Total mercury in terrestrial systems (air-soil-plant-water) at the mining region of San Joaquín,Queretaro, Mexico

Deficient management of cinnabar mining left the San Joaquín region with high concentrations of mercury in its soils (2.4 – 4164 mg kg^-1). Numerous cinnabar mines have contributed to the dispersion of mercury into agricultural (0.5 –314 mg kg^-1) and forest (0.2 – 69 mg kg^-1) soils. Sediments are a natural means of transportation for mercury, causing its spreading, especially in areas near mine entrances (0.6 – 687 mg kg^-1). The nearness of maize crops to mines favors mercury accumulation in the different plant structures, such as roots, stems, leaves, and grain (0.04 – 8.2 mg kg^-1); these being related to mercury volatilization and accumulation in soils. Mercury vapor present in the settlements could indicate a constant volatilization from lands and soils (22 – 153 ng m^-3). The mercury levels found in the soils, in maize grain, and in the air resulted greater than the standards reported by the Official Mexican Norm (NOM) and the World Health Organization (WHO). Mercury in rainwater is due mainly to the presence of suspended atmospheric particles, later deposited on the surface (1.5 – 339 μg |^-1). Mercury dissolution was found in the drinking water (10 – 170 ng |^-1), with concentrations below those established by the NOM and the WHO. The contamination existing in the San Joaquín region does not reach the levels of the world’s greatest mercury producers: Almaden (Spain) and Idrija (Slovenia). It is, however, like that found in other important second degree world producers such as Guizhou (China). The population of San Joaquín, as well as its surrounding environment, are constantly exposed to mercury contamination, thus making a long term monitoring necessary to determine its effects, especially to people.     

Deforestation and fragmentation of seasonal tropical forests in the southern Yucatán,Mexico (1990–2006)

The southern Yucatán (SY) has been recognized as a hotspot of biodiversity with great risk of deforestation. Land change analysis, based on classified Landsat TM and ETM?+?satellite imagery (1990, 2000 and 2006), was used to estimate the annual deforestation rates of 141 land management units of the SY, and spatial patterns of forest fragmentation around and within the Calakmul Biosphere Reserve (CBR), which comprises approximately one-third of the region. Results indicate a decrease in annual deforestation rates over 1990–2006, from 0.15% year^?1 to 0.06% year^?1, but with significant sub-regional variations in the quantity and rate of forest loss. Despite a decline in deforestation during this period, there was considerable fragmentation both inside and outside the CBR. While population pressures and the expansion of pasture have caused deforestation across the region, agricultural intensification, diversified income strategies and reserve conservation may have contributed to reduced forest loss during the study period.     

Spatial Metrics to Analyse the Impact of Regional Factors on Pattern of Urbanisation in Gurgaon,India

In recent years, there has been lot of emphasis on the study of urban land use/ land cover changes to discover the growth pattern due to rapid urbanisation. This study presents spatial metrics and gradient analysis approach for quantifying and capturing changes in urban landscape using LISS III imagery of 1999, 2001 and 2004 of Gurgaon, India. A combination of spatial metrics i.e. percentage of landscape, mean patch size, number of patches, landscape shape index and largest patch index, available in Fragstats ver. 3.3, have been used to quantify the patterns of urban growth in different directions in terms of size, shape and complexity of development. The local built-up areas were quantified by the “moving window” technique. A gradient analysis has been carried out through sampling from a reference point to 8 km in 16 directions with a window size of 500 mts. Results of this study demonstrate the potential of spatial metrics and gradient modelling to quantify the impact of regional factors on the growth pattern of Gurgaon city.     

Neoarchean suprasubduction zone arc magmatism in southern India: Geochemistry,zircon U-Pb geochronology and Hf isotopes of the Sittampundi Anorthosite Complex

The Sittampundi Anorthosite Complex (SAC) in southern India is one of the well exposed Archean layered anorthosite-gabbro-ultramafic rock associations. Here we present high precision geochemical data for the various units of SAC, coupled with zircon U-Pb geochronology and Hf isotopic data for the anorthosite. The zircon ages define two populations, the older yield a concordia age of 2541 ± 13 Ma, which is interpreted as the best estimate of the magmatic crystallization age for the Sittampundi anorthosite. A high-grade metamorphic event at 2461 ± 15 Ma is suggested by the upper intercept age of the younger zircon population. A Neoproterozoic event at 715 ± 180 Ma resulted in Pb loss from some of the metamorphic zircons. The magmatic age of the anorthosite correlates well with the timing of crystallization of the arc-related ~ 2530 Ma magmatic charnockites in the adjacent Salem Block, while the metamorphic age is synchronous with the regional metamorphic event. The geochemical data suggest that the rocks were derived from a depleted mantle source. Sub-arc mantle metasomatism of slab derived fluids and subsequent partial melting produced hydrous, aluminous basalt magma. The magma fractionated at depth to produce a variety of high-alumina basalt compositions, from which the anorthositic complex with its chromite-rich and amphibole-rich layers formed as cumulates within the magma chamber of a supra-subduction zone arc. The coherent initial¹⁷⁶Hf/¹⁷⁷Hf ratios and positive εHf values (1.7 – 4.5) of the magmatic zircons in the anorthosite are consistent with derivation of a rather homogeneous juvenile parent magma from a depleted mantle source. Our study further confirms that the southern part of the Dharwar Craton was an active convergent margin during the Neoarchean with the generation and emplacement of suprasubduction zone arc magmas which played a significant role in continental growth.     

Web-GIS tool for the management of rural land markets

Land abandonment and stagnation of rural markets in the last few years have become one of the main concerns of rural administrations. The use of Web and GIS (Geographic Information System) technologies can help to mitigate the effects of these problems. This paper pro-poses a novel Web-GIS tool with spatial capabilities for the dynamization of rural land markets by encouraging the transfer of land from owners to farmers through the leasing of plots. The system, based on open source software, offers information about the properties, their environment and their owners. It uses standards for handling the geographic information and for communicating with external data sources. This system was used as the basis for the development of SITEGAL, the tool for the management of the Land Bank of Galicia (www.bantegal.com/sitegal). SITEGAL has been operational since 2007 obtaining benefits for both administration and users (farmers and land owners), and promoting the e-Government.     

Geochemical processes regulating groundwater chemistry with special reference to nitrate and fluoride enrichment in Chhatarpur area, Madhya Pradesh, India

The present study focuses on the hydrogeochemical composition of groundwater in Chhatarpur area with special focus on nitrate and fluoride contamination, considering the fact that groundwater is the only major source of drinking water here. Carbonate and silicate mineral weathering followed by ground water–surface water interactions, ion exchange and anthropogenic activities are mainly responsible for high concentrations of cations and anions in the groundwater in the region. The average concentration of nitrate and fluoride found in 27 samples is 1.08 and 61.4 mg/L, respectively. Nitrate enrichment mainly occurs in areas occupied with intense fertilizer practice in agricultural fields. Since the area is not dominated by industrialization, the possibility of anthropogenic input of fluoride is almost negligible, thus the enrichment of fluoride in groundwater is only possible due to rock–water interaction. The highly alkaline conditions, which favor the fluorite dissolution, are the main process responsible for high concentration of fluoride.     

Use of DEM data to monitor height changes due to deforestation

Deforestation has been a major cause of climate change and other environmental problems. An accurate estimation of the volume of deforested area is needed for United Nations Reducing Emissions from Deforestation and Forest Degradation (UN-REDD+) policies implementation and global carbon accounting. Accurate information about three-dimensional (3-D) structure of forests is required to quantify forest carbon stock. This study demonstrates the use of different digital elevation models (DEMs) to monitor changes in height due to deforestation in Cambodia to support climate change mitigation policies of UN-REDD+. The Shuttle Radar Topographic Mission-DEM (SRTM-DEM), Advanced Spaceborne Thermal Emission and Reflection Radiometer Global DEM (ASTER-GDEM) and Panchromatic Remote sensing Instrument for Stereo Mapping-Digital Surface Model (PRISM-DSM) data were calibrated using Ice Cloud and land Elevation Satellite Geoscience Laser Altimeter System (ICESat–GLAS) data. The results obtained from this study clearly indicate the changes in the height of forests due to deforestation activity. The height of cutover forest generated from the PRISM-DSM and SRTM-DEM is more reliable than that from the PRISM-DSM and ASTER-GDEM data. Field data has also been used to validate the height of the cutover forests, which shows ±5 m uncertainties in the estimation.     

Depositional environment in and around Tamiraparani estuary,and off Tuticorin,Tamil Nadu,India: clues from grain size studies

The sediments of the estuaries and offshore Tuticorin along the southern coast of Tamil Nadu were studied for their textural variation. Ninety sediment samples were collected from three sectors (river, estuary, offshore) on the basis of prevailing energy conditions and oceanographic parameters. Frequency curves show unimodal to bimodal in nature. Offshore samples also fall in bimodal with medium and fine sand where sediment is additionally deposited by the Tamiraparani River. The mean values ranging from 1.69 to 2.01 φ with medium to fine sand. The fine sand in the riverine region indicates the depositional nature of the sediments. In pre-monsoon, the standard deviation ranges from 0.29 to 0.81 φ, which falls in the very well sorted to moderately well sorted. Estuary ranges from 0.63 to 1.30 φ, with moderately sorted, whereas in the marine sediments ranges from 0.4 to 1.01 φ, with moderately to moderately well- sorted and some patches of poorly sorted is observed. In both monsoons, the grain size variations are mostly influenced in river and offshore samples compared to the estuaries. The CM pattern indicates the deposition of sediments in graded suspension. In estuary, the sediments are medium sand with moderately to poorly sorted, fine skewed which are indicative of denudation processes taking place there. In marine, the sediments are medium-to-fine, moderately-to-well sorted, and fine skewed to very fine skewed sediments, probably as a result of the influence of palaeo-sediments deposited by rivers from inland as well as by waves and currents from offshore. Further, the marine samples also highlight depositional processes.     

Chromospheric Sunspot Oscillations in Hα and Ca ii 8542 Å

We study chromospheric oscillations including umbral flashes and running penumbral waves in a sunspot of active region NOAA 11242 using scanning spectroscopy in Hα and Ca?ii 8542 Å with the Fast Imaging Solar Spectrograph (FISS) at the 1.6 meter New Solar Telescope at the Big Bear Solar Observatory. A bisector method is applied to spectral observations to construct chromospheric Doppler-velocity maps. Temporal-sequence analysis of these shows enhanced high-frequency oscillations inside the sunspot umbra in both lines. Their peak frequency gradually decreases outward from the umbra. The oscillation power is found to be associated with magnetic-field strength and inclination, with different relationships in different frequency bands.     

Velocities and Temperatures of an Ellerman Bomb and Its Associated Features

We investigated the velocity and temperature characteristics of an Ellerman bomb (EB) and its associated features based on observations made with the Fast Imaging Solar Spectrograph (FISS) and a broadband TiO filter of the 1.6 meter New Solar Telescope at Big Bear Solar Observatory. In the TiO images of the photospheric level, we found a granular cell expanding in two opposite directions near the site of the EB. When one end of this granule reached the EB site, the transverse speed of the tip of the expanding granule rapidly decreased and the EB brightened. The wings of the Hα profile of the EB indicated that the EB was blueshifted up to 7 km?s^?1. About 260 s after the EB brightening, a surge was seen in absorption and varied from a blueshift of 20 km?s^?1 to a redshift of 40 km?s^?1 seen in the Hα and Ca ii 8542 Å lines. From the Doppler absorption width of the two lines determined by applying the cloud model, we estimated the mean temperature of the surge material to be about 29000 K and the mean speed of nonthermal motion to be about 11 km?s^?1. We discuss the physical implications of our results in terms of magnetic reconnection and processes related to it.