Upper limits to trace constituents in Jupiter's atmosphere from an analysis of its 5-μm spectrum

A high-resolution (0.6 cm^?1) spectrum of Jupiter at 5 μm recorded at the Kuiper Airborne Observatory is used to determine upper limits to the column density of 19 molecules. The upper limits to the mixing ratios of SiH₄, H₂S, HCN, and simple hydrocarbons are discussed with respect to current models of Jupiter's atmosphere. These upper limits are compared to expectations based upon the solar abundance of the elements. This analysis permits upper limit measurements (SiH₄), or actual detections (GeH₄), of molecules with mixing ratios with hydrogen as low as 10^?9. In future observations at 5 μm the sensitivity of remote spectroscopic analyses should permit the study of constituents with mixing ratios as low as 10^?10, which would include the hydrides of such elements as Sn and As as well as numerous organic molecules.     

Reservoirs of atmospheric chlorine: Prospects for HOCl revisted

We have re-examined the prospects of HOCl as an inert reservoir for atmospheric chlorine in the light of new theoretical calculations and available experimental measurements of its photodissociation cross-sections. The theoretical calculations and most recent laboratory studies imply that the broad maxima 3200 Å observed in two other experimental spectra may not belong to HOCl. On the basis of this implication HOCl could have a long lifetime against photodissociation in the stratosphere, and could, thereby, become a reservoir for atmospheric chlorine comparable to ClONO₂ or even HCl. In this capacity HOCl could reduce the predicted ozone destruction due to any given level of total chlorine burden. We have also examined the difficulties in laboratory measurements of the HOCl absorption spectrum with particular emphasis on identifying the impurities which may be present in the experimental system. It appears that specialized new experiments are needed to clearly establish the nature and strength of HOCl absorption in the neighbourhood of 3200 Å. Some refinements in the theoretical calculations also seem desirable. In view of the difficulties involved in the laboratory determination of HOCl photodissociation cross-sections, it is suggested that a search for possible stratospheric HOCl by atmospheric spectroscopists would be worthwhile.     

On the relationship of 6300 Å airglow to parameters of the F-region of the ionosphere

It is shown that variations in 6300 Å airglow intensities can, under certain assumptions, be simply related to $\text{?}{}_0\text{F2}$ and its time derivative. In deriving the relationship it is not necessary to assume that the concentration of the neutral atmosphere remains constant and so the relationship is useful on occasions when changes in the neutral atmosphere do occur making it difficult to obtain agreement between observed and calculated 6300 Å intensities; An example is given of a night in which a post-midnight enhancement occurred in the airglow and for which the observations could not be reproduced using a neutral atmosphere constant with time. It is shown that the airglow variations can be explained in terms of the variations of f₀F2, implying that the airglow is due to recombination and that, during the night, changes occurred in the concentrations of the constituents of the neutral atmosphere.     

A study of the magnetic and velocity fields in an active region

A time sequence of magnetograms and velocity-grams in the H and Fe i 6569 Å lines has been made at a rate of 12 h^–1 of McMath Region 10385 from 26 to 29 October, 1969. The 14 flares observed during this period have been studied in relation to the configuration and changes in the magnetic and velocity fields. There was little correlation between flare position and the evolutionary changes in the photospheric magnetic and velocity field, except at large central meridian distances where the velocity observations suggested shearing taking place at flare locations. At central meridian distances > 30° we found that flares are located in areas of low line-of-sight photospheric velocity surrounded by higher velocity hills. The one exception to this was the only flare which produced a surge. Blue-shifted velocity changes in the photosphere of 0.3 to 1 km s^–1 were observed in localized areas at the times of 8 of 14 flares studied.Visiting Astronomer, Kitt Peak National Observatory.Operated by the Association of Universities for Research in Astronomy, Inc., under contract with the National Science Foundation.     

The height variation of granular and oscillatory velocities

Previous observations of spatially-resolved vertical velocity variations in ten lines of Fe i spanning the height range 0 h 1000 km are re-analyzed using velocity weighting functions. The amplitudes and scale heights of granular and oscillatory velocities are determined, as well as those of the remaining unresolved velocities. I find that the optimal representation of the amplitude of the outward-decreasing granular velocities is an exponentially decreasing function of height, with a scale height of 150 km and a velocity at zero height of 1.27 km s^–1. The optimal representation of the same quantities for oscillatory velocities is an exponential increase with height, with a scale height of 1100 km and a velocity at zero height of 0.35 km s^–1. The remaining unresolved velocities decrease with height, with a scale height of 380 km and a velocity at zero height of 2.3 km s^–1.     

The relationship of electron plasma oscillations to type III radio emissions and low-energy solar electrons

An extensive study of the IMP-6 and IMP-8 plasma and radio wave data has been performed to try to find electron plasma oscillations associated with type III radio noise bursts and low energy solar electrons. This study shows that electron plasma oscillations are seldom observed in association with solar electron events and type III radio bursts at 1.0 AU. In nearly four years of observations only one event was found in which electron plasma oscillations are clearly associated with solar electrons. Numerous cases were found in which no electron plasma oscillations with field strengths greater than 1 V/m could be detected even though electrons from the solar flare were clearly detected at the spacecraft.For the one case in which electron plasma oscillations are definitely produced by the electrons ejected by the solar flare, the electric field strength is very small, only about 100 V/m. This field strength is about a factor of ten smaller than the amplitude of electron plasma oscillations generated by electrons streaming into the solar wind from the bow shock. Electromagnetic radiation, believed to be similar to the type III radio emission, is also observed coming from the region of more intense electron plasma oscillations upstream of the bow shock. Quantitative calculations of the rate of conversion of the plasma oscillation energy to electromagnetic radiation are presented for plasma oscillations excited by both solar electrons and electrons from the bow shock. These calculations show that neither the type III radio emissions nor the radiation from upstream of the bow shock can be adequately explained by a current theory for the coupling of electron plasma oscillations to electromagnetic radiation. Possible ways of resolving these difficulties are discussed.     

Helium emission in the middle chromosphere

Slitless spectrograms obtained during the eclipse of 10 June 1972 have been analyzed to determine the height distribution of the D₃ He line intensity.For undisturbed regions the maximum of D₃ line intensity is confirmed to exist at about 1700km above the limb. Besides the above mentioned maximum, in plages a considerable intensity may be observed at low heights (h < 1000 km).An analysis of these observations for h > 1000 km has been carried out within the low temperature mechanism of triplet helium emission taking into account the helium ionization by XUV radiation. The density dependence of the 2³ S level population at different XUV flux values has been calculated. Our observations give N _e 2 × 10¹⁰ cm^–3 in the chromosphere at h = 2000 km. The probable coincidence of the H and He emission small filaments in the middle chromosphere is discussed.     

Scandium,chromium, iron,cobalt and nickel in some basic and ultrabasic rocks from west Norway

Sixteen eclogites and ultrabasic rock samples from west Norway have been analyzed for Sc, Cr, Fe, Co and Ni by instrumental neutron-activation analysis.In gneiss-eclogites, Sc and Co give values from about 30 to 60 ppm and Cr and Ni from 180 to 700 ppm. An eclogite surrounded by a peridotite body shows nearly the same content of Sc and Co as do the gneiss-eclogites, but up to 20 times more Cr. Ni is only slightly more enriched in this particular eclogite than in the others.The ultrabasites have only a few ppm Sc, Co concentrates around 100 ppm while the Cr and Ni values are mainly found between 2 and 3,000 ppm.Fe shows an average value of nearly 10%.