Chemical variation in a Proterozoic suite of granitoids extending across a mobile belt — craton boundary

Contrary to earlier opinions, the southwestern margin of the Baltic Shield was formed after the Svecokarelian orogenic event (2.2-1.8 Ga). During the initial stages of its formation (1.7-1.6 Ga), granitoid rocks intruded the southwestern margin and simultaneously also the already cratonized part of the shield. Among these granitoids, the most important chemical difference is between calc-alkalic differentiated granitoids to the west and alkalicalcic more evolved granites to the east of an intraorogenic “suture” (the Mylonite Zone). The chemical differences between alkali-calcic granites found on both sides of the interorogen boundary proper (the Protogine Zone) are less significant. As yet, a final choice cannot be made between wholly actualistic and non-actualistic, possibly intracratonic(?) variants of precursory plate-tectonic processes.     

A complete sea-breeze circulation cell derived from aircraft observations

Using an instrumented aircraft, a complete sea-breeze circulation cell was sampled from its offshore end to the sea-breeze front over land and up to a height of approximately 1000 m AMSL. Many of its typical features can be resolved in detail mainly by cross-sectional analysis. These are: the diverging onshore flow in the lower layers over the sea the convergence over land at the seabreeze front and the connected cross-frontal circulation, a distinct return flow in the upper layers, the propagation of the seaward end of the cell over water, as well as the propagation of the front over land, the baroclinicity as a driving mechanism of the cell and also budget and frontogenesis terms.     

Two distinct Precambrian terranes in the Southern Prince Charles Mountains, East Antarctica: SHRIMP dating and geochemical constraints

The Southern Prince Charles Mountains (SPCM) are mostly occupied by the Archaean Ruker Terrane. The Lambert Terrane crops out in the northeastern part of the SPCM. New geochemical and zircon U–Pb SHRIMP ages for felsic orthogneisses and granitoids from both terranes are presented. Orthogneisses from the Ruker and Lambert terranes differ significantly in their major and trace-element compositions. Those from the Ruker Terrane comprise two distinct groups: rare Y-depleted and abundant Y-undepleted. U–Pb isotopic data provide evidence for tonalite−trondhjemite emplacement at 3392 ± 9 and 3377 ± 9 Ma, pre-tectonic granite emplacement at 3182 ± 9 Ma, metamorphism(?) at c. 3145 Ma, and thermal events at c. 1300(?) and 626 ± 51 Ma. The Lambert Terrane orthogneisses probably originated in a continental magmatic arc. Zircon dating shows a very different geological history: pre-tectonic granitoid emplacement at 2423 ± 18 Ma, metamorphism at 2065 ± 23 Ma, and syn-tectonic granitoid emplacement at 528 ± 6 Ma, syn-tectonic pegmatite emplacement at 495 ± 18 Ma. The Lambert Terrane can be correlated with neither the Meso- to Neoproterozoic Beaver Terrane in the Northern PCM, which differs in isotopic composition, nor with the Archaean Ruker Terrane, which differs in both granitoid chemical composition and the timing of major geological events. It represents a Palaeoproterozoic orogen which experienced strong tectonic re-activation in Pan-African times. The Lambert Terrane has some geochronological features in common with the Mawson Block, which comprises south Australia and some areas in East Antarctica.     

Climatic Changes from 12,000 to 4,000 Years Ago in the Austrian Central Alps Tracked by Sedimentological and Biological Proxies of a Lake Sediment Core

Major and trace elements, minerals, and grain-size were analysed from the early to mid-Holocene (12 to 4 ky BP) period of a sediment core from the Alpine lake Oberer Landschitzsee (ObLAN, 2076 m a.s.l.), which is located on predominantly crystalline bedrock on the southern slopes of the Austrian Central Alps. Geochemistry and mineralogy were compared with diatom-inferred (Di-) ‘date of autumn mixing’ (A_mix), DOC, pH, and selected indicator pollen species from the same sediment core. Principal components analysis (PCA) indicated a positive correlation between processes triggered by temperature and precipitation (e.g., lake mixing, DOC). PCA grouped indicators of physical weathering and enhanced catchment run-off (sand, quartz, feldspar), elements of weathering (e.g., Ti, Rb, Mn) under dryer conditions (clay to silt fractions), and elements that probably were related to changes in redox conditions (Cu, Fe, S, Zn). The duration and height of the snow-pack played an important role in this high-alpine environment, affecting weathering, erosion, pH, and lake stratification. Low Alnus viridis pollen abundance, together with markers for increased elements of erosion, indicated extensive snow-pack. Changes in S coupled with As, and elements indicating increased weathering, reflected climate oscillations. LOI was affected by productivity and erosion. High (late) Di–A_mix coupled with increased Di-DOC indicated prolonged summers with increased productivity. Cold and wet (snow-rich) phases and subsequent melting caused low pH and a decoupling of the significant linear correlation between sedimentary Ca and Di-pH. Weathering and leaching during climate deteriorations opposed the long-term trend in a loss of cations and forced in-lake alkalinity generation during the following lake warming. Overall, the multi-proxy study indicated complex climate-driven processes within different time-scales (long-term trends, climate oscillations, seasonality). The climate oscillations within 12–5 ky BP corresponded well with the cool and wet phases known from central Europe suggesting a dominant common Atlantic climate impact. When Mediterranean climate established between 5 and 4 ky BP, its influence on the southern slopes of the Alps increased.     

The use of ‘bomb spike’ calibration and high-precision AMS C analyses to date salt-marsh sediments deposited during the past three centuries

A combination of ‘bomb spike’ calibration and conventional calibration of AMS ¹⁴C dating has been used to determine a detailed age-depth model for a 1-m sediment section collected from a salt marsh in Poole Harbour, southern England. These data were compared with the chronology obtained from ²¹⁰Pb analysis and ¹³⁷Cs age markers. We report post bomb values of over 1.46 F¹⁴C (> 146% modern ¹⁴C), and both the rising and falling limbs of the atmospheric ‘bomb spike’ are identified. Five pre-bomb samples were analysed using multi-target high-precision 2‰ AMS analysis, and after the replicates were combined the one-sigma uncertainty was as low as ± 9 ¹⁴C yr on some ages. These data, and an additional three normal-precision pre-bomb ¹⁴C samples, were calibrated using CALIB 5.0 and the chronology constrained using the ‘prior knowledge’ of independent age markers obtained from the analysis of pollen and spheroidal carbonaceous particle (SCPs). No agreement was found between the ¹⁴C ‘bomb spike’ dates and the CRS ²¹⁰Pb chronology modelled for this sequence. In addition, poor agreement was found between the signal of the 1960s weapons test fallout indicated by the ¹⁴C ‘bomb spike’ dates and the timing suggested by the ¹³⁷Cs data. This disagreement is attributed to the influence of the local discharge of ¹³⁷Cs from the former UKAEA site at Winfrith. We use our new chronology to confirm the existence of an acceleration in sedimentation rates in Poole Harbour during the last 100 yr previously reported for this site by Long et al. (Long, A.J., Scaife, R.G., Edwards, R.J. 1999. Pine Pollen in intertidal sediments from Poole Harbour, UK; implications for late-Holocene sediment accretion rates and sea-level rise. Quaternary International, 55, 3–16.), and conclude that ‘bomb spike’ ¹⁴C calibration dating may offer a more robust alternative to the use of ²¹⁰Pb chronologies for dating sediment deposition in salt-marsh environments. In addition, we demonstrate how the use of high-precision AMS analysis has the potential for reducing some of the uncertainties involved in the high-resolution dating of recent salt-marsh sediments.     

The timing of sub-solidus hydrothermal alteration in the Central Zone, Limpopo Belt (South Africa): Constraints from titanite U–Pb geochronology and REE partitioning

In the Central Zone of the Limpopo Belt (South Africa), Palaeoproterozoic granulite-facies metamorphism was superimposed on an earlier Archaean orogenic history. Previously determined ages of  2030–2020 Ma obtained from high-temperature chronometers (zircon, garnet, monazite) are generally thought to provide the best estimate of the peak of Palaeoproterozoic granulite-facies metamorphism in the Central Zone, whereas ages as young as  2006 Ma from late melt patches suggest that temperatures remained above the wet solidus for an extended period. We present a new MC-ICP-MS ²⁰⁷Pb–²⁰⁶Pb age of 2030.9 ± 1.5 Ma for titanite found in amphibolite- to greenschist-facies alteration zones developed adjacent to quartz vein systems and related pegmatites that cut a strongly deformed Central Zone metabasite. This age could potentially date cooling of rocks at this locality to temperatures below the wet solidus. Alternatively, the titanite could be inherited from the metabasite host, and the age determined from it date the peak of metamorphism. Integration of the geochronology with LA-ICP-MS trace element data for minerals from the metabasite, the hydrothermal vein systems and comparable rocks elsewhere shows that the titanite formed during the amphibolite-facies hydrothermal alteration, not at the metamorphic peak or during the greenschist-facies phase of veining. This suggests that high-grade rocks in the Central Zone have cooled differentially through the wet solidus, and provides timing constraints on when Palaeoproterozoic reworking in the Central Zone began. This study illustrates the potential of combined geochronological and high-resolution geochemical studies to accurately match mineral ages to distinct crustal processes.     

Lessons learned in remediation and restoration in the Oklahoma prairie: A review

For almost a decade the Tallgrass Prairie Preserve in Oklahoma has been used as a field laboratory for the investigation of aspects of the remediation and restoration of oil and brine spills. Objectives of this work have included: (1) simplification of the remediation process and lowering the cost of remediation; (2) the development of methods to accelerate or jump-start the restoration process; and (3) determining appropriate metrics for assessing the status of soil ecosystem recovery. This research has resulted in a number of lessons learned that will be presented here which can be exported to other exploration and production sites, especially sites located in sensitive ecosystems. Key observations have included the role of a fertilizer amendment in linking the remediation and restoration process at an oil-impacted site, the use of nematodes as ecological indicators in the restoration of oil- and brine-impacted sites, and the development of a two-stage process for remediation of brine impacted sites that does not include significant use of gypsum.     

Tomographic inversion of P410s delay times for simultaneous determination of P and S velocities of the upper mantle beneath the Baltic Shield

Teleseismic data recorded by stations in the Swedish National Seismic Network (SNSN) are used for a study of upper mantle structure beneath the Baltic Shield using the receiver function technique. The data show very clear conversions from the 410 and 660 km discontinuities. The signals associated with P to S conversions at these discontinuities arrive 1-2 s earlier than predicted by global models such as IASP91 or PREM. We interpret this as a manifestation of higher than average velocities in the mantle beneath the shield, consistent with lower than average global temperatures. For a 1400 km profile along the network, we observe variations of around 1 second in delay times of P410s and slightly less for P660s. Under the assumption that the mantle discontinuities are at a given constant depth, the delay times of the mantle converted phases are tomographically inverted to reveal P and S velocity structure below the stations. Synthetic tests show that this tomographic inversion has the potential to resolve P and S velocity variations at structural scales adequate for upper mantle studies. Results from application to real data appear to be consistent with independently produced mantle velocity structures deduced from normal tomographic arrival time data. For the P velocity model, a north-dipping body of (relatively) low velocity is found for the central part of the profile at 58-64°N. A sharp contrast from low to high velocities that may be associated with the Proterozoic-Archean boundary is found at 66°N.     

A QUANTITATIVE DETERMINATION OF A SECOND LINEAR LEAGUE USED IN NEW SPAIN

A linear league of about 4.19 km has often been cited as the only linear land league used in New Spain in the 16th Century, leading to significant underestimations of distances reported for that period. Data analysis of an itinerary written in the 1590's indicates a second Castilian league of 5.572 km was also used by travelers in New Spain. If applied where appropriate, this additional league evaluation should benefit historical geographical research in Spanish colonial North America.