Dissolution of nanocrystalline fluorite powders: An investigation by XRD and solution chemistry

The effect of lattice disorder and mineral surface area on the reactivity of finely ground fluorite was studied on ball-milled powders. Structural information was provided by X-ray whole powder pattern modeling (WPPM). The mean size of coherent scattering domains decreases with milling time from 70 nm to ∼20 nm, whereas the density of lattice defects increases with both time and intensity of milling treatment, from 4 × 10¹⁵ m^-2 to 24 × 10¹⁵ m^-2. High resolution transmission electron microscopy (HRTEM) of ground fluorite grains shows several line defects and a general tendency of nanometric crystalline domains to agglomerate in larger grains.Solution chemistry was investigated using batch reactors with free drift of solution saturation state with respect to fluorite. Total surface area was measured by the Brunaver, Emmet and Teller (BET) method, and dissolution rates were measured at pH = 2 (HCl) and T = 295 K. In far from equilibrium conditions, dissolution rates normalized by BET area do not increase with the dislocation density. In near-equilibrium condition, however, measured stationary ionic product clearly increases with both time and intensity of milling treatment. Thermodynamic predictions of the solubility constant indicate negligible or little effect of total surface area. Consequently, the observed increase in the stationary ionic product can be related to the increasing lattice defect content. This confirms the significant role of dislocation outcrops on mineral dissolution in close to equilibrium conditions.     

Large-scale stratigraphic architecture and sequence analysis of an early Pleistocene submarine canyon fill,Monte Ascensione succession (Peri-Adriatic basin,eastern central Italy)

The Monte Ascensione succession (c. 2.65–2.1 Ma) is a well-exposed example of an exhumed submarine canyon fill embedded within slope hemipelagic mudstones. This gorge represented a long-lasting pathway for sediment transport and deposition and during the Gelasian delivered Apennine-derived clastic sediment to the adjacent Peri-Adriatic basin. A total of six principal lithofacies types, representing both canyon-confining hemipelagic deposits and canyon-filling turbidity current and mass-transport deposits, can be delineated in the studied sedimentary succession. The canyon-fill deposits display a marked cyclic character and the component lithofacies succeed one another to form at least fifteen fining-upward stratal units, which are interpreted to represent high-frequency, unconformity-bounded depositional sequences. Variability in the vertical repetition of constituent lithofacies allows the identification of three basic styles of sequence architecture that can be interpreted in terms of differing positions along a conceptual down-canyon depositional profile. An integrated chronology, based on biostratigraphic data and on palaeomagnetic polarity measurements, strongly supports a one-to-one correlation between the sequence-bounding surfaces and oxygen isotope stages G2–78, suggesting that the most feasible sequence-engendering mechanism is that of orbitally dictated glacio-eustatic changes in sea level, which regulated timing of sediment storage on the shelf and its redistribution beyond the shelf edge. One of the most significant aspects of this study is the demonstration that processes occurring within upper slope canyons can be expected to be strongly influenced by variations in sea level; that is, the erosional and depositional features evident in these deposits can be strongly controlled by allocyclic processes rather than autocyclic or random processes.     

Analysis of Ground Deformation Detected Using the SBAS-DInSAR Technique in Umbria, Central Italy

Ground deformation affecting the Umbria region (central Italy) in the 9-year period from 1992 to 2000 was investigated through multi-temporal Differential Synthetic Aperture Radar Interferometry (DInSAR). For the purpose, the Small BAseline Subset (SBAS) technique was adopted, which allows studying the temporal evolution of the detected deformation at two spatial scales: a low-resolution (regional) scale, and a full-resolution (local) scale. For the analysis, SAR data acquired by the European Remote Sensing (ERS-1/2) satellites along ascending and descending orbits were used. The detected deformation was analysed to investigate its relevance to geophysical, geomorphologic, and human-induced processes that may result in hazardous conditions to the population of Umbria. Low-resolution deformation data were used to: (i) determine the amount of displacement caused by the Umbria-Marche earthquake sequence from September 1997 to April 1998 in the Foligno area, (ii) determine the number and percentage of the known landslides that can be monitored by the DInSAR technology in the investigated area, and (iii) identify and measure subsidence induced by exploitation of a confined aquifer in the Valle Umbra. Results indicate that earthquakes moved through the Foligno area westwards up to 3.9 cm and with an uplift reaching 1.7 cm. Intersection in a GIS of the low-resolution deformation maps with a detailed landslide inventory map allowed the determination that the portion of landslides that can be monitored by the SBAS-DInSAR technique in Umbria ranges from 2.7% to 3.4%, and the percentage of the total landslide area ranges from 10.4% to 12.8%. In the Valle Umbra, a dependency was found between the time and the amount of detected ground deformation, and the record of water withdrawal. The full-resolution deformation data were used to investigate the movement of the Ivancich landslide, in the Assisi Municipality. Joint analysis of the spatial and the temporal characteristics of the ground displacement allowed the formulation of a hypothesis on the landslide geometry and deformation pattern.     

Local effects on RC frames induced by AAC masonry infills through FEM simulation of in-plane tests

Unreinforced masonry infills are widely used in many parts of the world and it is common practice for seismic design to use simplified methods that usually do not take into account the interaction between the infill and the structure. Starting from the 1950s, many researchers have investigated the lateral response of masonry infills focusing on several different topics. The scientific interest on masonry infills is continuously raising due to the unsatisfactory seismic response of the infilled frame structures observed during post-event inspections and to the difficulty to contrive a widely scientifically and practical recognized solution. Although some modern codes consider the presence of infills with some specifications to prevent damage in the masonry panels and global and local effects on the structure, an effective evaluation of these detrimental effects has not been achieved yet. Within this paper, a FEM simulation of in-plane pseudo-static cyclic tests on a RC frame specimen infilled with unreinforced Autoclaved Aerated Concrete (AAC) masonry infill has been performed in order to study accurately the influence and the interaction of the infill with the RC structure. The experimental results performed by Calvi and Bolognini (J Earthq Eng 5:153–185, 1999), and Penna and Calvi (Campagna sperimentale su telai in c.a. con tamponamenti in Gasbeton (AAC) con diverse soluzioni di rinforzo” (in Italian), 2006) on one-bay one-storey full scale specimens are taken as reference. Non-linear static analyses using a “meso-modelling” approach have been carried out. The masonry used in the model has been calibrated according to tests of mechanical characterization and to in-plane cyclic tests on load-bearing AAC masonry conducted by Costa et al. (J Earthq Eng 15:1–31, 2011). The analyses performed have allowed to investigate the local effects on the frame and, in particular, the changes in the moment and shear demands on the RC elements due to the presence of the AAC infill in comparison with the ones in the bare structure, and to estimate the thrust and the contact length activated by the infill on the frame.     

Analytical and numerical modelling of air trapping during wetting of unsaturated soils

Acta Geotechnica - At high values of degree of saturation, the apparent soil water retention curve (SWRC) measured in a wetting test in the laboratory may differ from the true SWRC, because of the...     

Co‐seismic deformation and post‐glacial slip rate along the Magallanes‐Fagnano fault,Tierra Del Fuego,Argentina

Across the extreme south of Patagonia, the Magallanes‐Fagnano Fault (MFF) accommodates the left‐lateral relative motion between South America and Scotia plates. In this paper, we present an updated view of the geometry of the eastern portion of the MFF outcropping in Tierra del Fuego. We subdivide the MFF in eight segments on the basis of their deformation styles, using field mapping and interpretation of high‐resolution imagery. We quantify coseismic ruptures of the strongest recorded 1949, M_w7.5 earthquake, and determine its eastern termination. We recognize several co‐seismic offsets in man‐made features showing a sinistral shift up to 6.5 m, greater than previously estimated. Using ¹⁰Be cosmogenic nuclides depth profiles, we date a cumulated offset in post‐glacial morphologies and estimate the long‐term slip rate of the eastern MFF. We quantify a 6.4 ± 0.9 mm/a left‐lateral fault slip rate, which overlaps geodetic velocity and suggests stable fault behaviour since Pleistocene.     

Self-standing bent silicon crystals for very high efficiency Laue lens

Silicon mono-crystals have been bent thanks to a series of parallel superficial indentations on one of the largest faces of the crystals. This technique relies on irreversible compression of the crystal beneath and beside the indentations. This latter causes deformation with no need for external device, resulting in a uniform self-standing curvature within the crystal. Indented Si crystals have been characterized at European Synchrotron Radiation Facility using a monochromatic beam ranging from 150 to 700 keV. Crystals exhibited very high diffraction efficiency over a broad range of energy, peaking 95% at 150 keV. Measured angular spread of the diffracted beam was always very close to the morphological curvature of the sample under investigation, proving that the energy passband of bent crystals can be controlled by simply imparting a selected curvature to the sample. The method of superficial indentations was found to offer high reproducibility and easy control of diffraction properties of the crystals. Moreover the method is cheap and simple, being based on mass production tools. A Laue lens made of crystals bent by superficial indentations can provide high-efficiency concentration of hard x-ray photons, leading significant improvement in many astrophysical applications.     

Multiple spacecraft rendezvous maneuvers by differential drag and low thrust engines

A novel two-phase hybrid controller is proposed to optimize propellant consumption during multiple spacecraft rendezvous maneuvers in Low Earth Orbit. This controller exploits generated differentials in aerodynamic drag on each involved chaser spacecraft to effect a propellant-free trajectory near to the target spacecraft during the first phase of the maneuver, and then uses a fuel optimal control strategy via continuous low-thrust engines to effect a precision dock during the second phase. In particular, by varying the imparted aerodynamic drag force on each of the chaser spacecraft, relative differential accelerations are generated between each chaser and the target spacecraft along two of the three translational degrees of freedom. In order to generate this required differential, each chaser spacecraft is assumed to include a system of rotating flat panels. Additionally, each chaser spacecraft is assumed to have continuous low-thrust capability along the three translational degrees of freedom and full-axis attitude control. Sample simulations are presented to support the validity and robustness of the proposed hybrid controller to variations in the atmospheric density along with different spacecraft masses and ballistic coefficients. Furthermore, the proposed hybrid controller is validated against a complete nonlinear orbital model to include relative navigation errors typical of carrier-phase differential GPS (CDGPS). Limitations of the proposed controller appear relative to the target spacecraft’s orbit eccentricity and a general characterization of the atmospheric density. Bounds on these variables are included to provide a framework within which the proposed hybrid controller can effect an extremely low propellant rendezvous of multiple chaser spacecraft to a desired target spacecraft.     

Evaluation of a wind erosion model in a desert area of northern Asia by eddy covariance

For the first time, vertical fluxes of mineral dust measured by Eddy Covariance in two desert sites of Northern Asia have been used to test the performances of a wind erosion model in the field. Soil parameters required by the model were obtained through field and laboratory determinations. Model predictions and direct measurements have been compared. The main finding was that the direction of the horizontal wind relative to the orientation of nebkhas played a crucial role in determining the emission of particles in one of the investigated sites. Being unable to simulate such interaction, the model generally overestimated the actual emission. It provided, instead, reliable predictions (r² = 0·87) when the wind direction was suitable in detaching loose erodible elements placed on nebkhas thanks to their normal orientation. Copyright © 2009 John Wiley & Sons, Ltd.     

Oligocene to Present kilometres scale subsidence and exhumation of the Ligurian Alps and the Tertiary Piedmont Basin (NW Italy) revealed by apatite (U–Th)/He thermochronology: correlation with regional tectonics

The Ligurian Alps segment of the Alpine–Apennine orogen in NW Italy is unconformably covered by Upper Eocene to Holocene sediments in the Tertiary Piedmont Basin (TPB) and Po Plain. These sediments dip towards the north demonstrating the erosional nature of the southern border of the succession and implying that the adjacent orogenic belt formed the substratum rather than the margin of the sedimentary basin. Apatite (U–Th)/He and fission track thermochronology shows that the orogen first subsided and was buried at >4 km from 30 to 26 Ma and began its exhumation thereafter. From 26 Ma to present, this upward movement was contemporaneous with subsidence in the northern TPB. The couple exhumation in the S and subsidence in the N migrated northwards through time. Vertical movements in the area are similar to those reconstructed in Corsica. In both cases, the onset of exhumation becomes younger away from the Ligurian‐Provençal basin and has little correlation with the opening of the surrounding oceanic basins.