Non‐equilibrium concepts lead to a unified explanation of the formation of chondrules and chondrites

Abstract— Calculations of the formation of seven types of chondrules in Semarkona from a gas of solar composition were performed with the FACT computer program to predict the chemistries of oxides (including silicates), developed by the authors and their colleagues. The constrained equilibrium theory was used in the calculations with two nucleation constraints suggested by nucleation theory. The first constraint was the blocking of Fe and other metal gaseous atoms from condensing to form solids or liquids because of very high surface free energies and high surface tensions of the solid and liquid metals, respectively. The second constraint was the blocking of the condensation of solids and the formation of metastable liquid oxides (including silicates) well below their liquidus temperatures. Our laboratory experiments suggested subcooling of type IIA chondrule compositions of 400 degrees or more below the liquidus temperature. The blocking of iron leads to a supersaturation of Fe atoms, so that the partial pressure of Fe (p_Fe) is larger than the partial pressure at equilibrium (p_Fe(eq)). The supersaturation ratio S = p_Fe/p_Fe(eq) becomes larger than 1 and increases rapidly with a decrease in temperature. This drives the reaction Fe + H₂O ? H₂ + FeO to the right. With S = 100, the activity of FeO in the liquid droplet is 100 times as large as the value at equilibrium. The FeO activities are a function of temperature and provide relative average temperatures of the crystallization of chondrules. Our calculations for the LL3.0 chondrite Semarkona and our study of some non‐equilibrium effects lead to accurate representations of the compositions of chondrules of types IA, IAB, IB, IIA, IIAB, IIB, and CC. Our concepts readily explain both the variety of FeO concentrations in the different chondrule types and the entire process of chondrule formation. Our theory is unified and could possibly explain the formation of chondrules in all chondritic meteorites as well as provide a simple explanation for the complex chemistries of chondrites, and especially for type 3 chondrites.     

Mass loss from Wolf-Rayet stars

The observed times of minimum light derived from the photometry of the Wolf-Rayet eclipsing binary stars CQ Cep and V444 Cyg are used to estimate the mass-loss rate of the Wolf-Rayet components in several modes of mass-loss and mass-exchange.     

measurement of noise power spectrum in photon counting PMT's and the effect of the observed (1/f) noise on astronomical photometry

In astronomical photometry, the sensitivity of observations is limited by the dark counts of the photomultiplier tube. In the present work, the effect of dark count noise in photon counting systems is investigated by theory and experimental measurements. Dark counts are considered to be originating from two sources, namely: dc fluctuations and random pulses.Experimental measurements were carried out to determine noise effects in different operating regions of noise dominance. The results provide strong evidence that: in normal operating mode, where the effect of random pulses is dominant, dark counts do not follow Poisson statistics. The observed noise shows strong (1/f) power spectrum, where the observed noise power is found to increase with time of observation.The results are important in photon counting systems operating under dark count limited mode. The conclusions drawn can be useful in obtaining more accurate error estimates and in assessing astronomical photometric observations and data reduction techniques.     

Is the transition impact to post‐impact rock complete? Some remarks based on XRF scanning,electron microprobe,and thin section analyses of the Yaxcopoil‐1 core in the Chicxulub crater

Abstract The transition from impact to post‐impact rocks in the Yaxcopoil‐1 (Yax‐1) core is marked by a 2 cm‐thick clay layer characterized by dissolution features. The clay overlies a 9 cm‐thick hardground, overlying a 66 cm‐thick crossbedded unit, consisting of dolomite sandstone alternating with thin micro‐conglomerate layers with litho‐ and bioclasts and the altered remains of impact glass, now smectite. The micro‐conglomerates mark erosion surfaces. Microprobe and backscatter SEM analysis of the dolomite rhombs show an early diagenetic, complex‐zoned, idiomorphic overgrowth, with Mn‐rich zones, possibly formed by hot fluids related to cooling melt sheet in the crater. The pore spaces are filled with several generations of coelestite, barite, K‐feldpar, and sparry calcite. XRF core scanning analysis detected high Mn values in the crossbedded sediments but no anomalous enrichment of the siderophile elements Cr, Co, Fe, and Ni in the clay layer. Shocked quartz occurs in the crossbedded unit but is absent in the clay layer. The basal Paleocene marls are strongly dissolved and do not contain a basal Paleocene fauna. The presence of a hardground, the lack of siderophile elements, shocked quartz, or Ni‐rich spinels in the clay layer, and the absence of basal Paleocene biozones P0 and Pa all suggest that the top of the ejecta sequence and a significant part of the lower Paleocene is missing. Due to the high energy sedimentation infill, a hiatus at the top of the impactite is not unexpected, but there is nothing in the biostratigraphy, geochemistry, and petrology of the Yax‐1 core that can be used to argue against the synchroneity of the end‐Cretaceous mass‐extinctions and the Chicxulub crater.     

Self-similar solutions for the blast wave problem in radiative gasdynamics,I

Similarity solutions, describing the flow of a perfect gas behind spherical shock waves, are investigated including the radiation heat flux. The shock is assumed to be propagating in a medium at rest. Shock radius varies exponentially with time and density is inversely proportional to fifth power of the shock radius immediately ahead of the shock front.