An electrochemical study of pyrite oxidation in the presence of carbon coatings in cyanide medium

The anodic and cathodic behaviour of pyrite with clay and different carbon coatings of activated carbon, graphite and carbonaceous matter in cyanide medium was investigated using the potentiodynamic method. The presence of clay coating did not change the polarisation curve appearance for either the anodic oxidation of pyrite or the cathodic reduction of oxygen or the potential of the current plateau, but only decreased the plateau current especially at a higher coating thickness. The presence of the carbon coatings marginally shifted the rest potential for pyrite to a more anodic position and slightly changed the polarisation curve appearance for pyrite oxidation. The current density for pyrite oxidation largely increased in the presence of the carbon coatings, the potential at the plateau shifted to more cathodic positions, and the plateau width became smaller. These effects became more noticeable at a higher coating thickness. The activated carbon, graphite and carbonaceous matter coatings performed similarly in affecting pyrite oxidation at a similar thickness. The carbon coatings significantly increased the limiting current densities for oxygen reduction on pyrite, and the limiting current plateau became steeper at a higher coating thickness. The carbon coatings increased the limiting current density for oxygen reduction to a similar extent at a low coating thickness, but increased to varied extents at a higher coating thickness. The carbon coatings also greatly increased the cathodic current density for gold reduction on pyrite. The enhancement of pyrite oxidation and oxygen or gold reduction on pyrite by the carbon coatings was likely attributed to the electrochemical interaction between pyrite and the carbon materials with electron-rich surfaces and high conductivity. The presence of the carbon coatings significantly increased the oxidation of pyrite in aerated cyanide solutions and the preg-robbing of pyrite especially at a higher coating thickness.     

Paleoproterozoic (2155–1970 Ma) evolution of the Guiana Shield (Transamazonian event) in the light of new paleomagnetic data from French Guiana

We present a comprehensive paleomagnetic study on Paleoproterozoic (2173–2060 Ma) plutonic and metamorphic rocks from French Guiana, representative of the full range of the main Transamazonian tectonothermal steps. Twenty-seven groups of directions and poles were obtained from combination of 102 sites (613 samples) based on age constraint, similar lithology and/or geographical proximity. Paleomagnetic results show variations between rocks of different ages which are supposed to be characteristic of magnetizations acquired during uplift and cooling of successive plutonic pulses and metamorphic phases. This is also reinforced by positive field tests (baked contact and reversal tests). Recent U/Pb and Pb/Pb on zircon and complementary ⁴⁰Ar/³⁹Ar on amphibole and biotite allow questioning the problem of magnetic ages relative to rock formation ages. Estimated magnetic ages, based on amphibole dating as a proxy, enable us to construct a Guiana Shield apparent polar wander path for the 2155–1970 Ma period. It is also possible to present paleolatidudinal evolution and continental drift rates related to specific Transamazonian tectonic regimes.French Guiana and probably the Guiana Shield were located at the Equator from ca. 2155 to 2130 Ma during the Meso-Rhyacian D1 magmatic accretion phase, related to subduction of Eorhyacian oceanic crust. After closure of the Eorhyacian Ocean and collision of West African and Amazonian plates, the Guiana Shield moved. The first evolution towards 60° latitude, occurs after 2080 Ma, during the Neorhyacian D2a post collisional sinistral transcurrent phase. During the Late Rhyacian D2b phase, up to 2050 Ma, the Guiana Shield reaches the pole and starts to move to lower latitudes on an opposite meridian. By the Orosirian D2c phase, from ca. 2050 to 1970 Ma, the Guiana Shield reaches the Equator.Based on the amphibole ⁴⁰Ar/³⁹Ar dates, we estimate the continental drift between 12 and 16 cm/y for the Meso to Late Rhyacian period followed by a lower rate between 9 and 14 cm/y up to Orosirian time. This study highlights rock ages and magnetic ages are prerequisite to any continental reconstruction especially when it is shown continental drift is important for a 100–200 Ma time period. Our results confirm the possibility of APWP construction on Paleoproterozoic plutonic rocks but suggest improvement will rely on the combination with multidisciplinary approaches such as structural geology and multi-method radiometric dating.     

Developments in the characterisation of waste materials for environmental impact assessment purposes

The characterisation of waste is entering a new phase with the latest developments of characterisation leaching tests and associated modelling capabilities. The currently applied too simple testing approaches lead to poor choices in waste management. With the increased insight in release controlling processes chemical speciation aspects can be addressed even in the most complex and heterogeneous waste materials. From a composition perspective materials may be highly variable, but often materials are far more consistent in their leaching behaviour. This aspect should be exploited more extensively as it holds the key to treat waste materials in such a way that long term solutions are achieved rather than reaching temporary gains.     

The bimodal rift-related Juscelândia volcanosedimentary sequence in central Brazil: Mesoproterozoic extension and Neoproterozoic metamorphism

The Barro Alto Complex and Juscelândia volcanosedimentary sequence are exposed in the central part of the Neoproterozoic Brasília belt of central Brazil. The former is a large (approximately 150 km long), boomerang-shaped, mafic-ultramafic, layered complex formed by two different intrusions metamorphosed under granulite facies. These rocks are tectonically overlain by rocks of the Juscelândia volcanosedimentary sequence, represented mainly by biotite-gneiss and amphibolite, or amphibolite facies metamorphic equivalents of rhyolite and basalt, respectively. New SIMS U–Pb zircon data and Sm–Nd isochron data presented herein help clarify the igneous and metamorphic evolution of the Juscelândia volcanosedimentary sequence, as well as its relationship with the Barro Alto Complex. Zircon grains from two biotite gneisses were analyzed by SIMS (SHRIMP) and indicate Mesoproterozoic dates, approximately 1.28 Ga, interpreted as the time of bimodal volcanism in a tectonic setting transitional between a continental rift and an ocean basin. Metamorphism is constrained by Sm–Nd garnet-whole-rock isochrons for garnet amphibolite and pelitic schists of the Juscelândia sequence, as well as for clinopyroxene-garnet amphibolite and garnet granulite of the Barro Alto Complex, which give ages between 0.74 and 0.76 Ga, in agreement with SIMS dates for metamorphic zircon rims. These new data are significant, because they establish that a single metamorphic event affected both the Barro Alto Complex and the Juscelândia sequence. Based on these new data, we present a modified tectonic model for the Brasília belt.     

The seismic hazard assessment of the Dead Sea rift, Jordan

The Dead Sea fault system and its branching faults represent one of the most tectonically active regions in the Middle East. The aim of this study is to highlight the degree of hazards related to the earthquake activities associated with the Dead Sea rift, in terms of speculating the possible future earthquakes. The present investigation mainly is based on available data and vertical crustal modeling of Jordan and the Dead Sea model for the Dead Sea basin with particular emphasis of the recent earthquake activities, which occurred on December 31st, 2003 (Mc = 3.7), February 11th, 2004 (strongest Mc = 4.9 R), and March 15th, 2004 (Mc = 4). The present research examines the location of the strong events and correlates them with the various tectonic elements in the area. The source mechanism of the main shock and the aftershock events is also examined. The analyses were based on the available short period seismogram data, which was recorded at the Natural Resources Authority of Jordan, Seismological Observatory. The seismic energy appears to have migrated from the south to the north during the period from December 31st up to March 12th, where the released seismic energy showed a migration character to the southern block of the eastern side of the Dead Sea, which led the seismic event to occur on March 15th.     

Simulation of the Holocene climate evolution in Northern Africa: The termination of the African Humid Period

The Holocene climate evolution in Northern Africa is studied in a 9000-yr-long transient simulation with a coupled atmosphere–ocean–vegetation model forced by changes in insolation and atmospheric greenhouse gas concentrations. The model simulates in the monsoonal domains a significant decrease in precipitation under influence of the orbitally forced reduction in summer insolation. In the Western Sahara region, the simulated mid-Holocene transition from humid to arid conditions (the termination of the African Humid Period) is highly non-linear with the occurrence of centennial-scale climate fluctuations due to the biogeophysical feedback between precipitation and vegetation cover. This result is in agreement with proxy data from the Western Sahara region. The other monsoonal regions experience a more gradual climate evolution that linearly follows the insolation forcing, which appears in disagreement with available lake level records.     

Petrofacies, provenance and diagenesis of the dhosa sandstone member (Chari Formation) at Ler, Kachchh sub-basin, Western India

The sandstones of the Dhosa Sandstone Member of Late Callovian and Early Oxfordian age exposed at Ler have been analyzed for their petrofacies, provenance, tectonic setting and diagenetic history. These sandstones are fine to medium grained and poorly- to well sorted. The constituent mineral grains are subangular to subrounded. These sandstones were derived from a mixed provenance including granites, granite–gneisses, low- and high-grade metamorphic and some basic rocks of the Aravalli Range and Nagarparkar Massif. The petrofacies analysis reveals that these sandstones belong to the continental block-, recycled orogen- and rifted continental margin tectonic regime.The imprints of early and deep burial diagenesis of these sandstones include different stages of compaction, cementation, change in crystal boundaries, cement–cement boundaries, chertification and neomorphism. The sequence of cementation includes precipitation of calcite and its subsequent replacement by Fe calcite and silica cements. The typical intermediate burial (2–3 km depth) diagenetic signatures of these sandstones are reflected in the formation of suture and straight-line boundaries, and triple junctions with straight-line boundaries. The depositional environment, relatively low-energy environment that was below storm wave base but subjected to gentle currents, of the Dhosa Sandstone Member controlled the early diagenesis, which in turn influenced the burial diagenesis of these sandstones.     

First record of a Cretaceous cheilostome bryozoan from Hokkaido, Japan

A small collection of recrystallised, encrusting colonies of a single species from the Mikasa Formation (lower Middle Cenomanian), represents the first record of cheilostome (malacostegan or anascan) bryozoans from Hokkaido, Japan.     

Ophiomorpha irregulaire, rare trace fossil in shallow marine sandstones, Cretaceous Atane Formation, West Greenland

Ophiomorpha irregulaire is a large and extremely rare trace fossil. The type section is in the Book Cliffs, Utah, USA. A second on-shore locality is reported here, in the Nuussuaq Basin of West Greenland. Both occurrences date from the Late Cretaceous. Other reports of O. irregulaire are restricted to two-dimensional sections in well cores and are mostly Jurassic in age. The West Greenland occurrence is in the Atane Formation in shallow marine clean sandstone. The two on-shore localities lie in the same biogeographical region, in connection with the Cretaceous Western Interior Seaway of North America. O. irregulaire is characterized by a sinuous, branched meander maze lying mostly within a single horizontal plane, probably not far beneath the seafloor. The burrow lining has remarkably elongate pellets that probably were emplaced by the burrower. In some cases, diagenetic compression may have deformed the lining pellets to produce their elongated shape. The muddy sediment comprising the lining is almost unrepresented in the clean sands of the substrate, and it was probably trapped from suspension during suspension-feeding activity.     

Variability in drift macroalgal abundance in relation to biotic and abiotic factors in two seagrass dominated estuaries in the Western Gulf of Mexico

We examined the spatial and temporal variability in drift macroalgal abundance in two seagrass dominated estuarine systems on the Texas coast: Redfish Bay (in the Copano-Aransas Estuary) and Lower Laguna Madre. Measurements of benthic macroalgal variability were made in conjunction with a suite of biotic (seagrass biomass, percent cover, blade width and length, shoot density, epiphyte biomass, seagrass blade C:N ratios, and drift macroalgal abundance and composition) and abiotic (inorganic nitrogen and phosphorus concentrations, chlorophylla, total suspended solids, light attenuation, salinity, temperature, total organic carbon and porewater NH₄ ⁺) indicators. All parameters were measured at 30 sites within each estuary semiannually from July 2002 to February 2004. Principal components analysis (PCA) was used to examine relationships between drift macroalgal abundance and biotic and abiotic parameters. In both Redfish Bay and Lower Laguna Madre, drift macroalgal distribution was widespread, and during three of four sampling periods, abundance was equal to abovegro und biomass ofThalassia testudinum, the dominant seagrass. Drift macro algal abundance was highly variable within sites, between sites, and between seasons in both estuaries. No significant differences in drift macroalgal abundance were found between Redfish Bay and Lower Laguna Madre. In Redfish Bay, drift macroalgae (90.1±10.2 gm⁻²) tended to accumulate in bare patches within seagrass beds. In Lower Laguna Madre, drift macroalgae (72.7±10.7 gm⁻²) tended to accumulate in areas of dense seagrass cover rather than in bare areas. We found no relationship between drift macroalgal abundance and low (<2μM) water column nutrient concentrations, and although several of our measured parameters were related to drift macroalgal abundance, none alone sufficiently explained the variability in abundance noted between the two estuarine systems. The contrasting patterns of macroalgal accumulation between Redrish Bay and Lower Laguna Madre likely reflect differences in water circulation characteristics between the two regions as dictated by local physiography, in cluding the shape and orientation of the lagoons, with seasonal variations in macroalgal abundance related to changes in freshwater inflow and nutrient loading.