On the breakdown of zircon upon “dry” thermal annealing

Zircon samples without and with secondary chemical alteration from diverse sources were subjected to heat treatment at 1400 °C for 96 h. Resulting new phases and textures suggest that decomposition of zircon into component oxides occurred in all experiments to various degrees. The crucible material was found to have a strong influence on the extent of breakdown, especially in the case of altered starting materials. In this study the progressive stages of the breakdown of zircon grains are described. The factors that may govern the decomposition are discussed, including radiation damage, secondary alteration and external reaction conditions (sample container, atmosphere). Alumina crucibles should generally be avoided in dry annealing of zircon, to minimise uncontrolled breakdown into oxides.     

A chemical and thermodynamic model of oil generation in hydrocarbon source rocks

Thermodynamic calculations and Gibbs free energy minimization computer experiments strongly support the hypothesis that kerogen maturation and oil generation are inevitable consequences of oxidation/reduction disproportionation reactions caused by prograde metamorphism of hydrocarbon source rocks with increasing depth of burial.These experiments indicate that oxygen and hydrogen are conserved in the process.Accordingly, if water is stable and present in the source rock at temperatures ?25 but ?100 °C along a typical US Gulf Coast geotherm, immature (reduced) kerogen with a given atomic hydrogen to carbon ratio (H/C) melts incongruently with increasing temperature and depth of burial to produce a metastable equilibrium phase assemblage consisting of naphthenic/biomarker-rich crude oil, a type-II/III kerogen with an atomic hydrogen/carbon ratio (H/C) of ∼1, and water. Hence, this incongruent melting process promotes diagenetic reaction of detritus in the source rock to form authigenic mineral assemblages.However, in the water-absent region of the system CHO (which is extensive), any water initially present or subsequently entering the source rock is consumed by reaction with the most mature kerogen with the lowest H/C it encounters to form CO₂ gas and a new kerogen with higher H/C and O/C, both of which are in metastable equilibrium with one another.This hydrolytic disproportionation process progressively increases both the concentration of the solute in the aqueous phase, and the oil generation potential of the source rock; i.e., the new kerogen can then produce more crude oil.Petroleum is generated with increasing temperature and depth of burial of hydrocarbon source rocks in which water is not stable in the system CHO by a series of irreversible disproportionation reactions in which kerogens with higher (H/C)s melt incongruently to produce metastable equilibrium assemblages consisting of crude oil, CO₂ gas, and a more mature (oxidized) kerogen with a lower H/C which in turn melts incongruently with further burial to produce more crude oil, CO₂ gas, and a kerogen with a lower H/C and so forth.The petroleum generated in the process progresses from heavy naphthenic crude oils at low temperatures to mature petroleum at ∼150 °C. For example, the results of Computer Experiment 27 (see below) indicate that the overall incongruent melting reaction in the water-absent region of the system C-H-O at 150 °C and a depth of ∼4.3 km of an immature type-II/III kerogen with a bulk composition represented by C₂₉₂H₂₈₈O_12(c) to produce a mature (oxidized) kerogen represented by C₁₂₈H₆₈O_7(c), together with a typical crude oil with an average metastable equilibrium composition corresponding to C_8.8H_16.9 (C_8.8H_16.9(l)) and CO₂ gas (CO_2(g)) can be described by writing

(A)     

A morphological, sedimentological and geophysical investigation of the Woore Moraine, Shropshire, England

The Bar Hill-Whitchurch-Wrexham Morainic Complex is a large-scale glacial landform thought to represent either the maximum extent or the re-advance of the British-Irish Ice Sheet during the Late Devensian. The origin of the moraine remains uncertain as its key characteristics have not been studied in detail due to a lack of exposures from which its large-scale structure can be determined. The development of new technologies has enabled detailed examination of the topography and internal structure of such large-scale landforms. This paper describes a multi-disciplinary approach involving digital geomorphological mapping using enhanced resolution NextMAP™ digital surface models, geophysical imaging (electrical resistivity tomography) and conventional sedimentological analyses. This combination of techniques is useful for elucidating the origin of a large glacial landform in a region of poor exposure. Digital elevation models such as NextMAP™ offer an efficient and accurate method for landform-mapping, whilst electrical resistivity tomography was able to map the major constituent sediments of the moraine, which had in turn been identified in the single exposure available. Additional geophysical techniques should however be applied to provide further structural data and thereby enable a more detailed interpretation of the moraine's internal structure. Preliminary findings indicate that the moraine is a glaciotectonic landform composed of diamicton and glaciofluvial sediments, an origin consistent with recent suggestions that the Cheshire Plain contained an active ice lobe during the last glacial maximum.     

Chemistry of alkali extraction of brown coals—I. Kinetics, characterisation and implications to coalification

Three Australian brown coals have been separated into humin and humic acid fractions and studied by high resolution solid state ¹³C NMR spectroscopy and Fourier transform IR spectroscopy. The aromatic rings of the humic acids are highly substituted showing that extensive cross linking must have occurred during formation from wood lignin and tannin. However, the humins contain more aliphatic carbon and hydrogen than the corresponding humic acids. This shows that little cross linking has occurred with other components of the brown coal such as resins, waxes cutin and algal detritus, and cross linking has not rendered the aromatics alkali insoluble. The kinetics of extraction are complex and not simple first order. This is reflected in the chemical composition of the humic acid which is extraction temperature dependent. We also observed that there is a conversion of aromatic carbon to aliphatic carbon and gas during extraction, probably by alkaline oxidation, resulting in ring opening. A range of suitable model compounds have been studied to confirm this finding. Such a mechanism may account for the modification of lignin in oxidising environments such as those occurring in the initial stages of coalification (lignite or brown coal formation) and in soils.     

ISIS IR: The first infrared fibre-fed spectrograph

ISIS IR is the first attempt to use fibre optics for near infrared spectroscopy (1.8m). It is a field spectrograph (2D spectroscopy), and can work at various resolving powers (up to 25000). It can be transported anywhere, and soon it will be used at CFHT with one NICMOS 3-based camera.Département d'Astrophysique Extragalactique et de Cosmologie     

Anatomy of individual agglutinates from a lunar highland soil

Abstract— We report results of our investigation of the relationship between values of I_s/FeO (relative concentration of nanophase Fe⁰ divided by total FeO content), glass abundance, total Fe content, and degree of digestion of <20 μm clasts for 22 individual agglutinates (250–1000 μm) from the mature Apollo 16 soil 61181 (I_s/FeO = 82 units in the <250 μm fraction). Agglutinates are important products of space weathering on the Moon, and they influence spectral observations at visible and near-IR wavelengths. Values of I_s/FeO for individual agglutinates (250–1000 μm) within this single soil span a range from 3 to 262 units which is larger than the range observed for all Apollo 16 bulk soils (～0 to 110 units). No correlation was observed between I_s/FeO and glass abundance and FeO concentrations for either agglutinitic glass or whole agglutinate particles under investigation. Our results suggest that the variation in I_s/FeO for agglutinates from a single soil may be in part a consequence of natural mixing processes on the Moon that produce highly-variable environments (with respect to surface exposure) for agglutinate formation and in part to variable kinetics of reactions in an agglutinate melt, which are influenced by a variety of factors including melt composition, temperature, impactor velocity, and quench rate. We cannot exclude but do not see evidence for other processes including addition of exotic agglutinates, micrometeoritic bombardment into compositionally-diverse microtargets, recycling of agglutinates, preferential melting of very fine soil particles, and production of nanophase Fe⁰ in amorphous rims of very fine irradiated lunar grains contributing to the observed variation of I_s/FeO.     

Coronal changes associated with a disappearing filament

This paper describes Skylab/ATM observations of the events associated with a disappearing filament near the center of the solar disk on January 18, 1974. As the filament disappeared, the nearby coronal plasma was heated to a temperature in excess of 6 × 10⁶K. A change in the pattern of coronal emission occurred during the 11/3 hr period that the soft X-ray flux was increasing. This change seemed to consist of the formation and apparent expansion of a loop-like coronal structure which remained visible until its passage around the west limb several days later. The time history of the X-ray and microwave radio flux displayed the well-known gradual-rise-and-fall (GRF) signature, suggesting that this January 18 event may have properties characteristic of a wide class of X-ray and radio events.In pursuit of this idea, we examined other spatially-resolved Skylab/ATM observations of long-duration X-ray events to see what characteristics they may have in common. Nineteen similar long-lived SOLRAD X-ray events having either the GRF or post-burst radio classification occurred during the nine-month Skylab mission. Sixteen of these occurred during HAO/ATM coronagraph observations, and 7 of these 16 events occurred during observations with both the NRL/ATM slitless spectrograph and the MSFC-A/ATM X-ray telescope. The tabulation of these events suggests that all long-lived SOLRAD X-ray bursts involve transients in the outer corona and that at least two-thirds of the bursts involve either the eruption or major activation of a prominence. Also, these observations indicate that long-lived SOLARD events are characterized by the appearance of new loops of emission in the lower corona during the declining phase of the X-ray emission. However, sometimes these loops disappear after the X-ray event (like the post-flare loops associated with a sporadic coronal condensation), and sometimes the loops remain indefinitely (like the emission from a permanent coronal condensation).Visiting Scientist, Kitt Peak National Observatory, Tucson, Ariz. 85726, U.S.A. operated by the Association of Universities for Research in Astronomy, Inc., under contract with the National Science Foundation.Presently located at NASA/MSFC, Space Sciences Laboratory, Marshall Space Flight Center, Ala. 35812, U. S.A.     

The Depiction of Coronal Structure in White-Light Images

The very steep decrease in density with heliocentric distance makes imaging of coronal density structures out to a few solar radii challenging. The radial gradient in brightness can be reduced using numerous image processing techniques, thus quantitative data are manipulated to provide qualitative images. We introduce a new normalizing-radial-graded filter (NRGF): a simple filter for removing the radial gradient to reveal coronal structure. Applied to polarized brightness observations of the corona, the NRGF produces images which are striking in their detail. Total-brightness, white-light images include contributions from the F corona, stray light, and other instrumental contributions which need to be removed as effectively as possible to properly reveal the electron corona structure. A new procedure for subtracting this background from LASCO C2 white-light, total-brightness images is introduced. The background is created from the unpolarized component of total-brightness images and is found to be remarkably time-invariant, remaining virtually unchanged over the solar cycle. By direct comparison with polarized-brightness data, we show that the new background-subtracting procedure is superior in depicting coronal structure accurately, particularly when used in conjunction with the NRGF. The effectiveness of the procedures is demonstrated on a series of LASCO C2 observations of a coronal mass ejection (CME).