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191.
Federica Schiavi Katsura Kobayashi Takuya Moriguti Eizo Nakamura Massimo Pompilio Massimo Tiepolo Riccardo Vannucci 《Contributions to Mineralogy and Petrology》2010,159(4):541-561
During its 1800-year-long persistent activity the Stromboli volcano has erupted a highly porphyritic (HP) volatile-poor scoriaceous
magma and a low porphyritic (LP) volatile-rich pumiceous magma. The HP magma is erupted during normal Strombolian explosions
and lava effusions, while the LP one is related to more energetic paroxysms. During the March–April 2003 explosive activity,
Stromboli ejected two typologies of juvenile glassy ashes, namely highly vesicular LP shards and volatile-poor HP shards.
Their textural and in situ chemical characteristics are used to unravel mutual relationships between HP and LP magmas, as
well as magma dynamics within the shallow plumbing system. The mantle-normalized trace element patterns of both ash types
show the typical arc-lava pattern; however, HP glasses possess incompatible element concentrations higher than LP glasses,
along with Sr and Eu negative anomalies. HP shards are generally characterized by higher Li contents (to ~20 ppm) and lower
δ7Li values (+1.2 to −3.8‰) with respect to LP shards (Li contents of 7–14 ppm and δ7Li ranging between +4.6 and +0.9‰). Fractional crystallization models based on major and trace element compositions, combined
with a degassing model based on open-system Rayleigh distillation and on the assumption that melt/fluidDLi > 1, show that abundant (~30%) plagioclase precipitation and variable degrees of degassing can lead the more primitive LP
magma to evolve toward a differentiated (isotopically lighter) HP magma ponding in the upper conduit and undergoing slow continuous
degassing-induced crystallization. This study also evidences that in March 2003 Stromboli volcano poured out a small early
volume of LP magma that traveled slower within the conduit with respect to later and larger volumes of fast ascending LP magma
erupted during the April 5 paroxysm. The different ascent rates and cooling rates of the two LP magma batches (i.e., pre-
and post-paroxysm) resulted in small, but detectable, differences in their chemical signatures. Finally, this study highlights
the high potential of in situ investigations of juvenile glassy ashes in petrologic and geochemical monitoring the volcanic
activity and of Li isotopes as tracers of degassing processes within the shallow plumbing system. 相似文献
192.
Tewodros Rango Riccardo Petrini Barbara Stenni Gianluca Bianchini Francesca Slejko Luigi Beccaluva Tenalem Ayenew 《Applied Geochemistry》2010,25(12):1860-1871
Water samples from cold and geothermal boreholes, hot springs, lakes and rivers were analyzed for δD, δ18O and 87Sr/86Sr compositions in order to investigate lake water–groundwater mixing processes, water–rock interactions, and to evaluate groundwater flow paths in the central Main Ethiopian Rift (MER) of the Ziway–Shala basin. Different ranges of isotopic values were recorded for different water types: hot springs show δ18O −3.36 to +3.69 and δD −15.85 to +24.23, deep Aluto-Langano geothermal wells show δ18O −4.65 to −1.24 and δD −12.39 to −9.31, groundwater wells show δ18O −3.99 to +5.14 and δD −19.69 to +32.27, whereas the lakes show δ18O and δD in the range +3.98 to +7.92 and +26.19 to +45.71, respectively. The intersection of the Local Meteoric Water Line (LMWL: δD = 7 δ18O + 11.2, R2 = 0.94, n = 42) and the Local Evaporation Line (LEL: δD = 5.63δ18O + 8, n = 14, R2 = 0.82) was used to estimate the average isotopic composition of recharge water into the basin (δD = −5.15 and δ18O = −2.34). These values are depleted if compared with the modern-day average precipitation, presumably indicating paleo-groundwater components recharged during previous humid climatic phases. The measured stable isotope values indicate that the geothermal wells, some of the hot springs and groundwater wells mainly consist of meteoric water. The Sr isotopic signatures in all waters are within the range of the Sr isotopic composition of the rift basalts and rhyolites. The variability of Sr isotopic data also pinpoints complex water–rock interaction and mixing processes in groundwater and surface water. The 87Sr/86Sr ratio ranges from 0.70445 to 0.70756 in the hot springs, from 0.70426 to 0.70537 in two deep geothermal wells, and from 0.70673 to 0.70721 in the rift lakes Ziway, Langano, Shala and Awasa. The radiogenic composition recorded by the lakes indicates that the input water was predominantly affected by progressive interaction with rhyolitic volcanics and lacustrine sediments. 相似文献