Classifying zones of suitability for manual drilling using textural and hydraulic parameters of shallow aquifers: a case study in northwestern Senegal

A method is proposed that uses analysis of borehole stratigraphic logs for the characterization of shallow aquifers and for the assessment of areas suitable for manual drilling. The model is based on available borehole-log parameters: depth to hard rock, depth to water, thickness of laterite and hydraulic transmissivity of the shallow aquifer. The model is applied to a study area in northwestern Senegal. A dataset of boreholes logs has been processed using a software package (TANGAFRIC) developed during the research. After a manual procedure to assign a standard category describing the lithological characteristics, the next step is the automated extraction of different textural parameters and the estimation of hydraulic conductivity using reference values available in the literature. The hydraulic conductivity values estimated from stratigraphic data have been partially validated, by comparing them with measured values from a series of pumping tests carried out in large-diameter wells. The results show that this method is able to produce a reliable interpretation of the shallow hydrogeological context using information generally available in the region. The research contributes to improving the identification of areas where conditions are suitable for manual drilling. This is achieved by applying the described method, based on a structured and semi-quantitative approach, to classify the zones of suitability for given manual drilling techniques using data available in most African countries. Ultimately, this work will support proposed international programs aimed at promoting low-cost water supply in Africa and enhancing access to safe drinking water for the population.     

Pyroclastic density currents at Stromboli volcano (Aeolian Islands,Italy): a case study of the 1930 eruption

Pyroclastic density currents (PDC) related to paroxysmal eruptions have caused a large number of casualties in the recent history of Stromboli. We combine here a critical review of historical chronicles with detailed stratigraphic, textural, and petrographic analyses of PDC deposits emplaced at Stromboli over the last century to unravel the origin of currents, their flow mechanism and the depositional dynamics. We focus on the 1930 PDC as they are well described in historical accounts and because the 1930 eruption stands as the most voluminous and destructive paroxysm of the last 13 centuries. Stromboli PDC deposits are recognizable from their architecture and the great abundance of fresh, well-preserved juvenile material. General deposit features indicate that Stromboli PDC formed due to the syn-eruptive gravitational collapse of hot pyroclasts rapidly accumulated over steep slopes. Flow channelization within the several small valleys cut on the flanks of the volcano can enhance the mobility of PDC, as well as the production of fine particles by abrasion and comminution of hot juvenile fragments, thereby increasing the degree of fluidization. Textural analyses and historical accounts also indicate that PDC can be fast (15–20 m/s) and relatively hot (360–700 °C). PDC can thus flow right down the slopes of the volcano, representing a major hazard. For this reason, they must be adequately taken into account when compiling risk maps and evaluating volcanic hazard on the Island of Stromboli.     

On‐Site Vapor‐Phase Analysis as a Novel Approach for Monitoring Groundwater Wells

The results of comprehensive field testing of on‐site vapor‐phase‐based groundwater monitoring methods are presented to demonstrate their utility as a robust and cost‐effective approach for rapidly obtaining volatile organic compounds (VOCs) concentration data from a monitoring well. These methods—which rely on sensitive, commercially available field equipment to analyze vapor in equilibrium with groundwater—proved easy to implement and can be tailored to site‐specific needs, including multilevel sampling. During field testing, low‐flow groundwater concentrations could be reasonably estimated using submerged passive vapor diffusion samplers or field equilibration of collected groundwater (R² = 0.85 to 0.96). These two methods are not as reliant on in‐well mixing to overcome vertical stratification within wells as simpler headspace methods. The importance of well and aquifer‐specific factors on concentration data (and therefore method selection) is highlighted, including the effect of changing in‐well patterns due to seasonal temperature gradients. Results indicated that vertical stratification was relatively limited within the set of wells included in these studies, resulting in similar performance for short depth‐discrete passive vapor diffusion samplers (constructed from 40‐mL vials) and longer samplers (2.5 to 5 feet in length) designed to cover a larger portion of the screened interval. A year‐long, multi‐event evaluation demonstrated that vapor‐phase‐based monitoring methods are no more variable than conventional groundwater monitoring methods, with both types subject to similar spatial and temporal variability that can be difficult to reduce. Vapor sampling methods represent a promising approach for estimation of groundwater concentrations by reducing the cost liabilities associated with monitoring while providing a more sustainable approach.     

Geophysical investigation using resistivity and GPR methods: a case study of a lubricant oil waste disposal area in the city of Ribeirão Preto,São Paulo,Brazil

Geophysics has been shown to be effective in identifying areas contaminated by waste disposal, contributing to the greater efficiency of soundings programs and the installation of monitoring wells. In the study area, four trenches were constructed with a total volume of about 25,000 m³. They were almost totally filled with re-refined lubricating oil waste for approximately 25 years. No protection liners were used in the bottoms and laterals of the disposal trenches. The purpose of this work is to evaluate the potential of the resistivity and ground penetrating radar (GPR) methods in characterizing the contamination of this lubricant oil waste disposal area in Ribeirão Preto, SP, situated on the geological domain of the basalt spills of the Serra Geral Formation and the sandstones of the Botucatu Formation. Geophysical results were shown in 2D profiles. The geophysical methods used enabled the identification of geophysical anomalies, which characterized the contamination produced by the trenches filled with lubricant oil waste. Conductive anomalies (smaller than 185 Ωm) immediately below the trenches suggest the action of bacteria in the hydrocarbons, as has been observed in several sites contaminated by hydrocarbons in previously reported cases in the literature. It was also possible to define the geometry of the trenches, as evidenced by the GPR method. Direct sampling (chemical analysis of the soil and the water in the monitoring well) confirmed the contamination. In the soil analysis, low concentrations of several polycyclic aromatic hydrocarbons (PAHs) were found, mainly naphthalene and phenanthrene. In the water samples, an analysis verified contamination of the groundwater by lead (Pb). The geophysical methods used in the investigation provided an excellent tool for environmental characterization in this study of a lubricant oil waste disposal area, and could be applied in the study of similar areas.     

Changes in cetacean presence,relative abundance and distribution over 20 years along a trans‐regional fixed line transect in the Central Tyrrhenian Sea

From 1989 to 1992, systematic cetacean surveys were carried out twice weekly along a trans‐regional fixed transect in the Central Tyrrhenian Sea, utilising passenger ferries as research platforms. Using the same protocol and supervised by the same investigators, the research restarted in 2007, providing the opportunity to compare consistent data over a long 20‐year period. The monitored transect (Civitavecchia‐Golfo Aranci) runs along a strategic area just outside the southeastern border of the Pelagos Sanctuary. Over the last two decades, an increasing trend of temperature and salinity, in the deep and intermediate layers, has been documented in the region, as well as general changes over the Mediterranean basin. These changes, together with the increasing impact of some pressures (e.g. maritime traffic) may have led to changes in oceanographic and anthropogenic features and, subsequently, in cetacean presence and distribution. The research aimed to verify whether any changes occurred in the pattern of cetacean occurrence over the 20‐year period along the representative transect in the Central Tyrrhenian Sea. Data from 90 summer weekly runs undertaken in the 1990s were compared with data obtained from 95 runs undertaken in the 2000s. Each ferry run was considered an independent statistical unit: the encounter rate (ER = number of sightings per hour spent on effort) was calculated to compare relative abundance between periods, years and months. Spatial analysis was performed on geographical data using Kernel analysis to map the distribution of sightings. Logistic regression (GLM) was performed to compare habitat preference. Total encounter rate in the 1990s (ER = 0.59 ± CI 0.08) was significantly lower (P < 0.01) compared with the 2000s (ER = 0.94 ± CI 0.15). The same seven out of eight species known for their regular presence in the Mediterranean Sea were sighted in both the investigated periods. The most common species were striped dolphin (Stenella coeruleoalba), fin whale (Balaenoptera physalus) and common bottlenose dolphin (Tursiops truncatus). Neither the pilot whale nor any other rare or occasional species were sighted during the 6 years of the study. Despite the time span, no dramatic changes were observed for any species, bar fin whale, in terms of distribution, relative abundance, group size or habitat preference. Sightings of fin whale have surprisingly increased (+300%, P< 0.001), and their spatial and temporal distribution and habitat preference showed a radical difference between the two periods. The 2000s surveys confirmed the existence of high density areas of cetaceans, especially of fin whale, and the consequent necessity of specific legislative acts for cetacean conservation.     

Removal of Pyridine from Aqueous Solution by Adsorption on an Activated Carbon Cloth

Pyridine is a very toxic pollutant that has to be removed from wastewater. In this work, adsorption of pyridine on activated carbon cloth (ACC) is studied as a possible alternative for eliminating pyridine from aqueous solution. The ACC was produced from polyacrylonitrile. The adsorption equilibrium data of pyridine on ACC was obtained in a batch adsorber. The experimental data was interpreted with the isotherms of Langmuir, Freundlich, and Prausnitz‐Radke (PR), and the PR isotherm better represented the experimental data. The capacity of ACC for adsorbing pyridine was favored increasing the solution pH from 3 to 6, and this effect was due to the π–π dispersive and electrostatic interactions between the pyridine species in solution and the surface complexes of ACC. The modified Langmuir model fitted reasonably well the influence of pH on the adsorption capacity. In this model was assumed that both neutral pyridine and pyridinium were simultaneously adsorbed on ACC accordingly to the experimental results. The adsorption capacity was almost independent of temperature. The reversibility study revealed that 75% of the pyridine can be desorbed from ACC indicating that part of the pyridine was irreversibly adsorbed, and possibly chemisorbed.     

Seismic stratigraphy of Lago Puyehue (Chilean Lake District): new views on its deglacial and Holocene evolution

Prior to the collection of a series of sediment cores, a high- and very-high-resolution reflection seismic survey was carried out on Lago Puyehue, Lake District, South-Central Chile. The data reveal a complex bathymetry and basin structure, with three sub-basins separated by bathymetric ridges, bedrock islands and interconnected channels. The sedimentary infill reaches a thickness of >200 m. It can be sub-divided into five seismic-stratigraphic units, which are interpreted as: moraine, ice-contact or outwash deposits (Unit I), glacio-lacustrine sediments rapidly deposited in a proglacial or subglacial lake at the onset of deglaciation (Unit II), lacustrine fan deposits fed by sediment-laden meltwater streams in a proglacial lake (Unit III), distal deposits of fluvially derived sediment in an open, post-glacial lake (Unit IV) and authigenic lacustrine sediments, predominantly of biogenic origin, that accumulated in an open, post-glacial lake (Unit V). This facies succession is very similar to that observed in other glacial lakes, and minor differences are attributed to an overall higher depositional energy and higher terrigenous input caused by the strong seismic and volcanic activity in the region combined with heavy precipitation. A long sediment core (PU-II core) penetrates part of Unit V and its base is dated as 17,915 cal. yr. BP. Extrapolation of average sedimentation rates yields an age of ca. 24,750 cal. yr. BP for the base of Unit V, and of ca. 28,000 cal. yr. BP for the base of Unit IV or for the onset of open-water conditions. This is in contrast with previous glacial-history reconstructions based on terrestrial records, which date the complete deglaciation of the basin as ca. 14,600 cal. yr. BP. This discrepancy cannot be easily explained and highlights the need for more lacustrine records from this region. This is the second in a series of eight papers published in this special issue dedicated to the 17,900 year multi-proxy lacustrine record of Lago Puyehue, Chilean Lake District. The papers in this special issue were collected by M. De Batist, N. Fagel, M.-F. Loutre and E. Chapron.     

Deposition and tectonic setting of the Palaeoproterozoic Castelo dos Sonhos metasedimentary formation,Tapajós Gold Province,Amazonian Craton,Brazil: age and isotopic constraints

The Castelo dos Sonhos Formation (CSF) represents a relic of a sedimentary basin located in the southeastern Tapajós Gold Province (TGP), at its boundary with the Iriri–Xingu Domain (IX), south of the Amazonian Craton. The formation comprises mature, coarse-grained metasandstones (quartz-arenites) intercalated with auriferous metaconglomerates with clasts of quartz and subordinately of banded iron formation, quartzite, schist, and felsic metavolcanic rocks. Lithology, planar, channelled, and large-scale cross-bedding suggest deposition in continental setting by the braided fluvial system associated with alluvial fans and subordinate aeolian dunes. The rocks underwent very low metamorphism and gently synformal folding, and were intruded by andesites and granitoids (2011–1918 Ma). U–Pb LA-ICP-MS zircon data indicate maximum depositional ages of 2050 Ma (metaconglomerate) and 2074, 2088, and 2104 Ma (metasandstones). Hence, deposition occurred at 2050–2011 Ma, slightly preceding or being coeval with the onset of the orogenic phase in TGP (2030–1956 Ma). The quartz-arenite composition, zircon U–Pb data, and negative εHf (?1.3 to ?13.0) and εNd (?2.9 to ?5.3) values indicate: (1) quartzose provenance, (2) prolonged transport and recycling of sedimentary sources, (3) multiple age peaks (2050–3700 Ma), with predominant sources of 2100 and 2750 Ma, and (4) long crustal residence time for the source rocks. Source areas were Rhyacian–Siderian orogenic belts to Mesoarchaean terranes of the Amazonian Craton located to the east, southeast, and northeast of TGP, along with Palaeoarchaean and Eoarchaean detrital zircons recycled from older sedimentary rocks. We interpret CSF as part of a larger foreland system related to the evolution of Rhyacian orogens, currently represented by the Bacajá and Santana do Araguaia domains. The present location of CSF in the easternmost TGP, close to its boundary with IX, is due to rifting (1.89–1.80 Ga) that produced the Uatumã Silicic Large Igneous Province (Uatumã SLIP), and the juxtaposition of the crustal domains is supported by gravity data.