Petrological and experimental evidence for differentiation of water-rich magmas beneath St. Kitts,Lesser Antilles

St. Kitts lies in the northern Lesser Antilles, a subduction-related intraoceanic volcanic arc known for its magmatic diversity and unusually abundant cognate xenoliths. We combine the geochemistry of xenoliths, melt inclusions and lavas with high pressure–temperature experiments to explore magma differentiation processes beneath St. Kitts. Lavas range from basalt to rhyolite, with predominant andesites and basaltic andesites. Xenoliths, dominated by calcic plagioclase and amphibole, typically in reaction relationship with pyroxenes and olivine, can be divided into plutonic and cumulate varieties based on mineral textures and compositions. Cumulate varieties, formed primarily by the accumulation of liquidus phases, comprise ensembles that represent instantaneous solid compositions from one or more magma batches; plutonic varieties have mineralogy and textures consistent with protracted solidification of magmatic mush. Mineral chemistry in lavas and xenoliths is subtly different. For example, plagioclase with unusually high anorthite content (An_≤100) occurs in some plutonic xenoliths, whereas the most calcic plagioclase in cumulate xenoliths and lavas are An₉₇ and An₉₅, respectively. Fluid-saturated, equilibrium crystallisation experiments were performed on a St. Kitts basaltic andesite, with three different fluid compositions (XH₂O = 1.0, 0.66 and 0.33) at 2.4 kbar, 950–1025 °C, and fO₂ = NNO ? 0.6 to NNO + 1.2 log units. Experiments reproduce lava liquid lines of descent and many xenolith assemblages, but fail to match xenolith and lava phenocryst mineral compositions, notably the very An-rich plagioclase. The strong positive correlation between experimentally determined plagioclase-melt Kd_Ca–Na and dissolved H₂O in the melt, together with the occurrence of Al-rich mafic lavas, suggests that parental magmas were water-rich (> 9 wt% H₂O) basaltic andesites that crystallised over a wide pressure range (1.5–6 kbar). Comparison of experimental and natural (lava, xenolith) mafic mineral composition reveals that whereas olivine in lavas is predominantly primocrysts precipitated at low-pressure, pyroxenes and spinel are predominantly xenocrysts formed by disaggregation of plutonic mushes. Overall, St. Kitts xenoliths and lavas testify to mid-crustal differentiation of low-MgO basalt and basaltic andesite magmas within a trans-crustal, magmatic mush system. Lower crustal ultramafic cumulates that relate parental low-MgO basalts to primary, mantle -derived melts are absent on St. Kitts.     

A Century of Spinosaurs - A Review and Revision of the Spinosauridae with Comments on Their Ecology

The spinosaurids represent an enigmatic and highly unusual form of large tetanuran theropods that were first identified in 1915. A recent flurry of discoveries and taxonomic revisions of this important and interesting clade has added greatly to our knowledge. Spinosaur body fossils are however generally rare and most species are known from only limited skeletal remains. Their unusual anatomical adaptations to the skull, limbs and axial column all differ from other large theropods and point to an unusual ecological niche and a lifestyle intimately linked to water.     

Exploring the marine biotic index (AMBI): variations on a theme by Ángel Borja

The results of manipulating the input data to AMBI are explored using various transformations of numerical species abundance (NAMBI), biomass (BAMBI) and production (PAMBI) from a variety of stations on the NE Atlantic shelf at which the pollution/disturbance status is known. There is a close agreement between the proportions of species in the five AMBI ecological groups and a phylum level meta-analysis axis of increasing environmental impact. All AMBI measures provide a better monotonic relationship with the impact axis than do traditional species diversity measures, which show higher diversity at intermediate levels of disturbance. A marginally better relationship with the impact axis of the meta-analysis is achieved by a moderate (square root) transformation of the data. ‘Production’ data (an appropriate combination of abundance and biomass information) provide only a marginal improvement on abundance data, but are ecologically and functionally much more relevant. Severe transformation of the data, culminating in presence/absence, degrades the relationship with the impact axis, but if only simple species lists are available then these may still be useable in making an environmental assessment.     

Degradation of plastic carrier bags in the marine environment

There is considerable concern about the hazards that plastic debris presents to wildlife. Use of polymers that degrade more quickly than conventional plastics presents a possible solution to this problem. Here we investigate breakdown of two oxo-biodegradable plastics, compostable plastic and standard polyethylene in the marine environment. Tensile strength of all materials decreased during exposure, but at different rates. Compostable plastic disappeared from our test rig between 16 and 24 weeks whereas approximately 98% of the other plastics remained after 40 weeks. Some plastics require UV light to degrade. Transmittance of UV through oxo-biodegradable and standard polyethylene decreased as a consequence of fouling such that these materials received ～ 90% less UV light after 40 weeks. Our data indicate that compostable plastics may degrade relatively quickly compared to oxo-biodegradable and conventional plastics. While degradable polymers offer waste management solutions, there are limitations to their effectiveness in reducing hazards associated with plastic debris.     

3D seismic imaging of a Tertiary Dyke Swarm in the Southern North Sea,UK

We use three‐dimensional (3D) seismic reflection and magnetic data to interpret and describe the 3D geometry of igneous dykes in the southern North Sea. The dykes were emplaced into Paleozoic and Mesozoic sediments and have a common upper termination in Early Tertiary sediments. We interpret the dykes to be part of the British Tertiary volcanic province and estimate the age of the dykes to be 58 Ma. The dykes are characterized by a narrow 0.5–2 km wide vertical disturbance of seismic reflections that have linear plan view geometry. Negative magnetic anomalies directly align with the vertical seismic disturbance zones and indicate the presence of igneous material. Linear coalesced collapse craters are found above the dykes. The collapse craters have been defined and visualized in 3D. Collapse craters have formed above the dyke due to the release of volatiles at the dyke tip and resulting volume loss. Larger craters have potentially formed due to explosive phreatomagmatic interaction between magma and pore water. The collapse craters are a new Earth analogue to Martian pit chain craters.     

Remote and local forcing of a coastal lagoon: The Virginia Coast Reserve

The effects of local and remote wind forcing of water level heights in the Virginia Coast Reserve (VCR) are examined in order to determine the significant forces governing estuarine motions over subtidal time scales. Recent (1996–2008) data from tide and wind stations in the lagoon, a tide station to the north at Sandy Hook, NJ, and one offshore wind station at the Chesapeake Light Tower are examined. Sea surface height spectrum calculations reveal significant diurnal and semidiurnal tidal effects along with subtidal variations, but a suppressed inertial signal. Sea-surface heights (SSH) with 2–5 day periods at Wachapreague, VA are coherent with those at Sandy Hook and lag them in time, suggesting that southward-propagating continental shelf waves provide subtidal variability within the lagoon. The coherence between lagoon winds and sea surface height, as well as between winds and cross-lagoon sea height gradient, were significant at a relatively small number of frequency and wind direction combinations. The frequencies at which this wind forcing occurs are the tidal and subtidal bands present to the north, so that lagoon winds selectively augment existing SSH signals, but do not generate them. The impact of the wind direction is closely related to the geometry of the lagoon and bounding landmasses. The effect of wind stress is also constrained by geometry in affecting the cross-lagoon water height gradient. Water levels at subtidal frequencies are likely forced by a combination of local wind forcing, remote wind forcing and oceanic forcing modified by the complex topography of the lagoon, shelf, and barrier islands.     

A discontinuous finite element baroclinic marine model on unstructured prismatic meshes

We describe the time discretization of a three-dimensional baroclinic finite element model for the hydrostatic Boussinesq equations based upon a discontinuous Galerkin finite element method. On one hand, the time marching algorithm is based on an efficient mode splitting. To ensure compatibility between the barotropic and baroclinic modes in the splitting algorithm, we introduce Lagrange multipliers in the discrete formulation. On the other hand, the use of implicit–explicit Runge–Kutta methods enables us to treat stiff linear operators implicitly, while the rest of the nonlinear dynamics is treated explicitly. By way of illustration, the time evolution of the flow over a tall isolated seamount on the sphere is simulated. The seamount height is 90% of the mean sea depth. Vortex shedding and Taylor caps are observed. The simulation compares well with results published by other authors.     

Ocean eddy momentum fluxes at the latitudes of the Gulf Stream and the Kuroshio extensions as revealed by satellite data

Eddy momentum fluxes, i.e. Reynold stresses, are computed for the latitude bands of the Gulf Stream and Kuroshio extensions using 13 years of data from the merged satellite altimeter product of Le Traon et al. The spatial pattern and amplitude of the fluxes is remarkably similar to that found by Ducet and Le Traon using the 5 years of data that were available to them. In addition to updating the work of Ducet and Le Traon, we provide new insight into the role played by the underlying variable bottom topography, both for determining the structure of the eddy momentum fluxes seen in the satellite data and for influencing the way these fluxes feedback on the mean flow. While there is no clear evidence that eddies locally flux momentum into the eastward jets of the Gulf Stream and Kuroshio extensions, a clearer picture emerges after zonally integrating across each of the North Atlantic and North Pacific basins. We argue that the eddy momentum fluxes do indeed drive significant transport, a conclusion supported by preliminary results from a 3-D model calculation. We also present evidence that in the North Pacific, the Reynolds stresses are important for driving the recirculation gyres associated with the Kuroshio extension, taking advantage of new data from both observations and high-resolution model simulations.     

Capturing the residence time boundary layer—application to the Scheldt Estuary

At high Peclet number, the residence time exhibits a boundary layer adjacent to incoming open boundaries. In a Eulerian model, not resolving this boundary layer can generate spurious oscillations that can propagate into the area of interest. However, resolving this boundary layer would require an unacceptably high spatial resolution. Therefore, alternative methods are needed in which no grid refinement is required to capture the key aspects of the physics of the residence time boundary layer. An extended finite element method representation and a boundary layer parameterisation are presented and tested herein. It is also explained how to preserve local consistency in reversed time simulations so as to avoid the generation of spurious residence time extrema. Finally, the boundary layer parameterisation is applied to the computation of the residence time in the Scheldt Estuary (Belgium/The Netherlands). This timescale is simulated by means of a depth-integrated, finite element, unstructured mesh model, with a high space–time resolution. It is seen that the residence time temporal variations are mainly affected by the semi-diurnal tides. However, the spring–neap variability also impacts the residence time, particularly in the sandbank and shallow areas. Seasonal variability is also observed, which is induced by the fluctuations over the year of the upstream flows. In general, the residence time is an increasing function of the distance to the mouth of the estuary. However, smaller-scale fluctuations are also present: they are caused by local bathymetric features and their impact on the hydrodynamics.