containing information about the price and 27 characteristics of 11,796 owner-occupied single family homes. As far as the authors are aware, it is the largest database ever used to analyze the Madrid housing market. The results of the study clearly favor the use of subjective air quality measures.     

Alternative closed‐form solutions for the mean rate of exceedance of structural limit states

Two new closed‐form expressions representing the mean rate of exceedance of a given limit state are presented herein. These proposals overcome limitations that were identified with the original formulation of the well‐known SAC/FEMA approach. The new expressions involve new parametric functions for the modeling of the seismic hazard data and for the demand evolution for increasing values of the earthquake intensity measure. Given the carefully selected parametric form of these functions, mathematical tractability is able to be maintained to establish two new closed‐form solutions representing the mean rate of exceedance of a given limit state. The function proposed for the hazard exhibits nonlinear behavior in log‐log space and is able to represent the actual hazard data over a wider range of earthquake intensity levels. The function proposed for the demand evolution addresses issues related to the inadequate performance of the SAC/FEMA approach when force‐based demand parameters such as the shear force are considered. To illustrate the applicability of the new closed‐form solutions, the probability of occurrence of several limit states is determined for a reinforced concrete structure. Copyright © 2013 John Wiley & Sons, Ltd.     

Study of the Contributions of Non‐Specific and Specific Interactions during Fluoxetine Adsorption onto Activated Carbons

The adsorption of fluoxetine onto activated carbons (ACs) prepared from almond tree pruning by steam and CO₂ activation under different temperature conditions (650–950°C), was studied. In both series increasing the temperature caused an increase in the BET apparent surface area, yielding ACs with S_BET up to 870 and 710 m² g^?1 after steam and CO₂ activation, respectively. Also, a slight widening of the porosity was found in both cases. In order to modify the functionality of the ACs, two of them were impregnated with triethylenediamine (TEDA) prior to the adsorption process, which caused a decrease in the AC apparent surface mainly due to micropore blockage. The fluoxetine adsorption isotherms at 25°C showed maximum adsorption capacities between 110 and 224 mg g^?1. The adsorption isotherms were analyzed using Langmuir and Freundlich models. Although the impregnation reduced the pore volume, it did not cause a decrease in the fluoxetine maximum adsorption capacity, but a modification in the adsorption mechanism was observed.     

Structural and magnetic fabric study of the Marimanha granite (Axial Zone of the Pyrenees)

The structural and magnetic fabric study of the Marimanha granite, Axial Zone of the Pyrenees, provides new data to characterize the zonation and the internal structure of the pluton. The Marimanha granite intrudes Cambro–Ordovician clastic rocks and Silurian–Devonian limestones and slates. The zonation of the low field magnetic susceptibility, consistent with the petrological zonation of the igneous body, indicates a concentric arrangement of rock types, with more basic compositions at the external areas. This pluton is characterized by a low susceptibility, and rock–magnetic studies indicate a majority of “paramagnetic” samples. Magnetic foliations strike parallel to petrographic contacts and to contours of zonation of magnetic susceptibility, and show a dominant NE–SW strike, steeply dipping towards the North. Locally, in the northern border of the pluton foliation directions become perpendicular to petrographic contacts and depict sigmoidal trajectories. Magnetic lineations are characterized by the predominance of NE–SW trends with shallow plunges to the NE and SW. These foliations and lineations are parallel to the slight elongation of internal petrographic zonation. Magnetic fabric within the granitoid body and internal elliptical shape of petrographic zonation, suggest an intrusion contemporary with a transpressional regime and NNW–SSE shortening, syntectonic with the late stages of the Variscan orogeny. These results are in accordance with anisotropy of magnetic susceptibility studies of others plutons in the Pyrenees. To explain the origin of the Marimanha granite we propose magma ascent through faults at depth and emplacement by ballooning in situ at the rheological boundary between Cambro–Ordovician and Siluro–Devonian metasediments.     

Mechanics of thick-skinned Variscan overprinting of Cadomian basement (Iberian Variscides)

Remnants of the Cadomian basement can be found in the Iberian Variscides (IBVA) in several key sectors of its autochthonous units (composed of Neoproterozoic to Lower Palaeozoic metasedimentary sequences) and within the Continental Allochthonous Terrane (CAT). Comprehensive characterization of these critical exposures shows that the prevailing features are related to major geological events dated within the age range of 620–540 Ma. Indeed, near the Cambrian–Ordovician boundary, the IBVA Internal Zones experienced pervasive basement thinning and cover thickening, reflecting diffusive displacement of intracratonic rifting that continued until Lower Devonian times. In the thick-skinned Internal Zones, Helvetic/Penninic style nappes were generated, whereas flower upright axial structures developed along transpressive, intraplate shear zones. These features contrast with those preserved in the thin-skinned IBVA External Zones, dominated by décollements above (un-)deformed Palaeozoic and Cadomian basement. The inferred attenuation of rheological contrast between Cadomian basement and Palaeozoic cover can be explained by inherited fabrics due to thermal softening operated during the Cambrian–Lower Devonian extensional regime. Deeper décollements (and subsequent strain partitioning) are also expected to develop at the upper-lower crust (and at the Moho?) transition, as imaged by the available seismic profiling and MT surveys. The whole data implies a significant discontinuity between Cadomian and Variscan Cycles that should have constrained subsequent lithospheric evolution.