Volatile retention from cometary impacts on the Moon

Impacts of comets and asteroids play an important role in volatile delivery on the Moon. We use a novel method for tracking vapor masses that reach escape velocity in hydrocode simulations of cometary impacts to explore the effects of volatile retention. We model impacts on the Moon to find the mass of vapor plume gravitationally trapped on the Moon as a function of impact velocity. We apply this result to the impactor velocity distribution and find that the total impactor mass retained on the Moon is approximately 6.5% of the impactor mass flux. Making reasonable assumptions about water content of comets and the comet size-frequency distribution, we derive a water flux for the Moon. After accounting for migration and stability of water ice at the poles, we estimate a total 1.3×10⁸-4.3×10⁹ metric tons of water is delivered to the Moon and remains stable at the poles over 1 Ga. A factor of 30 uncertainty in the estimated cometary impact flux is primarily responsible for this large range of values. The calculated mass of water is sufficient to account for the neutron fluxes poleward of 75° observed by Lunar Prospector. A similar analysis for water delivery to the Moon via asteroid impacts shows that asteroids provide six times more water mass via impacts than comets.     

Lu–Hf geochronology and trace element distribution in garnet: Implications for uplift and exhumation of ultra-high pressure granulites in the Sudetes, SW Poland

Combining Lu–Hf garnet geochronology with in situ trace element analyses in garnet allowed us to gain new insight into the metamorphic evolution of UHP–UHT rocks in the Stary Gierałtów region, in the Polish Sudetes. Prograde garnet growth recorded by Rayleigh-type heavy REE (HREE) zoning in the felsic granulites indicates that the obtained 386.6 ± 4.9 Ma Lu–Hf age represents the time of garnet crystallization on a prograde UHP metamorphic path. The surrounding rocks were metamorphosed at the same time as indicated by 381.2 ± 6.7 Ma Sm–Nd garnet age obtained for the mid-crustal metapelites. The second metamorphic episode, which affected most of the lower crust in the Orlica–Śnieżnik Massif (OSM) occurred at ca. 340 Ma as determined by U–Pb zircon and Sm–Nd garnet dating of granulites in this and previous studies is interpreted as a high temperature event, which took place on a retrograde path.

Trace element distribution in garnets from the layered granulites showed significant differences in distribution of medium and HREE in garnets from mafic and felsic protoliths over the course of the metamorphic evolution. This had strong impact on the isotopic dating results and led to “decoupling” of the Sm–Nd and Lu–Hf clocks, which recorded timing of the two different metamorphic episodes separated by as much as 40 Ma. Moreover, the preservation of the HREE growth zonation profile in garnets from the felsic granulites whose minimum metamorphic temperature was established at 900 °C implies that the Lu–Hf system under relatively dry conditions does not undergo significant diffusional re-equilibration even at such extreme temperatures and therefore it sill provides the age of prograde garnet growth. Under hydrous conditions, at least some resetting will take place, as documented by the partially relaxed HREE zonation profile in the amphibolitised mafic granulite, which yielded a 10 Ma younger age. The HREE distribution study appeared to be a particularly valuable and essential tool, which allowed us to distinguish garnet growth from post-growth complexities and hence, provide improved age interpretation. Medium REE, on the other hand, did not show any obvious correlation with the isotopic signature of garnet.

Two distinct metamorphic episodes recorded in the Stary Gierałtów region show that buoyancy-driven uplift of UHP rocks can be arrested at the base of a continental crust if not supported by any additional force. In our case study, the UHP rocks would have never reached the surface if their uplift had not been resumed after a long pause under a different tectonic regime. The multistage, discontinuous uplift revealed by the UHP rocks of the OSM provides a new scenario for the exhumation of continental crust from mantle depths distinct from the fast-track exhumation histories recognized in UHP terranes elsewhere.     

Calorimetric study of the coesite-stishovite transformation and calculation of the phase boundary

High temperature drop-solution calorimetry in molten 2 PbO · B₂O₃ at 1044 K for coesite and stishovite polymorphs of silica was carried out to determine the enthalpy of the coesite-stishovite transition. These experiments were performed on high-purity, single-phase samples of coesite and stishovite. Our new value for the enthalpy of the coesitestishovite transition (ΔH ₂₉₈ ⁰ ) is 29.85 ± 0.78 kJ/mol, which is about 35% lower than previously reported by Akaogi and Navrotsky (1984) and Holm et al. (1967), but which compares well with new measurements by Akaogi et al. (1994b). Using these new data, we have calculated the equilibrium phase boundary between coesite and stishovite and obtained a slope, dP/dT=0.0031 (2) GPa/K. This calculated slope is in good agreement with that determined [0.0026 (2) GPa/K] from the in-situ X-ray diffraction study of Zhang et al. (1996).     

Charting the emergence of ‘global water initiatives’ in world water governance

Over the last century, the aperture of water governance has widened beyond local and regional schemes to include a growing number of dynamic organizations and events with a “global” scope. Until recently, little had been written about the historical development of global water governance, institutional connectivity within the field, or key organizational successes and failures as perceived by water experts. This paper provides water scientists, managers, policymakers, and those with an interest in international water issues with an overview of global initiatives. It charts the emergence of a set of institutions and events, referred to as “global water initiatives,” or GWIs, using a survey of water experts and other research. Institutional diversity among GWIs is described by defining four distinct types of initiatives and specific differences in scope and programmatic orientation. This overview also entails the historical paradigms of water management, evaluation of the results of the growth and proliferation of numerous new GWIs in recent decades, and some recommendations for supporting and sustaining GWI efforts in order to foster and improve multilevel water management in the future.     

Surface wave array tomography in SE Tibet from ambient seismic noise and two-station analysis – II. Crustal and upper-mantle structure

We determine the 3-D shear wave speed variations in the crust and upper mantle in the southeastern borderland of the Tibetan Plateau, SW China, with data from 25 temporary broad-band stations and one permanent station. Interstation Rayleigh wave (phase velocity) dispersion curves were obtained at periods from 10 to 50 s from empirical Green's function (EGF) derived from (ambient noise) interferometry and from 20 to 150 s from traditional two-station (TS) analysis. Here, we use these measurements to construct phase velocity maps (from 10 to 150 s, using the average interstation dispersion from the EGF and TS methods between 20 and 50 s) and estimate from them (with the Neighbourhood Algorithm) the 3-D wave speed variations and their uncertainty. The crust structure, parametrized in three layers, can be well resolved with a horizontal resolution about of 100 km or less. Because of the possible effect of mechanically weak layers on regional deformation, of particular interest is the existence and geometry of low (shear) velocity layers (LVLs). In some regions prominent LVLs occur in the middle crust, in others they may appear in the lower crust. In some cases the lateral transition of shear wave speed coincides with major fault zones. The spatial variation in strength and depth of crustal LVLs suggests that the 3-D geometry of weak layers is complex and that unhindered crustal flow over large regions may not occur. Consideration of such complexity may be the key to a better understanding of relative block motion and patterns of seismicity.     

On the consistency of the current conventional EOP series and the celestial and terrestrial reference frames

Precise transformation between the celestial reference frames (CRF) and terrestrial reference frames (TRF) is needed for many purposes in Earth and space sciences. According to the Global Geodetic Observing System (GGOS) recommendations, the accuracy of positions and stability of reference frames should reach 1 mm and 0.1 mm year\(^{-1}\), and thus, the Earth Orientation Parameters (EOP) should be estimated with similar accuracy. Different realizations of TRFs, based on the combination of solutions from four different space geodetic techniques, and CRFs, based on a single technique only (VLBI, Very Long Baseline Interferometry), might cause a slow degradation of the consistency among EOP, CRFs, and TRFs (e.g., because of differences in geometry, orientation and scale) and a misalignment of the current conventional EOP series, IERS 08 C04. We empirically assess the consistency among the conventional reference frames and EOP by analyzing the record of VLBI sessions since 1990 with varied settings to reflect the impact of changing frames or other processing strategies on the EOP estimates. Our tests show that the EOP estimates are insensitive to CRF changes, but sensitive to TRF variations and unmodeled geophysical signals at the GGOS level. The differences between the conventional IERS 08 C04 and other EOP series computed with distinct TRF settings exhibit biases and even non-negligible trends in the cases where no differential rotations should appear, e.g., a drift of about 20 \(\upmu \)as year\(^{-1 }\)in \(y_{\mathrm{pol }}\) when the VLBI-only frame VTRF2008 is used. Likewise, different strategies on station position modeling originate scatters larger than 150 \(\upmu \)as in the terrestrial pole coordinates.