Atmospheric chemistry of the monoterpene reaction products nopinone,camphenilone, and 4-acetyl-1-methylcyclohexene

Rate constants for the gas-phase reactions of OH radicals with nopinone (6,6-dimethylbicyclo[3.1.1]heptan-2-one) and camphenilone (3,3-dimethylbicyclo[2.2.1]heptan-2-one) and for the reactions of 4-acetyl-1-methylcyclohexene with OH and NO₃ radicals and O₃ have been measured at 296±2 K. The rate constants (cm³ molecule^–1 s^–1 units) obtained were, for reaction with the OH radical: nopinone, (1.43±0.37)×10^–11; camphenilone, (5.15±1.44)×10^–12; and 4-acetyl-1-methylcyclohexene, (1.29±0.33)×10^–10; for reaction with the NO₃ radical: 4-acetyl-1-methylcyclohexene, (1.05±0.38)×10^–11; and for reaction with O₃: 4-acetyl-1-methylcyclohexene, (1.50±0.53)×10^–16. These data are used to calculate the tropospheric lifetimes of these monoterpene atmospheric reaction products.     

Scenarios of land use and land cover change in the conterminous United States: Utilizing the special report on emission scenarios at ecoregional scales

Global environmental change scenarios have typically provided projections of land use and land cover for a relatively small number of regions or using a relatively coarse resolution spatial grid, and for only a few major sectors. The coarseness of global projections, in both spatial and thematic dimensions, often limits their direct utility at scales useful for environmental management. This paper describes methods to downscale projections of land-use and land-cover change from the Intergovernmental Panel on Climate Change's Special Report on Emission Scenarios to ecological regions of the conterminous United States, using an integrated assessment model, land-use histories, and expert knowledge. Downscaled projections span a wide range of future potential conditions across sixteen land use/land cover sectors and 84 ecological regions, and are logically consistent with both historical measurements and SRES characteristics. Results appear to provide a credible solution for connecting regionalized projections of land use and land cover with existing downscaled climate scenarios, under a common set of scenario-based socioeconomic assumptions.     

Interactions of nocturnal slope flows with ambient winds

A quasi-one-dimensional numerical model containing a prognostic turbulent kinetic energy parameterization and simplified approximations to horizontal gradients is used to study interactions of thermally induced nocturnal slope flows with following and opposing ambient winds. It is found that a following ambient wind causes the peak perturbation wind to be weaker and to be realized at a greater height, while an opposing ambient wind leads to a stronger perturbation wind at a lower height. The reason for this response lies in the interactions of the shears of the thermal and ambient components through the mechanical production of turbulent kinetic energy.     

Detailed bed topography and sediment load measurements for two stepdown flows in a laboratory flume

Streams and rivers, particularly smaller ones, often do not maintain steady flow rates for long enough to reach equilibrium conditions for sediment transport and bed topography. In particular, streams in small watersheds may be subject to rapidly changing hydrographs, and relict bedforms from previous high flows can cause further disequilibrium that complicates the prediction of sediment transport rates. In order to advance the understanding of how bedforms respond to rapid changes in flow rate,...     

Numerical Study of Tsunami Generated by Multiple Submarine Slope Failures in Resurrection Bay, Alaska, during the M W 9.2 1964 Earthquake

We use a viscous slide model of Jiang and LeBlond (1994) coupled with nonlinear shallow water equations to study tsunami waves in Resurrection Bay, in south-central Alaska. The town of Seward, located at the head of Resurrection Bay, was hit hard by both tectonic and local landslide-generated tsunami waves during the M _W 9.2 1964 earthquake with an epicenter located about 150 km northeast of Seward. Recent studies have estimated the total volume of underwater slide material that moved in Resurrection Bay during the earthquake to be about 211 million m³. Resurrection Bay is a glacial fjord with large tidal ranges and sediments accumulating on steep underwater slopes at a high rate. Also, it is located in a seismically active region above the Aleutian megathrust. All these factors make the town vulnerable to locally generated waves produced by underwater slope failures. Therefore it is crucial to assess the tsunami hazard related to local landslide-generated tsunamis in Resurrection Bay in order to conduct comprehensive tsunami inundation mapping at Seward. We use numerical modeling to recreate the landslides and tsunami waves of the 1964 earthquake to test the hypothesis that the local tsunami in Resurrection Bay has been produced by a number of different slope failures. We find that numerical results are in good agreement with the observational data, and the model could be employed to evaluate landslide tsunami hazard in Alaska fjords for the purposes of tsunami hazard mitigation.     

The 15 August 2007 Peru Earthquake and Tsunami: Influence of the Source Characteristics on the Tsunami Heights

The tsunami caused by the 2007 Peru earthquake (M_w 8.0) provoked less damage than by the seismic shaking itself (numerous casualties due to the earthquake in the vicinity of Pisco). However, it propagated across the Pacific Ocean and small waves were observed on one tide gauge in Taiohae Bay (Nuku Hiva, Marquesas, French Polynesia). We invert seismological data to recover the rupture pattern in two steps. The first step uses surface waves to find a solution for the moment tensor, and the second step uses body waves to compute the slip distribution in the source area. We find the slip distribution to consist of two main slip patches in the source area. The inversion of surface waves yields a scalar moment of 8.9 10²⁰ Nm, and body-wave inversion gives 1.4 10²¹ Nm. The inversion of tsunami data recorded on a single deep ocean sensor also can be used to compute a fault slip pattern (yielding a scalar moment of 1.1 10²¹ Nm). We then use these different sources to model the tsunami propagation across the Pacific Ocean, especially towards Nuku Hiva. While the source model taken from the body-wave inversion yields computed tsunami waves systematically too low with respect to observations (on the central Pacific Ocean DART buoy as on the Polynesian tide gauge), the source model established from the surface-wave inversion is more efficient to fit the observations, confirming that the tsunami is sensitive to the low frequency component of the source. Finally we also discuss the modeling of the late tsunami arrivals in Taiohae Bay using several friction coefficients for the sea bottom.     

Three-Dimensional Scalar Microfront Systems in a Large-Eddy Simulation of Vegetation Canopy Flow

Large-eddy simulation is used to reproduce neutrallystratified airflow inside and immediately above a vegetation canopy. A passive scalaris released from the canopy and the evolution of scalar concentration above the canopyis studied. The most significant characteristic of the scalar concentration is the repeatedformation and dissipation of scalar microfronts, a phenomenon that has been observedin nature. These scalar microfronts consist of downstream-tilted regions of highscalar concentration gradients. Computer visualization tools and a conditional samplingand compositing technique are utilized to analyze these microfronts. Peaks in positivepressure perturbation exceeding an experimental threshold are found to be effectiveindicators of scalar microfronts. Convergence of the streamwise velocity componentand divergence of the cross-stream velocity component are observed in the immediatevicinity of scalar microfronts, which helps explain their relatively longlifetimes. Many of these three-dimensional features have been observedin previous field studies of canopy flow.     

Composition and spatial organization of a cold seep community on the South Barbados accretionary prism: Tectonic, geochemical and sedimentary context

Deep faunal assemblages were observed on cold seeps, between 1000 and 2000m depth, along the southern termination of the Barbados accretionary prism, during the Caracolante II and Diapicar cruises. Faunal composition and microdistribution of a cold seep community were analyzed at one site using deep-sea photographs and seismic (3.5 Kz) profiles. The community is dominated by large mussels up to 20cm long (possibly related to the genus Bathymodiolus), tiny vesicomyid clams, and vestimentiferan clusters in which animals are up to 2m long. There is a high density of sponges (three species), bryozoans and gorgonians. Other taxa occasionally associated with this assemblage include galatheid crabs, anemones, holothurians and possibly pennatulaceans which are numerous at boundaries of the site. A typical deep-sea fauna of fish, asteroids and ophiuroids is also scattered about the vicinity. This seep community is distributed as a band of discontinuous colonies, 40–50m in width and more than 10km in length. Living colonies alternate with accumulations shells and bare areas. The substratum is hard mud covered by a ferrugineous crust and cemented by carbonates. The early diagenetic character of the bottom and the occurrence of biological assemblages indicate that seepages of sulphur and/or methane, which have been revealed along the decollement zone of the Barbados prism, must diffuse through the sea floor. These biological and geological features are located on the crests of NE-SW anticlinal ridges and mud volcanoes which have been built by diaprism.     

Particle fluxes to the interior of the Southern Ocean in the Western Pacific sector along 170°W

An array of five bottom-tethered moorings with 19 PARFLUX time-series sediment trap at three depths (1 and 2 km below the surface, and 0.7 km above the sea-floor) was deployed in the western Pacific sector of the Southern Ocean, along 170°W. The five stations were selected to sample settling particles in the main hydrological zones of the Southern Ocean. The sampling period spanned 425 days (November 28, 1996–January 23, 1998) and was divided into 13 or 21 synchronized time intervals. A total of 174 sequential samples were recovered and analyzed to estimate fluxes of total mass (TMF), organic carbon, carbonate, biogenic silica, and lithogenic particles. The fluxes of biogenic material were higher than anticipated, challenging the notion that the Southern Ocean is a low-productivity region. Organic carbon fluxes at 1 km depth within the Polar Frontal Zone and the Antarctic Zone were relatively uniform (1.7–2.3 g m⁻² yr⁻¹), and about twice the estimated ocean-wide average (ca. 1 g m⁻² yr⁻¹). Carbonate fluxes were also high and uniform between the Subantarctic Front and ca. 64°S (11–13 g m⁻² yr⁻¹). A large fraction of the carbonate flux in the Antarctic Zone was due to the presence of pteropod shells. Coccoliths were found only to the north of the Polar Front, and calcium carbonate became the dominant phase in the Subantarctic Zone. In contrast, carbonate particles were nearly absent near 64°S. Latitudinal variations in biogenic silica fluxes were substantial. The large opal flux (57 g m⁻² yr⁻¹) measured in the Antarctic Zone suggests that opal productivity in this region has been previously underestimated and helps to explain the high sedimentary opal accumulation often found south of the Polar Front. Unlike biogenic material, fluxes of lithogenic particles were among the lowest measured in the open-ocean (0.12–0.05 g m⁻² yr⁻¹), reflecting a very low dust input.     

Volcanic and Seismic Swarm Events on the Reykjanes Ridge and Their Similarities to Events on Iceland: Results of a Rapid Response Mission

On 21 May 1989, a major earthquake swarm on the Reykjanes Ridge at59°44 N, 29°32 W at a water depth of about 1000 m andabout 500 km southwest of Iceland was detected on both the WorldwideStandard Seismic Network (WWSSN) and Icelandic seismic networks. As part ofa multi-institutional response to this swarm, the Naval ResearchLaboratory arranged for a P3 Orion Aircraft to deploy sonobuoys and AXBTs inthe immediate vicinity of the swarm activity. The detection of the swarmmotivated a survey of the region in 1990, using the towed SeaMARC IIside-looking sonar system. In 1990–1991 the Russian ShirshovInstitute of Oceanology offered the use of its MIR deep-divingsubmersibles to investigate the rise axis for recent volcanism. During 1992,a scientific team comprised of five US and ten Russian scientists mobilizedthe twin, deep diving Russian submersibles to study the spreading axis ofthe Reykjanes Ridge. The resulting data analyses allows us to conclude thatthe 1989 seismic swarm event occurred adjacent to and east of the largeaxial high in the center of our survey area. The length, width and depthrange of the earthquakes were very similar to major seismic swarm eventsconfined to fissure systems in the Krafla region of Iceland. It is likelythat the earthquake swarm was located on a fresh, well-defined systemof fissures and faults extending south of the northernmost axial highstudied. The earthquake swarm was probably associated with an emanation oflava creating a region of high backscatter, located just to the east of thecentral axial high. In addition, the region of high-backscatterremains unsampled because it lay underneath the nadir of the processedSeaMARC tracks used to plan the submersible survey. However many sampleswere taken and structural studies of the evolving Reykjanes Ridge werecarried out.