Dissolved Trace Metal–Organic Complexes in the Lot–Garonne River System Determined Using the C18 Sep-Pak System

An 11-month observation of dissolved and particulate organic matter, chlorophyll a(Chl a), C18 Sep-Pak extractable hydrophobic dissolved organic matter (hDOM) fraction and associated dissolved trace metals (Cd, Cu, V, Co, Ni, Mo, U) was performed in the Lot–Garonne River system. This system includes the Riou Mort, the Lot River and the downstream reaches of the Garonne River and represents the fluvial transport path of trace metals between the major point source of polymetallic pollution, located in the Riou Mort watershed and the Gironde estuary. Spatial and temporal variations of dissolved and particulate organic carbon and Chl areflect the presence of different types of organic matter and their relation with the hDOM fraction. Maximum Chl a/POC ratios (up to 0.03), indicate intense phytoplankton production from March to May. In the Lot River (Temple), DOC and POC concentrations were clearly higher and mean Chl a concentration (2.8 mg g⁻¹) was about three times higher than those of the other sites. High Chl a/POC ratios suggest high phytoplankton activity with maxima in spring and late summer. In the Riou Mort River, very high POC concentrations of up to 40 (mean: 20) occurred, whereas Chl a concentrations were relatively low indicating low phytoplankton activity. High, strongly variable DOC and POC concentrations suggest important natural (Carboniferous soils, forests) or anthropogenic (e.g., former coal mines, waste areas, agriculture, sewage) carbon sources within the small Riou Mort watershed. Despite high DOC concentrations in the Riou Mort River, hDOM metal fractions were generally lower than those at the other sites. The general order of decreasing binding strength between metals and the organic hydrophobic phase (Cu, U > Co, Ni > V, Mo > Cd) at all four sites was in good agreement with the Irving–William series of transition element affinity towards organic ligands. Accordingly, the role of the hydrophobic phase in dissolved Cd transport appeared to be negligible, whereas the hDOM–Cu fraction strongly contributed to dissolved Cu transport.     

Investigating the scale of structural controls on chlorinated hydrocarbon distributions in the fractured-porous unsaturated zone of a sandstone aquifer in the UK

Contaminant migration behaviour in the unsaturated zone of a fractured porous aquifer is discussed in the context of a study site in Cheshire, UK. The site is situated on gently dipping sandstones, adjacent to a linear lagoon historically used to dispose of industrial wastes containing chlorinated solvents. Two cores of more than 100 m length were recovered and measurements of chlorinated hydrocarbons (CHCs), inorganic chemistry, lithology, fracturing and aquifer properties were made. The results show that selecting an appropriate vertical sampling density is crucial both to providing an understanding of contaminant pathways and distinguishing whether CHCs are present in the aqueous or non-aqueous phase. The spacing of such sampling should be on a similar scale to the heterogeneity that controls water and contaminant movement. For some sections of the Permo-Triassic aquifer, significant changes in lithology and permeability occur over vertical distances of less than 1 m and samples need to be collected at this interval, otherwise considerable resolution is lost, potentially leading to erroneous interpretation of data. At this site, although CHC concentrations were high, the consistent ratio of the two main components of the plume (tetrachloroethene and trichloroethene) provided evidence of movement in the aqueous phase rather than in dense non-aqueous phase liquid (DNAPL).     

Mercury speciation and mobilization in contaminated soils of the Valle del Azogue Hg mine (SE,Spain)

Hg mobilization from contaminated soils and mine wastes was the source of environmental contamination in the Valle del Azogue mining area. We researched solid-phase speciation and aqueous mobility of Hg through Scanning electron microscopy-energy dispersive X-ray spectroscopy and electron probe microanalysis analysis, solid-phase-Hg-thermo-desorption (SPTD) and laboratory column experiments. We found that in contaminated soils and mine wastes, the predominant Hg species was cinnabar (HgS), mainly formed from the weathering of Hg-rich pyrite, and metallic Hg (0) in the matrix, whereas in calcines and tailings the dominant species was metallic Hg (0). The mobilization of Hg in the aqueous phase seems to have originated from the dissolution of elemental Hg (0) present in soils and wastes, reaching concentrations of up to 67 μg l⁻¹, and showing a higher long-term environmental potential risk, in addition to atmospheric emissions.     

环境样品中痕量元素的化学形态分析Ⅱ．砷汞镉锡铅硒铬的形态分析

环境中元素的生物有效性和毒性依赖于其存在的化学形态。文章依据文献的有关报道介绍砷、汞、镉、锡、铅、硒和铬在环境中的分布、毒性及它们在环境样品如水、土壤、沉积物和生物体中的形态分析方法,包括分析物的保存、提取、分离和检测。引用文献120篇。     

Single frequency processing of Ørsted GPS radio occultation measurements

The Global Positioning System (GPS) radio occultation measurements obtained using the TurboRogue GPS receiver on the Danish satellite Ørsted have been processed using the single frequency method. Atmospheric profiles of refractivity and temperature are derived and validated against numerical weather prediction data from the European Centre for Medium-Range Weather Forecast (ECMWF). Results from the Ørsted GPS measurement campaign in February 2000 indicate that the single frequency method can provide retrievals with accuracy comparable to that of using two frequencies. From comparisons between measured dry temperature profiles and corresponding dry temperature profiles derived from ECMWF analysis fields, we find a mean difference of less than 0.5 K and a standard deviation of 2–4 K between 500 and 30 hPa in height. Above 30 hPa the impact of the ionosphere becomes more dominant and more difficult to eliminate using the single frequency method, and the results show degraded accuracy when compared to previous analysis results of occultation data from other missions using the dual frequency method. At latitudes less than 40° (denoted low latitudes), the standard deviation is generally smaller than at latitudes higher than 40° (denoted high latitudes). A small temperature bias is observed centered at 200 hPa for low latitudes and at 300 hPa for high latitudes. This indicates that the ECMWF analyses do not adequately resolve the tropopause temperature minimum. In the lowest part of the troposphere an observed warm bias is thought to be due to erroneous tracking of the GPS signal in cases of atmospheric multipath propagation.     

World-wide synthetic tide parameters for gravity and vertical and horizontal displacements

The response of the Earth’s crust to the direct effect of lunisolar gravitational forcing is known as the body tide. The body tide is superimposed by surface-loading forces due to the pressure of the periodically varying ocean tide acting on the Earth, called ocean tide loading (OTL). Both body tide and OTL can be decomposed into components of the same frequency known as tidal parameters. However, OTL is more complicated than body tides because of the dynamic effects of the ocean. Estimating OTL requires a model of the ocean tides and knowledge of the elastic properties of the solid Earth. Thus, synthetic tide parameters (amplitude factors and phase leads) have been developed here on a world-wide grid for gravity and positional displacements. The body tide contributions were added to the oceanic contribution to provide the Earth tide response. The accuracy and reliability of the synthetic tidal parameters have been estimated by comparing observed gravity and vertical-displacement tide parameters with those interpolated from our synthetic model, which shows good agreement. Tests also indicate that the synthetic tide parameters provide realistic gravimetric and displacements for practical use in tidal prediction.     

Land use/land cover identification in an alpine and arid region (Nubra Valley, Ladakh) using satellite remote sensing

The remote sensing technology has been widely used for mapping the vegetation types in the tropical landscapes. However, in the temperate and alpine arid regions of India very few studies have been conducted using this technique. In the mountainous temperate arid conditions the vegetation is largely confined to marsh meadows, streams courses, river valleys and moist pockets close to snowfields. The ground truth collection in these zones are physically challenging due to tough terrain and restricted mobility. The detailed mapping of vegetation and other land use classes in these areas is therefore, extremely difficult. This paper describes the use of IRS-ID LISS III sensor for deciphering land cover details Nubra Valley, northern portion of Ladakh Autonomous Hill Council, Jammu & Kashmir (India). This analysis essentially emphasizes in bringing out various vegetation classes (speciallyHippophae rhamnoides and other medicinal plant communities) along the narrow river valleys.     

Wind and Wave Data Analysis for the Aegean Sea - Preliminary Results

In this paper, a statistical analysis on wind and wave buoy measurements and wind and wave model forecasts obtained during a two-year period (1999-2001) is presented with reference to four characteristic near-shore sites of the Aegean Sea. The measurements are a main product of the "POSEIDON" system aiming at the monitoring and forecasting of the state of the Greek seas, operated by the National Centre for Marine Research (NCMR). Although the two-year period is rather short for a thorough analysis of the local wind and wave climate, yet the obtained results, presented herein for the first time, reveal some interesting features of the corresponding wave and wind characteristics. Comparisons between the measurements and the forecast results are also performed at the locations under consideration. It is found that (i) wind speeds obtained from the POSEIDON weather forecasting system are, in general, in agreement with the measurements, except for high wind speeds which are systematically underestimated, (ii) the WAM model can successfully follow the monthly and over year trend of the evolution of wind and wave characteristics, but face significant problems for efficient sea-state forecasting. Finally, the overall pattern of the wind/wave climate for the entire Aegean Sea as obtained from the models is presented by means of the spatial distribution of the mean annual wind and sea-state intensity.     

Distribution of seasonal rainfall in the East Asian monsoon region

Summary ?This study deals with the climatological aspect of seasonal rainfall distribution in the East Asian monsoon region, which includes China, Korea and Japan. Rainfall patterns in these three countries have been investigated, but little attention has been paid to the linkages between them. This paper has contributed to the understanding of the inter-linkage of various sub-regions. Three datasets are used. One consists of several hundred gauges from China and South Korea. The second is based on the Climate Prediction Center (CPC) Merged Analysis of Precipitation (CMAP). The two sources of precipitation information are found to be consistent. The third dataset is the NCEP/NCAR reanalysis 850-hPa winds. The CMAP precipitation shows that the seasonal transition over East Asia from the boreal winter to the boreal summer monsoon component occurs abruptly in mid-May. From late March to early May, the spring rainy season usually appears over South China and the East China Sea, but it is not so pronounced in Japan. The summer monsoon rainy season over East Asia commonly begins from mid-May to late May along longitudes of eastern China, the Korean Peninsula, and Japan. A strong quasi-20-day sub-seasonal oscillation in the precipitation appears to be dominant during this rainy season. The end date of the summer monsoon rainy season in eastern China and Japan occurs in late July, while the end date in the Korean Peninsula is around early August. The autumn rainy season in the Korean Peninsula has a major range from mid-August to mid-September. In southern China, the autumn rainy season prevails from late August to mid-October but a short autumn rainy season from late August to early September is noted in the lower part of the Yangtze River. In Japan, the autumn rainy season is relatively longer from mid-September to late October. The sub-seasonal rainfall oscillation in Korea, eastern China and Japan are explained by, and comparable to, the 850-hPa circulation. The strong westerly frontal zone can control the location of the Meiyu, the Changma, and the Baiu in East Asia. The reason that the seasonal sea surface temperature change in the northwestern Pacific plays a critical role in the northward advance of the onset of the summer monsoon rainfall over East Asia is also discussed. Received October 5, 2001; revised April 23, 2002; accepted May 11, 2002