Different styles of metasomatic veining in ultramafic xenoliths from the TUBAF Seamount (Bismarck Microplate,Papua New Guinea)

Petrologic, geochemical and isotopic investigations on two ultramafic xenoliths with metasomatic veins from the TUBAF Seamount in the Bismarck Archipelago NE of Papua New Guinea reveal different styles of metasomatic overprinting. The first xenolith, a clinopyroxene–poor spinel lherzolite, was part of the depleted upper mantle. It contains an orthopyroxene-rich vein that formed by hydrous metasomatism at ~ 980 °C and ~ 1.5 GPa. The second xenolith is a clinopyroxene-dominated spinel olivine websterite that formed as a magmatic cumulate at the transition of the upper mantle to the oceanic crust. The websterite contains a vein with orthopyroxenes and clinopyroxenes, which give evidence for high-temperature crystallization at ~ 1300 °C and < 0.36 GPa. Both xenoliths were transported to the seafloor by a Quaternary trachybasalt in a fore-arc position. The vein minerals show a strong affinity to a supra-subduction zone or island arc setting. The REE pattern of the vein in the clinopyroxene–poor lherzolite strongly resembles the one from the host trachybasalt, with a high enrichment of the LREE and a strong to moderate enrichment of the MREE and HREE. Although broadly similar in shape, the REE pattern of the vein in the websterite shows a much weaker enrichment. The same applies to the trace-element patterns, although there are significant differences in the Eu, Zr, Hf and Nb concentrations. The isotope signatures of both veins suggest a derivation from a subducted slab that had been hydrothermally altered by seawater (high ⁸⁷Sr/⁸⁶Sr values).The contrasting crystallization temperatures of the vein minerals as well as their overall geochemical differences indicate that the metasomatic agents responsible for the vein in the websterite were mobilized from a previously depleted source at a much deeper mantle level than those forming the vein of the clinopyroxene–poor lherzolite. The metasomatic agents may also have been mobilized at different times and from different plates, i.e., the deeply subducted Solomon Sea Microplate (for the veins in the websterite) and the shallow dehydrating Pacific Plate (for the veins in the clinopyroxene–poor lherzolite).Metasomatic agents responsible for similar petrologic phenomena, i.e., modal or cryptic metasomatism, may have distinctly different origins and show contrasting histories. A strongly depleted lherzolite may totally lose its initial geochemical signature by the influence of an enriched metasomatic agent, whereas a primarily enriched ultramafic rock, e.g., a websterite, may strongly obscure the trace-element pattern of a less enriched metasomatic vein. Furthermore, the geochemistry of the ultramafic xenoliths may reflect polyphase cryptic and modal metasomatism related to veining and later transport by the hosting melt to the seafloor.     

Schuppung und Faltung im glazialtektonischen Experiment

Zusammenfassung Die wichtigsten glazialen Stauchungsvorgänge wurden experimentell nachgeahmt. Als Versuchsmaterial fanden erwärmte Sand-Paraffin-Gemenge mit eingelegten Schichten von Modellgips Verwendung. Bei Temperaturen über dem Schmelzpunkt des Paraffins besitzen sie ähnlich günstige Eigenschaften wie der meist bevorzugte Tonschlamm, bei Zimmertemperatur sind sie erhärtet und erlauben, im Gegensatz zum Tonschlamm, beliebige Profilschnitte und damit Einblicke in den inneren Bau.Die Experimente ergaben Zusammenhänge zwischen Veränderungen im Versuchsansatz und verschiedenen Störungstypen. Es entstanden:Schuppen bei Stauchung vor dem Modell einer Eiszunge,Falten bei Stauchung unter Belastung,Horizontal eingeschlichtete Streifen bei Bewegung des Modelles unter seiner Sohle.Die Beobachtungen stimmen weitgehend überein mit den Lagerungsstörungen in eisentstandenen Formen entsprechender Bildungsbedingungen.     

4He diffusion in specular hematite

In order to test the chronometer qualities of speculante for the (U + Th)/He dating method, ⁴He release experiments by stepwise heating of two specularites from the Rimbach mineralization locality in the southern Vosgues (France) have been carried out. The diffusion coefficients define linear Arrhenius plots within a temperature interval of 250 to 830 °C, which is suggestive of volume diffusion. Extrapolation of the diffusion behavior to 20° C yields diffusion coefficients (D₂₀ values) smaller than 10^?26 [cm² s^?1] for both hematites with activation energies at 116 [kJ/mole]. The results of our study suggest that specularite is a very helium retentive hematite variety which is capable of quantitatively retaining radiogenic helium over geologic periods of time.     

Uranium–lead ages of apatite from iron oxide ores of the Bafq District,East-Central Iran

Iron oxide–apatite (IOA) deposits, often referred to as Kiruna-type iron ore deposits, are known to have formed from the Proterozoic to the Tertiary. They are commonly associated with calc–alkaline volcanic rocks and regional- to deposit-scale metasomatic alteration. In the Bafq District in east Central Iran, economic iron oxide–apatite deposits occur within felsic volcanic tuffs and volcanosedimentary sequences of Early Cambrian age. In order to constrain the age of formation of these ores and their relationship with the Early Cambrian magmatic event, we have determined the U–Pb apatite age for five occurrences in the Bafq District. In a ²⁰⁶Pb/²³⁸U vs. ²⁰⁷Pb/²³⁵U diagram, apatite free of or poor in inclusions of other minerals plots along the Concordia between 539 and 527 Ma with four out of five samples from one deposit clustering at the upper end of this range. For this deposit, we interpret this cluster to represent the age of apatite formation, whereas the spread towards younger ages may reflect either minor Pb loss or several events of IOA formation. Apatite with inclusions of monazite (±xenotime) yields disturbed systems with inclusions having developed after formation of the iron ore–apatite deposits, possibly as late as 130–140 Ma ago. Obtained apatite ages confirms that (IOA) and the apatite-rich rocks (apatites) of the Bafq district formed coevally with the Early Cambrian magmatic (-metasomatic) events.     

Zircon fission‐track ages from Newfoundland—A proxy for high geothermal gradients and exhumation before opening of the Central Atlantic Ocean

Following Appalachian orogenesis, metamorphic rocks in central Newfoundland were exhumed and reburied under Tournaisian strata. New zircon fission‐track (ZFT) ages of metamorphic rocks below the Tournaisian unconformity yield post‐depositionally reset ages of 212–235 Ma indicating regional fluid‐absent reheating to at least ≥220°C. Post‐Tournaisian sedimentary thicknesses in surrounding basins show that burial alone cannot explain such temperatures, thus requiring that palaeo‐geothermal gradients increased to ≥30–40°C/km before final late Triassic accelerated cooling. We attribute these elevated palaeo‐geothermal gradients to localized thermal blanketing by insulating sediments overlying radiogenic high‐heat‐producing granitoids. Late Triassic rifting and magmatism before break up of Pangaea likely also contributed to elevated heat flow, as well as uplift, triggering late Triassic accelerated cooling and exhumation. Thermochronological ages of 240–200 Ma are seen throughout Atlantic Canada, and record rifting and basaltic magmatism on the conjugate margins of the Central Atlantic Ocean preceding the onset of oceanic spreading at ~190 Ma.     

Calcite Dissolution Kinetics

We compare the canonical treatment of calcite’s dissolution rate from the literature in a closed system, particle batch reactor, with the alternative approach suggested by Truesdale (Aquat Geochem, 2015). We show that the decay of rate over time can be understood in terms of the evolution and distribution of reactive sites on the surface of these particles. We also emphasize that interpretation of observed rates must not exclude the fundamental role of crystal defects, whose importance is already implicitly reflected in the common form of rate laws in geochemistry. The empirical behavior of overall rate in closed systems, such as those described by Truesdale, may thus reflect relationships between defect centers and the generation of steps over the calcite surface (previously documented for silicates), such that below a critical free energy limit, there is insufficient driving force to open hollow cores and thus a loss of reaction mechanism. Dissolution in this very-near-equilibrium regime will be dependent on the distribution of extant steps and the energetics of new kink site nucleation. However, these sensitivities are complicated in the case of particle systems by grain boundaries, edges, corners, and other terminations. Such discontinuities constitute a defect class whose overall kinetic importance will be strongly tied to particle diameter and which can act independently of the internal strain field imposed by screw and edge dislocations.     

Genetic relationship between silver–lead–zinc mineralization in the Wutong deposit,Guangxi Province and Mesozoic granitic magmatism in the Nanling belt,southeast China

More than 50 % of the world's total reserves of tungsten are in China and most tungsten deposits are located in the Nanling range in southeast China. This study explores the potential genetic relationship between tungsten–tin (W–Sn) mineralization and shallower Ag–Pb–Zn deposits in the Nanling range based on data from the Wutong deposit, Guangxi Province. The lead, oxygen, carbon, sulfur, and strontium isotopic compositions of minerals at Wutong indicate that a single crustal-derived fluid was responsible for mineralization. Wutong likely formed at relatively low temperatures (～200–300 °C) and low pressures, as indicated by the similarity between homogenization temperatures of fluid inclusions and those estimated from S isotopic compositions of minerals. The hübnerite age (92.3–104.4 Ma) indicates that the Wutong mineralization is likely related to nearby Late Yanshanian (Cretaceous) S-type granites derived from Proterozoic crust. This mineralization event coincides with the last W–Sn mineralization event and the Cretaceous peak of mineralization in the Nanling range.     

Redistribution of HFSE elements during rutile replacement by titanite

Titanite growth at the expense of rutile during retrograde hydration of eclogite into amphibolite is a common phenomenon. We investigated an amphibolite sample from the Tromsø eclogite facies terrain in Northern Norway to gain insight into the trace element distribution between rutile and titanite during incomplete resorption of the rutile by titanite. Patchy compositional zoning of Al, Ti, and F in titanite relates to the presence of a fluid with variable Ti/Al and/or F during its growth. Laser ablation ICP–MS and electron microprobe data for high field strength elements (HFSE: Nb, Zr, Ta, and Hf) of rutile resorbed by titanite indicate a pronounced enrichment of these elements in the rim of a large single rutile crystal (~8 mm) and a systematic decrease towards uniform HFSE contents in the large core. HFSE contents of smaller rutile grains (~0.5 mm) and rutile inclusions (<100 μm) in the titanite overgrowth are similar or higher than in the rims of large rutile crystals. Element profiles from the rim inward demonstrate that HFSE enrichment in rutile is controlled by diffusion. HFSE ratios in diffusion-altered rutile show systematic variations compared with the uniform core composition of the large rutile. Modelling of Zr and Nb diffusion in rutile indicates that diffusion coefficients in rutile in fluid-dominated natural systems must be considerably higher than those determined experimentally at 1 bar in dry systems. Variations of HFSE contents in the newly formed titanite show no systematic spatial distribution. HFSE ratios in titanite and the rims of rutile are different, indicating different solid/fluid distribution coefficients in these minerals. Element fractionation by diffusion into the relict rutile and during fluid-mediated growth of new titanite could substantially change the HFSE budget of these minerals and could affect their use for geochemical tracing and other applications, such as Zr-based geothermobarometry.     

Vesuvianite-new tool for the U-Pb dating of skarn ore deposits

Summary Vesuvianites from the Early Proterozoic Björntjärn tungsten skarn deposit in northern Sweden were dated with the U-Pb and Pb-Pb methods. Low²⁰⁶Pb/²⁰⁴Pb values make the U-Pb dating of vesuvianite rather sensitive to the common lead correction. However, the combination of Pb-Pb and U-Pb data on the same material permits the deduction of precise ages on Proterozoic vesuvianites. Vesuvianite can be used to date the formation of skarn mineralizations and possibly also the metamorphism and metasomatism of argillaceous limestones.

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Vesuvianit-ein neues Werkzeug zur U-Pb Datierung von Skarnerzlagerstätten

Zusammenfassung Vesuvianit von der Wolfram-Skarnerzlagerstätte Björntjärn in Nordschweden wurde mit der U-Pb and Pb-Pb Methode datiert. Das tiefe²⁰⁶Pb/²⁰⁴Pb Verhältnis des Vesuvianits macht die U-Pb Altersbestimmung kräftig von der Korrektur des gewöhnlichen Bleis abhängig. Die Kombination von Pb-Pb und U-Pb Altersbestimmung am gleichen Probenmaterial erlaubt jedoch die präzise Datierung proterozoischer Vesuvianite. Vesuvianit kann zur direkten Altersbesimmung von Skarnlagerstätten und möglicherweise der Metamorphose und Metasomatose von mergeligen Kalksteinen verwendet werden.

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With 4 Figures     

Stratigraphic evidence for an Early Aptian sea-level fluctuation: the Graua Limestone of south-eastern Ethiopia

The occurrence of a thin band of marine limestone (Graua Limestone) within a thick succession of fluviatile sandstones in south-eastern Ethiopia is direct evidence of flooding of part of the East African craton (Horn of Africa). According to the presence of abundant orbitolinid foraminifers (Palorbitolina lenticularis Blumenbach andPraeorbitolina cormyi Schroeder), the age of the Graua Limestone can be referred to the Early Aptian. Stratigraphy and palaeogeographic reconstructions for the Early Cretaceous in the surrounding regions (Kenya, Somalia, Yemen, Socotra, Oman, Syria, Lebanon, Israel, Egypt and Libya) show that the Early Aptian transgression was of regional extent. Our data seem to confirm that this transgression was of relatively short duration. This pulse cannot be related to tectono-eustatic mechanisms, which are too slow. A short-lived event should be invoked: either a regional tectonic pulse or the desiccation of the proto-South Atlantic.