U-Pb-Hf isotopic data from detrital zircons in late Carboniferous and Mid-Late Triassic sandstones,and also Carboniferous granites from the Tauride and Anatolide continental units in S Turkey: implications for Tethyan palaeogeography

ABSTRACT

Zircons from Carboniferous sandstones (three samples) and Mid-Late Triassic sandstones (four samples) from the Tauride and Anatolide continental units were analysed for U-Pb-Hf isotopes. For comparison, zircons were also analysed from Carboniferous granites of the Afyon Zone, Anatolides (three samples). A NE African/Arabian source is inferred for both the Carboniferous sandstones of the Taurides (Alada?) and the Anatolides (Konya Complex). In contrast, the Carboniferous Karaburun Melange is characterised by a NW African provenance. A prominent Devonian population occurs in the Carboniferous Karaburun Melange, characterised by mainly positive ε_Hf(t) values that differ significantly from those of the Devonian granites of the Sakarya continental crustal unit (Pontides). Middle-Late Triassic Tauride sandstones include minor Palaeozoic and Early Mesozoic zircons. In contrast, Devonian and Carboniferous zircons are relatively abundant in Late Triassic sandstones of the Karaburun Peninsula. The Hf isotopic compositions of 25 Carboniferous-aged zircons from three samples of Mid-Late Triassic sandstone and one of Late Carboniferous age (one sample) overlap with the ε_Hf(t) values of Carboniferous arc-type granites in the Anatolides. Taking account of the available U-Pb and Lu-Hf isotopic data from comparative crustal units, the Devonian zircon populations from the melanges in the Karaburun Peninsula and the Konya Complex are inferred to have a westerly source (e.g. granitic rocks of Aegean region or central Europe). A tectonic model is proposed in which Palaeozoic Tethys sutured during the late Carboniferous in the west (Aegean region westwards), leaving an eastward-widening oceanic gulf in which sandstone turbidites accumulated, including Devonian zircons.     

Reporting negative results to stimulate experimental hydrology: discussion of “The role of experimental work in hydrological sciences – insights from a community survey”*

ABSTRACT

Experimental work in hydrology is in decline. Based on a community survey, Blume et al. showed that the hydrological community associates experimental work with greater risks. One of the main issues with experimental work is the higher chance of negative results (defined here as when the expected or wanted result was not observed despite careful experimental design, planning and execution), resulting in a longer and more difficult publishing process. Reporting on negative results would avoid putting time and resources into repeating experiments that lead to negative results, and give experimental hydrologists the scientific recognition they deserve. With this commentary, we propose four potential solutions to encourage reporting on negative results, which might contribute to a stimulation of experimental hydrology.     

Forecasting Groundwater Temperature with Linear Regression Models Using Historical Data

Although temperature is an important determinant of many biogeochemical processes in groundwater, very few studies have attempted to forecast the response of groundwater temperature to future climate warming. Using a composite linear regression model based on the lagged relationship between historical groundwater and regional air temperature data, empirical forecasts were made of groundwater temperature in several aquifers in Switzerland up to the end of the current century. The model was fed with regional air temperature projections calculated for greenhouse‐gas emissions scenarios A2, A1B, and RCP3PD. Model evaluation revealed that the approach taken is adequate only when the data used to calibrate the models are sufficiently long and contain sufficient variability. These conditions were satisfied for three aquifers, all fed by riverbank infiltration. The forecasts suggest that with respect to the reference period 1980 to 2009, groundwater temperature in these aquifers will most likely increase by 1.1 to 3.8 K by the end of the current century, depending on the greenhouse‐gas emissions scenario employed.     

Magmatic evolution of the Karmøy Ophiolite Complex,SW Norway: relationships between MORB-IAT-boninitic-calc-alkaline and alkaline magmatism

The polyphasal magmatic evolution of the Caledonian Karmøy Ophiolite Complex includes: (1) formation of an axis sequence from island-arc tholeiitic (IAT) and more MORB-like magmas (493+7/-4 Ma); (2) intrusion of magmas of boninitic affinity (485±2 Ma); (3) intrusion of MORB- and IAT-like magmas; (4) intrusion and extrusion of calc-alkaline magmas (470+9/-5 Ma); (5) intrusion and extrusion of basalts with alkaline trace-element affinity. Repeated intrusion of MORB and IAT-like magmas may be explained by intermittent magmatism involving magma-chamber solidification and remelting of a source characterized by initial _Nd of approximately +6.5. The boninitic rocks may have formed from two LREE-depleted sources: the primary source of the axis-sequence magmas and the residual source left after extraction of these magmas. These sources have been enriched in LREE, Th and Zr from subducted material exhibiting a continental Nd-isotope signature with initial _Nd less than-8. Covariation between _Nd and Th, Zr, Nd, Y and Yb may be explained by metasomatic enrichment of a LREE-depleted mantle source by a LREE-enriched subduction component, followed by partial melting during which the degree of melting of the metasomatized mantle source increased linearly with the amount of subduction component added to the mantle source. The calc-alkaline magmas may have formed by remelting of a highly depleted source, which became enriched in some trace elements derived from the source of the subsequent alkaline magmatism. The geology and geochemistry of the Karmøy Ophiolite Complex suggest growth of an island-arc upon newly-formed oceanic crust, followed by arc-splitting and the development of a new basin.     

Uptake and tissue distribution of C4-C7 alkylphenols in Atlantic cod (Gadus morhua): relevance for biomonitoring of produced water discharges from oil production

The sensitivity of different tissues for assessment of chronic low-dose environmental exposure of fish to alkylphenols (APs) was investigated. We exposed Atlantic cod (Gadus morhua) in the laboratory to tritium labelled 4-tert-butylphenol, 4n-pentylphenol, 4n-hexylphenol, and 4n-heptylphenol via seawater (8 ng/l) and via contaminated feed (5 μg/kg fish per day). Measurements of different fish tissues during eight days of exposure and eight subsequent days of recovery revealed that APs administered via spiked seawater were readily taken up whereas the uptake was far less efficient when APs were administered in spiked feed. AP residues were mainly located in the bile fluid whereas the concentrations in liver were very low, indicating a rapid excretion and the liver-bile axis to be the major route of elimination. The biological half-life of APs in the exposed cod was short, between 10 and 20 h. Our study shows that in connection with biomonitoring of AP exposure in fish, assessment of AP metabolites in bile fluid is a more sensitive tool than detection of parent AP levels in liver or other internal tissues.     

Protoliths and phase petrology of whiteschists

Whiteschists appear in numerous high- and ultrahigh-pressure rock suites and are characterized by the mineral assemblage kyanite + talc (+-quartz or coesite). We demonstrate that whiteschist mineral assemblages are well stable up to pressures of more than 4 GPa but may already form at pressures of 0.5 GPa. The formation of whiteschists largely depends on the composition of the protolith, which requires elevated contents of Al and Mg as well as low Fe, Ca, and Na contents, as otherwise chloritoid, amphibole, feldspar, or omphacite are formed instead of kyanite or talc. Furthermore, the stability field of the whiteschist mineral assemblage strongly depends on XCO₂ and fO₂: already at low values of XCO₂, CO₂ binds Mg to carbonates strongly reducing the whiteschist stability field, whereas high fO₂ enlarges the stability field and stabilizes yoderite. Thus, the scarcity of whiteschist is not necessarily due to unusual P–T conditions, but to the restricted range of suitable protolith compositions and the spatial distribution of these protoliths: (1) continental sedimentary rocks and (2) hydrothermally and metasomatically altered felsic to mafic rocks. The continental sedimentary rocks that may produce whiteschist mineral assemblages typically have been deposited under arid climatic conditions in closed evaporitic basins and may be restricted to relatively low latitudes. These rocks often contain large amounts of the clay minerals palygorskite and sepiolite. Marine sediments generally do not yield whiteschist mineral assemblages as marine shales commonly have too high iron contents. Sabkha deposits may have too high CO₂ contents. Protoliths of appropriate geochemical composition occur in and on continental crust. Therefore, whiteschist assemblages typically are only found in settings of continental collision or where continental fragments were involved in subduction. Our calculations demonstrate that whiteschists can form by closed-system metamorphism, which implies that the chemical and isotopic composition of these rocks provide constraints on the development of the protoliths.     

Exploring the impact of diagenesis on (isotope) geochemical and microstructural alteration features in biogenic aragonite

For the Quaternary and Neogene, aragonitic biogenic and abiogenic carbonates are frequently exploited as archives of their environment. Conversely, pre‐Neogene aragonite is often diagenetically altered and calcite archives are studied instead. Nevertheless, the exact sequence of diagenetic processes and products is difficult to disclose from naturally altered material. Here, experiments were performed to understand biogenic aragonite alteration processes and products. Shell subsamples of the bivalve Arctica islandica were exposed to hydrothermal alteration. Thermal boundary conditions were set at 100°C, 175°C and 200°C. These comparably high temperatures were chosen to shorten experimental durations. Subsamples were exposed to different ¹⁸O‐depleted fluids for durations between two and twenty weeks. Alteration was documented using X‐ray diffraction, cathodoluminescence, fluorescence and scanning electron microscopy, as well as conventional and clumped isotope analyses. Experiments performed at 100°C show redistribution and darkening of organic matter, but lack evidence for diagenetic alteration, except in Δ₄₇ which show the effects of annealing processes. At 175°C, valves undergo significant aragonite to calcite transformation and neomorphism. The δ¹⁸O signature supports transformation via dissolution and reprecipitation, but isotopic exchange is limited by fluid migration through the subsamples. Individual growth increments in these subsamples exhibit bright orange luminescence. At 200°C, valves are fully transformed to calcite and exhibit purple‐blue luminescence with orange bands. The δ¹⁸O and Δ₄₇ signatures reveal exchange with the aqueous fluid, whereas δ¹³C remains unaltered in all experiments, indicating a carbonate‐buffered system. Clumped isotope temperatures in high‐temperature experiments show compositions in broad agreement with the measured temperature. Experimentally induced alteration patterns are comparable with individual features present in Pleistocene shells. This study represents a significant step towards sequential analysis of diagenetic features in biogenic aragonites and sheds light on reaction times and threshold limits. The limitations of a study restricted to a single test organism are acknowledged and call for refined follow‐up experiments.     

The GeoForschungsZentrum Potsdam/Groupe de Recherche de Gèodésie Spatiale satellite-only and combined gravity field models: EIGEN-GL04S1 and EIGEN-GL04C

The recent improvements in the Gravity Recovery And Climate Experiment (GRACE) tracking data processing at GeoForschungsZentrum Potsdam (GFZ) and Groupe de Recherche de Géodésie Spatiale (GRGS) Toulouse, the availability of newer surface gravity data sets in the Arctic, Antarctica and North-America, and the availability of a new mean sea surface height model from altimetry processing at GFZ gave rise to the generation of two new global gravity field models. The first, EIGEN-GL04S1, a satellite-only model complete to degree and order 150 in terms of spherical harmonics, was derived by combination of the latest GFZ Potsdam GRACE-only (EIGEN-GRACE04S) and GRGS Toulouse GRACE/LAGEOS (EIGEN-GL04S) mean field solutions. The second, EIGEN-GL04S1 was combined with surface gravity data from altimetry over the oceans and gravimetry over the continents to derive a new high-resolution global gravity field model called EIGEN-GL04C. This model is complete to degree and order 360 and thus resolves geoid and gravity anomalies at half- wavelengths of 55 km at the equator. A degree-dependent combination method has been applied in order to preserve the high accuracy from the GRACE satellite data in the lower frequency band of the geopotential and to form a smooth transition to the high-frequency information coming from the surface data. Compared to pre-CHAMP global high-resolution models, the accuracy was improved at a spatial resolution of 200 km (half-wavelength) by one order of magnitude to 3 cm in terms of geoid heights. The accuracy of this model (i.e. the commission error) at its full spatial resolution is estimated to be 15 cm. The model shows a reduced artificial meridional striping and an increased correlation of EIGEN-GL04C-derived geostrophic meridional currents with World Ocean Atlas 2001 (WOA01) data. These improvements have led to select EIGEN-GL04C for JASON-1 satellite altimeter data reprocessing. Electronic Supplementary Material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Chironomid-based paleosalinity records in southern British Columbia, Canada: a comparison of transfer functions

Chironomid remains from Big Lake, British Columbia were analysed and paleosalinities were estimated using a pre-existing transfer function and several developed using new regression methods. A two component partial-least-squares model (PLS-2) had the highest coefficient of determination (R² _(Jackknifed) = 0.75) and lowest root-mean-squared error-of-prediction (RMSEP). As compared to the pre-existing model, it was also less sensitive to the influence of rare taxa. Nevertheless, the marginally larger R² _(Jackknifed) and lower RMSEP do not clearly identify a single best model. The models were applied to Big, Mahoney and Kilpoola lakes, revealing the sensitivity of paleosalinity inferences to model selection. A synopsis of chironomid-based paleosalinities in British Columbia and their correspondence with other paleoclimatic data are presented and discussed.