Eastern Mediterranean sea during the last glacial maximum; an 18,000-years B.P. reconstruction

An ecological transfer function based on the distribution of planktonic foraminifera in 66 Mediterranean and 8 North Atlantic surface-sediment samples is used to estimate sea-surface temperatures and salinities for the eastern Mediterranean during the last glacial maximum (18,000 yr B.P.). The present-day distribution of planktonic foraminifera can be explained by four faunal assemblages, each of which has diagnostic environmental preferences. Factor 1 is a tropical-subtropical assemblage; factor 2 is a transitional assemblage; factor 3 is a low-salinity assemblage; and factor 4 is a subpolar assemblage. The geographic distribution of these faunal assemblages reflect the variation in overlying hydrographic conditions. The 18,000-yr B.P. samples were selected based on total faunal stratigraphy, oxygen-isotope stratigraphy, and previously determined radiometric dates for eastern Mediterranean volcanic ash layers. Estimated temperature and salinity patterns show that the greatest change between present-day and 18,000-yr B.P. sea-surface conditions existed in the Aegean Sea and immediately south of Crete. The winter temperature anomaly (18,000 yr B.P.-present) within the Aegean Sea is 6°C cooler than present. In contrast to this, the maximum summer temperature anomaly exists to the south of Crete, where sea-surface temperatures were 4°C cooler than present. Estimated sea-surface salinities also show that the greatest change took place within the Aegean Sea, being 5‰ less saline than present. The estimated temperature and salinity patterns seem to reflect changing drainage patterns during glacial times and the diversion of cool, low-salinity water into the Aegean Sea. The source of this glacial runoff appears to be large freshwater lakes that existed during this time over parts of eastern Europe and western Siberia.     

Cosmogenic nuclide methods for measuring long-term rates of physical erosion and chemical weathering

Understanding the evolution of geochemical and geomorphic systems requires measurements of long-term rates of physical erosion and chemical weathering. Erosion and weathering rates have traditionally been estimated from measurements of sediment and solute fluxes in streams. However, modern sediment and solute fluxes are often decoupled from long-term rates of erosion and weathering, due to storage or re-mobilization of sediment and solutes upstream from the sampling point. Recently, cosmogenic nuclides such as ¹⁰Be and ²⁶Al have become important new tools for measuring long-term rates of physical erosion and chemical weathering. Cosmogenic nuclides can be used to infer the total denudation flux (the sum of the rates of physical erosion and chemical weathering) in actively eroding terrain. Here we review recent work showing how this total denudation flux can be partitioned into its physical and chemical components, using the enrichment of insoluble tracers (such as Zr) in regolith relative to parent rock. By combining cosmogenic nuclide measurements with the bulk elemental composition of rock and soil, geochemists can measure rates of physical erosion and chemical weathering over 1000- to 10,000-year time scales.     

Particle transport and distribution on the Mars Science Laboratory mission: Effects of triboelectric charging

We report on the nature of fine particle (<150 μm) transport under simulated martian conditions, in order to better understand the Mars Science Laboratory’s (MSL) sample acquisition, processing and handling subsystem (SA/SPaH). We find that triboelectric charging due to particle movement may have to be controlled in order for successful transport of fines that are created within the drill, processed through the Collection and Handling for In situ Martian Rock Analysis (CHIMRA) sample handing system, and delivered to the Sample Analysis at Mars (SAM) and Chemistry and Mineralogy (CheMin) instruments. These fines will be transferred from the surface material to the portioner, a 3 mm diameter, 8 mm deep distribution center where they will drop ∼2 cm to the instrument inlet funnels. In our experiments, movement of different material including terrestrial analogs and martian soil simulants (Mars Mojave Simulant - MMS) resulted in 1-7 nanocoulombs of charge to build up for several different experimental configurations. When this charging phenomenon occurs, several different results are observed including particle clumping, adherence of material on conductive surfaces, or electrostatic repulsion, which causes like-charged particles to move away from each other. This electrostatic repulsion can sort samples based upon differing size fractions, while adhesion causes particles of different sizes to bind into clods. Identifying these electrostatic effects can help us understand potential bias in the analytical instruments and to define the best operational protocols to collect samples on the surface of Mars.     

A new model for barred spiral galaxies

Computer simulations are used to demonstrate that normal spiral galaxies with symmetrically warped arms can appear to have bar and bar-within-ring structures when viewed from appropriate position angles.     

Ground viscosity and stiffness measurements for near surface seismic velocity

In land surveys, the weathering layer can often distort the seismic signal due to it passing through rapid velocity and density changes, dispersion, scattering and inelastic absorption. In a simple spring‐dashpot model for the earth response, an equivalent medium groups these complex phenomena into two parameters only; these are called ground viscosity and ground stiffness. The most recent controllers for vibrators can estimate both parameters. To validate these measurements, Saudi Aramco conducted an experiment measuring ground viscosity and stiffness from two different vibrator control systems over an area of varying terrain conditions, including unconsolidated sand and limestone outcrop. The two systems measured different values, but detected similar trends that correlated well with weathering conditions and surface geology, e.g. lower viscosity values on the outcrop than on the sand. The ratio of ground viscosity to ground stiffness can approximate the shallow S‐wave velocity, which we converted into P‐wave velocity through calibration with sparse uphole data. Static corrections incorporating this velocity information somewhat improved the focusing of seismic time sections. This new approach does not require additional acquisition efforts, and can model shallow complex formations in arid areas where classical static methods often fail.     

Numerical Modeling of Emulsified Oil Distribution in Heterogeneous Aquifers

In situ anaerobic bioremediation using edible oil emulsions will be most effective if the oil droplets can be brought into close contact with the contaminant to be treated. However, uniformly distributing oil in heterogeneous aquifers can be difficult. The impact of injection conditions on emulsion distribution in a three-dimensional heterogeneous aquifer is examined using MODFLOW and RT3D. Emulsion retention is simulated using a rate-limited Langmuir isotherm. Volume and flow contact efficiency are shown to be functions of mass of oil injected, injection fluid volume, well spacing, and injection sequence. Regression equations are developed relating dimensionless scaling factors to expected contact efficiency for area treatment and barriers. Cleanup time for uncontacted zones is estimated using a mobile-immobile zone modeling approach.     

DDT,PCB and benzo(a)pyrene levels in white croaker (Genyonemus lineatus) from southern California

In 1978 the California Department of Fish and Game carried out a major, independent sportfishing survey in southern California. The results of that survey indicated that approximately one million angler-trip hours per year were spent fishing and that one in three fish caught was a white croaker (Genyonemus lineatus). There was no attempt by the Department of Fish and Game to determine the disposition of caught fish. We conducted a subsequent survey in 1980 which included 12 popular sportfishing sites in the Los Angeles area. Our results also indicated that one in three fish caught was a white croaker. In addition our survey showed that 82% of the sportfishermen ate the white croaker they caught and the median consumption was 14.8 g day^?1 person^?1. White croaker were then sampled by hook-and-line from 11 of the 12 survey sites plus two control sites and analysed for PCB, DDT and BaP. Median PCB levels ranged from 0.014 to 0.41 mg wet kg^?1; median DDT from 0.059 to 7.5 mg wet kg^?1 and BaP was below detectable limits of 1 ng for all sites.     

The “North American shale composite”: Its compilation,major and trace element characteristics

The compilation and major element composition of the “North American shale composite” (NASC) are reported for the first time, along with redeterminations for the REE and selected other elements by modern, high precision analytical methods. The NASC is not strictly of North American origin; 5 of the constituent samples are from Africa and Antarctica, and 15 are from unspecified locations. The major element composition of the NASC compares quite closely with other average shale compositions. New analyses of the NASC document that significant portions of the REE and some other trace elements are contained in minor phases (zircon and possibly other minerals) and that their uneven distribution in the NASC powder appears to have resulted in heterogeneity among analyzed aliquants. The results of this study show that the REE distributions of detrital sediments can be dependent to some extent on their minor mineral assemblages and the sedimentological factors that control these assemblages. Consequently, caution should be exercised in the interpretation of the REE distributions of sediment samples as they may be variable and biased relative to average REE distribution of the crustal rocks supplying detritus. These effects appear to be largely averaged out in sediment composites, with the result that their REE distributions are more likely to be representative of their provenances.     

Environmental Issues Pertaining to the Kwale Mineral Sands Project,Kenya's South Coast—Reply

Tiomin Resources Inc. (“Tiomin”), the proponent of the Kwale Mineral Sands Project in Kenya, presents a response to the article authored by J. O. Z. Abuodha and P. O. Hayombe, entitled “Protracted Environmental Issues on a Proposed Titanium Minerals Development in Kenya's South Coast”, published in Volume 24, Number 2, April–June 2006. This article contains a series of inaccuracies, some grossly misleading and many statements relate to outdated information. Tiomin is greatly concerned at the publication of such a misleading report and is obliged to state the facts correctly. This response seeks to identify the misrepresentation of statements and/or facts in the article and present a correct and accurate perspective on the environmental issues of the project.