Polar constituents isolated from Green River oil shale

This paper interprets the mass spectrometric, i.r. absorption and NMR data for 22 compounds obtained from a polar fraction of Green River shale. The major constituents analyzed are believed to be of the following compositional types: C_nH_2nO (cyclohexanols and chain isoprenoid ketones), C_nH_2n?10O (tetralones and indanones), C_nH_2n?7N (tetrahydroquinolines), C_nH_2n?11N (quinolines), C_nH_2n?1NO (alkoxypyrrolines), C_nH_2n?5NO₂ (maleimides), C_nH_2n?8 (tetralins), C_nH_2n?12 (naphthalenes) and C_nH_2n?14 (benzylbenzenes). This work expands the present information about nitrogen, oxygen and aromatic constituents indigenous to Green River shale.     

An extrusion energy absorber suitable for the protection of structures during an earthquake

A structure moving under the influence of an earthquake is normally required to absorb its own energy of motion. However, in many cases it is possible to attach to the structure energy absorbing devices which absorb most of its energy of motion. One such device is an energy absorber which works by extruding lead back and forth through an orifice. On being extruded the deformed lead recrystallizes immediately, thereby recovering its original mechanical properties before the next extrusion or stroke. Accordingly, the amount of energy absorbed is not limited by work hardening or fatigue of the lead, but rather by the heat capacity of the device, the melting point of lead being the upper limit to the operating temperature. Furthermore, the device is able to absorb energy during a large number of earthquakes. A number of 20 kN × 2 cm stroke to 200 kN × 26 cm stroke extrusion energy absorbers have been tested at rates of 10^?6 to 3.6 × 10^?6 cm/min. They behaved as ‘plastic solids’ or ‘coulomb dampers’ with nearly rectangular hysteresis loops and little rate dependence.     

Composition and Textual Characterization of Platinum-group Mineral (PGM) in Chromites from Zedang Ophiolite in Tibet, China

<正>1 Introduction Platinum-group elements(PGE)are mainly concentrated in some specific minerals known as PGMs,which commonly occur in podiform chromites of ophiolites.In-situ PGM assemblages in chromites can provide valuable information on the physico-chemical nature of the parental melt(s)from which chromitite     

A Comparative Study of Five Reference Materials and the Lombard Meteorite for the Determination of the Platinum‐Group Elements and Gold by LA‐ICP‐MS

A range of independently characterised reference materials (RMs) for LA‐ICP‐MS, used for the determination of the platinum‐group elements (PGE) and Au in a sulfide matrix, were analysed and compared: 8b, PGE‐A, NiS‐3, Po727‐T1, Po724‐T and the Lombard meteorite. The newly developed RM NiS‐3 was used as the RM for the calibration of all LA‐ICP‐MS analyses and the measured concentrations of the other RMs compared against their published concentrations. This data were also used to assess the consistency of concentrations calibrated against the different RMs. It was found that Po727‐T1 and 8b produced results that were comparable, within uncertainty, for all elements. Po727‐T1 also produced consistent results with NiS‐3 for all elements. All other RMs showed differences for some elements, especially Ru in Po724‐T, and Os, Ir and Au in PGE‐A. The homogeneity of the PGE and Au in each RM was assessed, by comparing the precision of multiple LA‐ICP‐MS spot analyses with the average uncertainty of the signal. Po724‐T, Po727‐T1 and the Lombard meteorite were found to be homogeneous for all elements, but 8b, PGE‐A and NiS‐3 were heterogeneous for some elements. This is the first direct comparison between a range of independently characterised PGE and Au LA‐ICP‐MS RMs.     

Fundamental and harmonic radiation in type III solar radio bursts

Type III solar radio bursts are investigated by modelling the propagation of the electron beam and the generation and subsequent propagation of waves to the observer. Predictions from this model are compared in detail with particle, Langmuir wave, and radio data from the ISEE-3 spacecraft and with other observations to clarify the roles of fundamental and harmonic emission in type III radio bursts. Langmuir waves are seen only after the arrival of the beam, in accord with the standard theory. These waves persist after a positive beam slope is last resolved, implying that sporadic positive slopes persist for some time, unresolved but in accord with the predictions of stochastic growth theory. Local electromagnetic emission sets in only after Langmuir waves are seen, in accord with the standard theory, which relies on nonlinear processes involving Langmuir waves. In the events investigated here, fundamental radiation appears to dominate early in the event, followed and/or accompanied by harmonic radiation after the peak, with a long-lived tail of multiply scattered fundamental or harmonic emission extending long afterwards. These results are largely independent of, but generally consistent with, the conclusions of earlier works.     

Mode coupling due to twisting of magnetic field lines

A new approach to the theory of mode coupling in an inhomogeneous, birefringent medium is used to treat mode coupling in a magnetized plasma with a twisted magnetic field. The twist introduces a resonance, corresponding to the rate of twisting being equal to the rate of generalized Faraday rotation. When this resonance occurs it introduces a new regime of strong mode coupling. The implications of this regime are discussed in connection with the long-standing problem in solar radiophysics that mode coupling appears to be stronger than theory implies, but no obvious resolution of the problem is found.     

The latitudinal distribution of carbon monoxide across the pacific from California to Antarctica

The results of a research study of the carbon monoxide concentration from California to 90° S, Antarctica are presented. The data both extend and support other research studies of the latitudinal distribution of carbon monoxide in that higher concentrations are evident over the Northern Hemisphere than over the Southern Hemisphere. Carbon monoxide concentrations range between 50 to 60 ppb with a few peaks into the 60s in the latitudinal area south of the ITCZ and values of 80 ppb or higher at latitudes north of Hawaii. A comparison is also made of carbon monoxide and ozone concentrations along the flight tract between California and Antarctica, over the Ellsworth Mountains of Antarctica, and between 78° S and the South Pole. These ozone-carbon monoxide data show statistically significant negative correlations in the upper troposphere and lower stratosphere over Antarctica. It is believed that this is a good indication of mixing across the tropopause.     

Modelling the bar in the centre of the starburst galaxy M82

We present VLA A-array 21-cm atomic hydrogen (H  i ) absorption observed against the central region of the starburst galaxy M82 with an angular resolution of ∼1.3 arcsec (≃20 pc). These observations, together with MERLIN H  i absorption measurements, are compared with the molecular (CO) and ionized ([Ne  ii ]) gas distributions and are used to constrain the dynamics and structure of the ionized, neutral and molecular gas in this starburst.
A position–velocity diagram of the H  i distribution reveals an unusual 'hole' feature which, when previously observed in CO, has been interpreted as an expanding superbubble contained within a ring of gas in solid body rotation. However, we interpret this feature as a signature of a nearly edge-on barred galaxy. In addition, we note that the CO, H  i and [Ne  ii ] position–velocity diagrams reveal two main velocity gradients, and we interpret these as gas moving on x₁- and x₂-orbits within a bar potential. We find the best fit to the data to be produced using a bar potential with a flat rotation curve velocity v _b=140 km s⁻¹ and a total length of 1 kpc, a non-axisymmetry parameter q =0.9, an angular velocity of the bar Ω_b=217 km s⁻¹ arcsec⁻¹, a core radius R _c=25 pc, an inclination angle i =80° and a projected angle between the bar and the major axis of the galaxy φ '=4°. We also discuss the orientation of the disc and bar in M82.     

The generation of non aspect sensitive plasma density irregularities by field aligned drifts in the lower ionosphere

A theory of the generation of plasma density irregularities with virtually no aspect sensitivity, in the lower ionosphere at high latitudes, by electron drifts aligned with the geomagnetic field, is presented. The theory is developed through fluid equations in which the destabilising mechanism involves positive feedback from electron collisional heating. When field aligned electron drift speeds exceed a few km s^–1, this effect destabilises waves with wavelengths in excess of a few tens of metres in the lower E-region, where collisional effects are sufficiently large. Furthermore, the threshold conditions are almost independent of the wave propagation direction and the unstable waves propagate at speeds well below the ion acoustic speed. The role that this new instability may play in recent radar backscatter observations of short scale irregularities propagating in directions close to that of the geomagnetic field, in the lower E-region is also considered.