Eutrophication assessment of the Baltic Sea Protected Areas by available data and GIS technologies

Concerning increased degradation of marine ecosystems, there is a great political and institutional demand for an array of different tools to restore a good environmental status. Thereby, eutrophication is acknowledged as one of the major human induced stressors which has to be monitored and reduced. The present study concentrates on an assessment of the eutrophication status of the Baltic Sea Protected Areas by use of available data and GIS technologies. Two geodata layers were used for analysis: (1) a map on the eutrophication status of the Baltic Sea generated by the Helsinki Commission applying the HELCOM Eutrophication Assessment Tool (HEAT), and (2) modelled data on atmospheric nitrogen deposition made available by the European Monitoring and Evaluation Programme (EMEP). The results yielded comprehensive and conclusive data indicating that most of the BSPAs may be classified as being 'affected by eutrophication' and underlining the need to decrease the overall emissions of nutrients.     

Gravitational attraction and potential of spherical shell with radially dependent density

Solutions to the direct problem in gravimetric interpretation are well-known for wide class of source bodies with constant density contrast. On the other hand, sources with non-uniform density can lead to relatively complicated formalisms. This is probably why analytical solutions for this type of sources are rather rare although utilization of these bodies can sometimes be very effective in gravity modeling. I demonstrate an analytical solution to that problem for a spherical shell with radial polynomial density distribution, and illustrate this result when applied to a special case of 5th degree polynomial. As a practical example, attraction of the normal atmosphere is calculated.     

Holocene temperature variations at a high-altitude site in the Eastern Alps: a chironomid record from Schwarzsee ob Sölden, Austria

Few well-dated, quantitative Holocene temperature reconstructions exist from high-altitude sites in the Central Eastern Alps. Here, we present a chironomid-based quantitative reconstruction of mean July air temperatures (T_July) throughout the Holocene for a remote high-mountain lake, Schwarzsee ob Sölden, situated above the treeline at 2796 m a.s.l. in the Austrian Alps. Applying a chironomid-temperature inference model developed from lakes of the Alpine region to a high-resolution chironomid record from the lake provides evidence for early Holocene (ca 10000–8600 cal yr BP) T_July of up to 8.5 °C, i.e. >4 °C above the modern (1977–2006) mean July temperature. The reconstruction reveals the so-called ‘8.2-ka cold event’ centered at ca 8250–8000 cal yr BP with temperatures ca 3 °C below the early-Holocene thermal maximum. Rather warm (ca 6 °C) and productive conditions prevailed during ca 7900–4500 cal yr BP. The chironomid record suggests a climate transition between ca 5200 and 4500 cal yr BP to cooler T_July. A distinct cooling trend is evident from ca 4500 until ca 2500 cal yr BP. Thereafter, the study site experienced its coldest conditions (around 4 °C or less) throughout the rest of the Holocene, with the exception of the warming trend during the late 20th century. Beside other factors, the Northern Hemisphere summer insolation seems to be the major driving force for the long-term trends in T_July at high altitudes in the Eastern Alps. Due to the extreme location of the lake and the limited temperature range represented by the applied calibration data set, the chironomid-based temperature reconstruction fails to track phases of the late-Holocene climatic history with T_July cooler than 4 °C. Further chironomid-based palaeoclimate model and down-core studies are required to address this problem, provide more realistic T_July estimates from undisturbed high-altitude lakes in the Alps, and extract a reliable regional temperature signal.     

Age structure and recharge conditions of a coastal aquifer (northern Germany) investigated with 39Ar, 14C, 3H, He isotopes and Ne

A tide-influenced two-layer aquifer system in northern Germany was investigated using environmental dating tracers (³H, ³⁹Ar, ¹⁴C), the noble gas isotopes ³He, ⁴He and Ne. The study area is a marshland at the River Ems estuary, exposed to regular flooding until?AD 1000. The construction of dykes, artificial land drainage and groundwater abstraction define the hydraulic gradient. The aquifer depicts a pronounced age stratification with depth. Tritium concentrations above 0.03 TU are found only in the top 30?m. Two tritium-free samples between 20 and 30?m depth show ³⁹Ar ages of 130 and 250?years. Below a clay layer?Cabout 50?m below surface level (mbsl)?Call analysed samples are ³⁹Ar free and, thus, older than 900?years. The initial ¹⁴C activities were about 70 pmC. Resulting ¹⁴C ages increase with depth and increase up to 9,000?years, in agreement with minimal ³⁹Ar ages. Concentrations of radiogenic ⁴He correlate with ¹⁴C ages. Samples in a mid-depth range (20?C70 mbsl) show significant gas loss. The gas loss is assigned to recharge in a methane producing environment. Deduced ⁴He ages were used to assign this water to a infiltration period of about AD 1000.     

Vertex-centred discretization of multiphase compositional Darcy flows on general meshes

This paper concerns the discretisation on general 3D meshes of multiphase compositional Darcy flows in heterogeneous anisotropic porous media. Extending Coats’ formulation [15] to an arbitrary number of phases, the model accounts for the coupling of the mass balance of each component with the pore volume conservation and the thermodynamical equilibrium and dynamically manages phase appearance and disappearance. The spatial discretisation of the multiphase compositional Darcy flows is based on a generalisation of the Vertex Approximate Gradient scheme, already introduced for single-phase diffusive problems in [24]. It leads to an unconditionally coercive scheme for arbitrary meshes and permeability tensors. The stencil of this vertex-centred scheme typically comprises 27 points on topologically Cartesian meshes, and the number of unknowns on tetrahedral meshes is considerably reduced, compared with the usual cell-centred approaches. The efficiency of our approach is exhibited on several examples, including the nearwell injection of miscible CO₂ in a saline aquifer taking into account the vaporisation of H₂O in the gas phase as well as the precipitation of salt.     

A record of early to middle Holocene environmental change inferred from lake deposits beneath a sabkha sequence in the Central Sahara (Seggedim, NE Niger)

Seggedim is a remote site in NE Niger where previous studies demonstrated the presence of Holocene paleolake deposits beneath an existing sabkha. In 2005, we retrieved a 15-m core that contains a high-resolution record of early to middle Holocene environmental change. Mineralogical, chemical and petrographic data were used to infer paleoenvironmental conditions recorded by successive lake stages. An exceptionally stable lake regime existed from 10.6 to 7.3 cal ka BP. This regime, reflecting moist conditions, was characterized by deposition of continuously laminated diatomite with high organic matter content, formed under meromictic conditions, with very low detrital input. A lake regime shift occurred at 7.3 cal ka BP, interpreted as the beginning of a transition to arid conditions. This shift was initially marked by a change to predominantly clastic sedimentation, followed by increased sand input during later stages, culminating in the onset of the sabkha stage. Because of the presence of reworked organic material in the deposits, reliable radiocarbon dating of the succession of lake stages could not be achieved.     

Effects of multiple stressors on lakes in south-central Ontario: 15 years of change in lakewater chemistry and sedimentary diatom assemblages

Freshwater ecosystems are increasingly affected by human influences. Since the pre-industrial era, lakes of the Muskoka–Haliburton region of south-central Ontario have had increases in shoreline residential development and acid deposition. Previous research on 54 of these lakes, using sediment cores and diatom-based transfer functions, showed changes in lakewater pH and total phosphorus concentration between the preindustrial era and 1992. Since 1992, there has been further change, which we have documented for the same set of lakes, using similar methods. For example, dissolved organic carbon has increased and there have been significant increases in planktonic diatoms (e.g. Cyclotella stelligera) commonly associated with climate warming. More striking diatom changes have occurred in the past 15 years than between pre-industrial times and 1992. Significant changes observed in both chemical (e.g. pH, Ca, DOC) and biological data suggest that novel stressors, such as declines in lake calcium concentrations, acting in conjunction with climate and land-use change, have created ecosystems for which there are no historical analogs.