Integrated coastal fisheries management

There are two principal threats to sustainable coastal fisheries. The concern which has been evident in most parts of the world for many years is the existence of open access to fisheries which has led to over-capitalization, over-fishing of the resource and, often, conflict. Increasingly in recent years, however, a second threat has become apparent. This is the loss of fish habitat and deterioration of water quality brought about by environmental changes generated in other sectors. Integrated coastal fisheries management addresses these issues through a strategy in which the removal of open access plays the key role, supported by elements such as creation of awareness, local participation in management, training and research, and improved sectoral coordination and planning. It is noted that, very often, the amelioration of the second of the two principal threats may be dependent on the fishery sector resolving the first.     

Internal structure and occurrence of accretionary lapilli — a case study at Laacher See Volcano

Accretionary lapilli are common in fine-grained pyroclastic flow and surge deposits and related co-ignimbrite/co-surge ash layers of Laacher See volcano. Two morphologically different types are distin-guished: (1) Rim-type lapilli are composed of a coarse-grained core surrounded by a fine-grained rim. Rims are internally graded or made up of several layers of alternating fine and very-fine grained ash. (2) Core-type lapilli lack fine-grained rims. Field relationships, internal, and grain-size characteristics are specific to accretionary lapilli from different types of tephra deposits. Accretionary lapilli may therefore be a helpful tool to infer the origin of tephra of different origin. In co-ignimbrite ashfall, accretionary lapilli are generally concentrated at the base, whereas pyroclastic flow and surge deposits contain lapilli in the upper parts of individual, thin-bedded layers. Rim-type lapilli are found in pyroclastic flow and surge deposits up to 4 km from the source. Core-type lapilli occur at greater distances or are associated with vesiculated tuffs where they are within 1 km from the vent. Accretionary lapilli from co-ignimbrite/co-surge ash show open framework textures and edge-to-face contacts of individual ash particles. Vesicularity is generally low but the overall porosity of 40% to 50% results in an average density of 1200 kg/m³. Accretionary lapilli in pyroclastic flow and surge deposits are more densely packed and platy particles are often in face-to-face contacts. Vesicularity of those from pyroclastic flow deposits is significantly higher; the overall porosity is about 30% to 40% and the average density 1600 kg/m³. Grain-size analyses show that the accretionary lapilli in co-ignimbrite/co-surge ashfall deposits are the most fine-grained with a median (Md) of 20 to 30 m and a maximum grain size of 250 to 350 m. Accretionary lapilli from pyroclastic flow deposits have intermediate Md-values of 30 to 50 m and a maximum grain size of 350 to 500 m. Those of surge deposits are the coarsest grained with Md-values of 30 to >63 m and a maximum grain size up to 2 mm.     

Direct dating of hydrothermal W mineralization: U-Pb age for hübnerite (MnWO4), Sweet Home Mine, Colorado

We have investigated the potential of hübnerite for U-Pb dating. Hübnerite forms typically at medium to low-temperatures in a wide range of pneumatolytic-hydrothermal mineral deposits, particularly porphyry molybdenum and Sn-specialized granites. Hübnerite from the Sweet Home Mine (Alma, Colorado) formed in a Pb-rich, U-poor environment, but still developed relatively radiogenic Pb isotopic compositions. The low Pb_common contents in hübnerite (0.075 to 0.155 ppm) demonstrate that Pb is efficiently excluded from the crystal lattice. In contrast, U may substitute for Mn. The U-Pb data of hübnerite scatter. Most of the scatter originates from samples with ²⁰⁶Pb/²⁰⁴Pb values below 50, where Pb_blank contributes up to 30% to Pb_total. Using the least radiogenic galena Pb, samples with ²⁰⁶Pb/²⁰⁴Pb values above 70 have overlapping ²⁰⁶Pb∗/²³⁸U and ²⁰⁷Pb∗/²³⁵U values and yield a ²⁰⁶Pb/²³⁸U age of 25.7 ± 0.3 Ma (2σ). Late stage apatite from the Sweet Home Mine yields a ²⁰⁶Pb/²⁰⁴Pb-²³⁸U/²⁰⁴Pb isochron corresponding to an age of 24.8 ± 0.5 Ma (2σ). A comparison of the U-Pb hübnerite ages with literature ⁴⁰Ar/³⁹Ar ages on earlier sericite and the U-Pb age on later apatite suggests that (i) hübnerite yields accurate U-Pb ages and (ii) the evolution of the Sweet Home mineralization from greisen-type mineralization to medium-temperature hydrothermal vein mineralization took place in a few hundred thousand years at most. Aqueous low-N₂-bearing and aqueous inclusions in the dated hübnerite have homogenization temperatures between 325 and 356 °C and moderate salinity (up to 6.7 wt% NaCl equiv.). Thus, hübnerite represents one of the rare examples of a mineral that can be dated accurately and carries petrological information.     

An uncertainty parameter of historical earthquakes – the record threshold

In this study we use the term record threshold of a historical earthquake for the seismic intensity (EMS92) in an area where a given percentage P of the serial sources of places have recorded the event as been noticed there. The record threshold is understood as a limiting measure, below which warranted statements about the intensity cannot be given. P defines the acceptable uncertainty and can be chosen according to the demands of the special task, for instance, 10%. It is shown that the record threshold of historical earthquakes is not the same as the human perceptibility threshold of earthquakes of the 20th Century. The historical sources have to be selected using criteria such as completeness and homogenity of data. This demand is approximately met by inquiries for sources covering an area greater than the expected felt area of the historical earthquake.The Friuli event of 25 January 1348 is presented as an example. It is compared with the well known Friuli event of 6 May 1976 in order to calibrate its intensity. The record threshold of the 1348 event was probably IV or less than IV EMS92 for P = 10%. The method, properly modified, can be applied to different cultural epochs and areas. This result throws a light on the possible error in determining the felt area of historical events.     

Spatio‐temporal variability of zooplankton biomass and environmental control in the Northern Benguela Upwelling System: field investigations and model simulation

Spatial and temporal distribution patterns of zooplankton are highly variable in the Northern Benguela Upwelling System. We studied the distribution of zooplankton (size class ≥ 0.33 mm) and used field data from four cruises that took place between March 2008 and February 2011, as well as simulation results of a regional ecosystem model. Remotely sensed sea surface temperatures (SST) and surface chlorophyll concentrations were analysed to investigate environmental influences on zooplankton biomass. The Intense Benguela Upwelling Index showed a distinct seasonal signal throughout the years and the highest upwelling peaks in August/September. Even though surface chlorophyll concentrations were very variable throughout the year, the highest concentrations were always detected in September, following the upwelling of nutrient‐rich water. In field catches, zooplankton biomass concentration in the upper 200 m was highest above the outer shelf and shelf‐break in December 2010 and February 2011, i.e. 6 months after the upwelling peaks. In contrast, zooplankton biomass simulated by the model in the surface water was highest in September. In March/April, biomass maxima were typically measured in the field at intermediate water depths, but the vertical distribution was also affected by extensive oxygen minimum zones. The ecosystem model reproduced this vertical pattern. Although general trends were similar, simulation data of zooplankton standing stocks overestimated the field data by a factor of 3. In upwelling systems, food webs are generally considered to be short and dominated by large cells. However, our field data indicate more small‐sized zooplankton organisms above the shelf than offshore.     

The significance of chemical,isotopic, and detrital components in three coeval stalagmites from the superhumid southernmost Andes (53°S) as high-resolution palaeo-climate proxies

Stalagmites are important palaeo-climatic archives since their chemical and isotopic signatures have the potential to record high-resolution changes in temperature and precipitation over thousands of years. We present three U/Th-dated records of stalagmites (MA1–MA3) in the superhumid southern Andes, Chile (53°S). They grew simultaneously during the last five thousand years (ka BP) in a cave that developed in schist and granodiorite. Major and trace elements as well as the C and O isotope compositions of the stalagmites were analysed at high spatial and temporal resolution as proxies for palaeo-temperature and palaeo-precipitation. Calibrations are based on data from five years of monitoring the climate and hydrology inside and outside the cave and on data from 100 years of regional weather station records.Water-insoluble elements such as Y and HREE in the stalagmites indicate the amount of incorporated siliciclastic detritus. Monitoring shows that the quantity of detritus is controlled by the drip water rate once a threshold level has been exceeded. In general, drip rate variations of the stalagmites depend on the amount of rainfall. However, different drip-water pathways above each drip location gave rise to individual drip rate levels. Only one of the three stalagmites (MA1) had sufficiently high drip rates to record detrital proxies over its complete length. Carbonate-compatible element contents (e.g. U, Sr, Mg), which were measured up to sub-annual resolution, document changes in meteoric precipitation and related drip-water dilution. In addition, these soluble elements are controlled by leaching during weathering of the host rock and soils depending on the pH of acidic pore waters in the peaty soils of the cave’s catchment area. In general, higher rainfall resulted in a lower concentration of these elements and vice versa. The Mg/Ca record of stalagmite MA1 was calibrated against meteoric precipitation records for the last 100 years from two regional weather stations. Carbonate-compatible soluble elements show similar patterns in the three stalagmites with generally high values when drip rates and detrital tracers were low and vice versa. δ¹³C and δ¹⁸O values are highly correlated in each stalagmite suggesting a predominantly drip rate dependent kinetic control by evaporation and/or outgassing. Only C and O isotopes from stalagmite MA1 that received the highest drip rates show a good correlation between detrital proxy elements and carbonate-compatible elements. A temperature-related change in rainwater isotope values modified the MA1 record during the Little Ice Age (～0.7–0.1 ka BP) that was ～1.5 °C colder than today. The isotopic composition of the stalagmites MA2 and MA3 that formed at lower drip rates shows a poor correlation with stalagmite MA1 and all other chemical proxies of MA1. ‘Hendy tests’ indicate that the degassing-controlled isotope fractionation of MA2 and MA3 had already started at the cave roof, especially when drip rates were low. Changing pathways and residence times of the seepage water caused a non-climatically controlled isotope fractionation, which may be generally important in ventilated caves during phases of low drip rates. Our proxies indicate that the Neoglacial cold phases from ～3.5 to 2.5 and from ～0.7 to 0.1 ka BP were characterised by 30% lower precipitation compared with the Medieval Warm Period from 1.2 to 0.8 ka BP, which was extremely humid in this region.     

An ice breeze mechanism for boundary-layer jets

The existence of a low-level (z=~1000 m) jet adjacent to a sea-ice boundary is investigated with a two-dimensional numerical model. A thermally-direct ice breeze circulation is induced by specifying an ice-sea surface temperature gradient, with the mean geostrophic wind parallel to the ice edge. Pressure changes associated with over-water mixed-layer development create an increase in geostrophic velocity that accounts for most of the increase in wind speed. A change in initial geostrophic wind direction has significant effects on location and intensity of the low-level jet; geostrophic winds parallel to the ice edge result in stronger jets than occur with cross-ice geostrophic winds. An inertial oscillation simulated by the model in 1-D makes a negligible contribution to the low-level jet.     

Stratospheric Photolysis Frequencies: Impact of an Improved Numerical Solution of the Radiative Transfer Equation

Numerical schemes for the calculation of photolysis rates are usually employed in simulations of stratospheric chemistry. Here, we present an improvement of the treatment of the diffuse actinic flux in a widely used stratospheric photolysis scheme (Lary and Pyle, 1991). We discuss both the consequences of this improvement and the correction of an error present in earlier applications of this scheme on the calculation of stratospheric photolysis frequencies. The strongest impact of both changes to the scheme is for small solar zenith angles. The effect of the improved treatment of the diffuse flux is most pronounced in the lower stratosphere and in the troposphere. Overall, the change in the calculated photolysis frequencies in the region of interest in the stratosphere is below about 20%, although larger deviations are found for H₂O, O₂, NO, N₂O, and HCl.     

Biochelates as a Cause of Metal Cycling Across the Redoxcline

The sharp concentration peak of the metals Cu, Cd and Zn at the redoxcline of the Framvaren Fjord, Norway, is described as an effect of chelation/complexation with organic ligands. The most dominating ligand is 2-mercaptobenzothiazole (MBT), which binds with a 2 : 1 ligand to metal stoichiometric ratio. MBT has the highest concentrations at the vicinity of the redoxcline where the oxidation of sulfide to elemental sulfur and sulfate is most extensive. We suggest the production being caused by sulfide oxidizing bacteria as we have not been able to detect MBT in pure cultures of sulfate reducing bacteria. Ni does not exhibit the same distribution as the other three metals due to lower preference for coordination with S and N donor atoms and a much lower rate for loss of water than Cu, Cd and Zn.