Clinopyroxene/liquid trace element partitioning in natural trachyte–trachyphonolite systems: insights from Campi Flegrei (southern Italy)

Trace element partition coefficients between clinopyroxenes and associated glassy matrix (^Cpx/L D) have been determined for 13 REE, HFSE^4+,5+, U, Th, Sr, Pb, Sc and V from combined LA-ICP-MS/EMP analyses in selected trachytes and trachyphonolites from Campi Flegrei. Composition of clinopyroxene and glass is pretty homogeneous in the trachyphonolites, pointing to an overall attainment of the equilibrium conditions. In trachytes, conversely, phases show some compositional heterogeneity (due to the presence of clinopyroxene xenocrysts) that requested a more careful petrographic and geochemical inspection of the samples to assess the equilibrium clinopyroxene composition. In the trachyte clinopyroxenes, REE are compatible from Nd to Lu (^Cpx/L D up to 2.9), like Y, Ti, Sc and V. The ^Cpx/L D for Eu is lower than those of the adjacent REE, highlighting Eu²⁺ contribution. High D values are also shown by U, Th, Pb, Zr, Hf, Nb and Ta relatively to basaltic and andesitic systems, whereas the D _Sr is roughly similar to that found for less evolved magmas. Trachyphonolites are characterized by an overall decrease of the ^Cpx/L D for highly-charged cations (with the exception of V), and by a slight increase of D _Sr. REE are still compatible from Nd to Lu (^Cpx/L D up to 2.1), like Ti, Y, Sc and V. This variation is also predicted for REE and Y by models based on the elastic strain theory, being consistent with the slightly lower polymerization degree estimated for the trachyphonolites. However, the observed ^Cpx/L D _(REE,Y) are matched by the modelled ones only considering very low T (≤825°C), which are believed unlikely. This mismatch cannot be attributed to effects induced by the water-rich composition of the trachyte–trachyphonolite suite, since they would lower the observed ^Cpx/L D _(REE,Y). Moreover, the anomalous inflections of measured ^Cpx/L D for HREE suggests some crystal-chemical control, such as the entrance of these elements in a site distinct from M2. It is concluded that the large ^Cpx/L D determined for trachytes and trachyphonolites are likely induced by hitherto unconstrained changes of the Z³⁺ activities related to the composition of melt and/or solid. All these considerations strongly highlight the importance of a direct characterization of trace element partitioning in natural samples from magmatic systems poorly characterized by experimental studies. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

GRIDA3—a shared resources manager for environmental data analysis and applications

GRIDA3 (Shared Resources Manager for Environmental Data Analysis and Applications) is a multidisciplinary project designed to deliver an integrated system to forge solutions to some environmental challenges such as the constant increase of polluted sites, the sustainability of natural resources usage and the forecast of extreme meteorological events. The GRIDA3 portal is mainly based on Web 2.0 technologies and EnginFrame framework. The portal, now at an advanced stage of development, provides end-users with intuitive Web-interfaces and tools that simplify job submission to the underneath computing resources. The framework manages the user authentication and authorization, then controls the action and job execution into the grid computing environment, collects the results and transforms them into an useful format on the client side. The GRIDA3 Portal framework will provide a problem-solving platform allowing, through appropriate access policies, the integration and the sharing of skills, resources and tools located at multiple sites across federated domains.     

Impact of past mining activity on the quality of groundwater in SW Sardinia (Italy)

Hydrogeochemical surveys were carried out in SW Sardinia (Italy) to investigate the impact of past mining activities on the quality of groundwater. The chemistry of waters from flooded galleries, adits and dumps has been compared with that of springs and wells in the same area at sites relatively far from any mine legacy. A feature, common to all waters, is the circumneutral pH, since the carbonate formations in the area neutralise the acidity produced by the oxidation of Fe-bearing sulphide minerals in the mine impacted water. However, groundwater interacting with mine workings is degraded in quality; it shows high dissolved SO₄, Zn, Cd and Pb contents. In some cases groundwater exceeds the limit established by the guidelines of the World Health Organization for Pb content in drinking water, so that groundwater is mixed before entering the local aqueducts. Results from this study suggest that more attention needs to be paid to the impact on the streams from contaminated water flowing out from some mine areas because during the dry season these streams are only fed by mine groundwater. We recommend focusing efforts to reduce the chemical contamination prior to discharge.     

Impact of the magnitude and frequency of debris‐flow events on the evolution of an alpine alluvial fan during the last two centuries: responses to natural and anthropogenic controls

The dynamics and the surface evolution of a post‐LGM debris‐flow‐dominated alluvial fan (Tartano alluvial fan), which lies on the floor of an alpine valley (Valtellina, Northern Italy), have been investigated by means of an integrated study comprising geomorphological field work, a sedimentological study, photointerpretation, quantitative geomorphology, analysis of ancient to modern cartography and consultation of historical documents and records. The fan catchment meteoclimatic, geological and geomorphological characteristics result in fast rates of geomorphic reorganization of the fan surface (2 km²). The dynamics of the fan are determined by the alternation of low‐return period catastrophic alluvial events dominated by non‐cohesive debris flows triggered by extreme rainstorms which caused aggradation and steepening of the fan and avulsion of its main channel, with periods of low to moderate streamflow discharge punctuated by low‐ to intermediate‐magnitude flood events, causing slower but steady topographic reworking. The most ancient parts of the fan surface date back at least to the first half of the 19th century, but most of the fan surface has been restructured after 1911, mainly during the debris‐flow‐dominated events of 1911 and 1987. Phases of rapid fan toe incision and fan degradation have been recognized; since the 1930s or 1940s, the Tartano fan has been subjected to a state of deep entrenchment and narrowing of the main trunk channel and distributary area. Post‐Little Ice Age climate change and present‐day surface uplift rates have been considered as possible explanations for the observed geomorphic evolution, but tectonic or climatic controls cannot account for the order of magnitude of the erosional pace. Anthropogenic controls plausibly override the natural ones: in particular, the building of a dam in the late 1920s, about 2 km upstream of the fan, seems to have triggered fan dissection, having altered the sediment discharge through sediment retention. Copyright © 2011 John Wiley & Sons, Ltd.     

Tephrochronological study in the quaternary Val d’Agri intermontane basin (Southern Apennines,Italy)

In the south-eastern depocentre of the Val d’Agri basin (Southern Apennines), a volcanic ash layer crops out interbedded within poorly structured alluvial fan deposits of Late Pleistocene age. Textural, depositional and pedological features of this weathered layer suggest a primary deposition from a pyroclastic fall-out of volcanic ash. Chemical analyses of feldspars show an alkali trachytic composition and accessory minerals association allow to correlate this tephra layer with the regionally dispersed Y-7 marine tephra layer (Tufo Verde Epomeo eruption, Ischia volcano), dated at 56 ± 4 ka. The Val d’Agri tephra here described for the first time was deposited during MIS Stage 3. Its recovery and characterization permit to contribute to regional correlation of the Mediterranean climatic and volcanic events from marine to continental successions and to describe landscape evolution of the Southern Apennines during glacial–interglacial cycles.     

AN ION PROBE CONTRIBUTION TO RARE EARTH ELEMENT INVESTIGATION OF GABBRO GOG-1 USING SECONDARY ION MASS SPECTROMETRY

An updated REE measurement of Gabbro GOG-1 was carried out by means of secondary ion mass spectrometry (SIMS). The availability of high amount of rock powder allowed the sample to be well ground and homogenized before analysis. Fused glass pellets were employed for SIMS investigations. REE data were compared with new ICP-AES and NAA analyses. REE results from all employed analytical techniques show good agreement and are consistent with in-situ SIMS measurements of REE in major mineral phases forming GOG-1. Extensive homogeneity tests seem to confirm the possibility to using this rock as a reference material for earth sciences.     

A mafic-ultramafic cumulate sequence derived from boninite-type melts (Niagara Icefalls,northern Victoria Land,Antarctica)

The layered sequence from Niagara Icefalls (northern Victoria Land, Antarctica) is related to the Cambrian-Early Ordovician Ross Orogeny. The sequence consists of dunites, harzburgites, orthopyroxenites, melagabbronorites and gabbronorites of cumulus origin. The Mg# of olivine, spinel, orthopyroxene and clinopyroxene from these rocks yields positive correlations, thus indicating formation from melts that mainly evolved through fractional crystallisation. The following fractionation sequence was identified: olivine (up to 94 mol% forsterite) + Cr-rich spinel → olivine + orthopyroxene ± spinel → orthopyroxene → orthopyroxene + anorthite-rich plagioclase ± clinopyroxene. Clinopyroxenes retain the peculiar trace element signature of boninite melts, such as extremely low concentrations of HREE and HFSE, and LILE enrichment over REE and HFSE. U–Pb isotope data on zircons separated from a gabbronorite have allowed us to constrain the age of emplacement of the Niagara Icefalls sequence at ∼514 Ma. The occurrence of inherited zircons dated at ∼538 Ma indicates that the boninitic melts experienced, at least locally, crustal contamination. The Niagara Icefalls sequence can be related to a regional scale magmatic event that affected the eastern margin of the Gondwana supercontinent in the Middle Cambrian. We propose that the formation of the sequence was associated with the development of an embryonic back-arc basin in an active continental margin. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Numerical modelling of intra-wave sediment transport on sandy beaches using a non-hydrostatic,wave-resolving model

Ocean Dynamics - The mutual feedback between the swash zone and the surf zone is known to affect large-scale morphodynamic processes such as breaker bar migration on sandy beaches. To fully resolve...     

Petrogenetic relationships between peralkaline rhyolite dykes and mafic rocks in the post-Variscan gabbroic complex from Bocca di Tenda (northern Corsica, France)

The Lower Permian complex from Bocca di Tenda (Corsica island, France) consists of a gabbroic sequence crosscut by chilled dykes ranging in composition from basalt to trachyandesite and peralkaline rhyolite. The gabbroic sequence is mostly composed of olivine gabbronorites, quartz gabbronorites/diorites locally displaying high ilmenite amounts, and hornblende-rich tonalites. The quartz gabbronorites/diorites and the hornblende-rich tonalites have similar initial ε_Nd values (+0.9 to ?1.1) and record a fractional crystallization process driven by separation of plagioclase, pyroxene, and ilmenite. The olivine gabbronorites have slightly higher initial ε_Nd than the quartz gabbronorites/diorites and the hornblende-rich tonalites, thereby documenting that the early evolution of the melts that gave rise to the gabbroic sequence was controlled by concomitant fractional crystallization and crustal assimilation. The trachyandesite dykes are rare and rich in dark mica. The selected trachyandesite has initial ε_Nd of +0.4, which is slightly lower than the ε_Nd of the basalt dykes. The basalt and the trachyandesite dykes are most likely genetically related through a process of fractional crystallization controlled by segregation of plagioclase, clinopyroxene and minor ilmenite, and assimilation of crustal material. The peralkaline rhyolites have initial ε_Nd values ranging from +0.3 to ?0.3. Whole-rock chemical variations and trace element compositions of Na-amphibole (arfvedsonite) indicate that the peralkaline rhyolite dykes record a process of fractional crystallization mainly controlled by separation of alkali feldspar and minor ilmenite and arfvedsonite. A plausible petrogenetic hypothesis for the genesis of the peralkaline rhyolite melts implies a protracted process of fractional crystallization from the trachyandesitic melts. This fractionation process would be initially ruled by separation of plagioclase, dark mica, and minor ilmenite. An alternative hypothesis for the origin of the peralkaline rhyolite melts implies partial melting of nearly coeval amphibole-rich mafic intrusives, which formed by crustally contaminated mantle-derived melts. The genesis of the peralkaline rhyolites is in any case correlated with mantle-derived melts that experienced extensive crustal contamination.