Role of melting process and melt–rock reaction in the formation of Jurassic MORB-type basalts (Alpine ophiolites)

This study reports a geochemical investigation of two thick basalt sequences, exposed in the Bracco–Levanto ophiolite (northern Apennine, Italy) and in the Balagne ophiolite (central-northern Corsica, France). These ophiolites are considered to represent an oceanward and a continent-near paleogeographic domain of the Jurassic Liguria–Piedmont basin. Trace elements and Nd isotopic compositions were examined to obtain information about: (1) mantle source and melting process and (2) melt–rock reactions during basalt ascent. Whole-rock analyses revealed that the Balagne basalts are slightly enriched in LREE, Nb, and Ta with respect to the Bracco–Levanto counterparts. These variations are paralleled by clinopyroxene chemistry. In particular, clinopyroxene from the Balagne basalts has higher Ce_N/Sm_N (0.4–0.3 vs. 0.2) and Zr_N/Y_N (0.9–0.6 vs. 0.4–0.3) than that from the Bracco–Levanto basalts. The basalts from the two ophiolites have homogeneous initial Nd isotopic compositions (initial ε_Nd from +?8.8 to +?8.6), within typical depleted mantle values, thereby excluding an origin from a lithospheric mantle source. These data also reject the involvement of contaminant crustal material, as associated continent-derived clastic sediments and radiolarian cherts have a highly radiogenic Nd isotopic fingerprint (ε_Nd at the time of basalt formation?=???5.5 and ??5.2, respectively). We propose that the Bracco–Levanto and the Balagne basalts formed by partial melts of a depleted mantle source, most likely containing a garnet-bearing enriched component. The decoupling between incompatible elements and Nd isotopic signature can be explained either by different degrees of partial melting of a similar asthenospheric source or by reaction of the ascending melts with a lower crustal crystal mush. Both hypotheses are reconcilable with the formation of these two basalt sequences in different domains of a nascent oceanic basin.     

Comparison of three geostatistical methods for hydrofacies simulation: a test on alluvial sediments

The hydrodispersive properties of porous sediments are strongly influenced by the heterogeneity at fine scales, which can be modeled by geostatistical simulations. In order to improve the assessment of the properties of three different geostatistical simulation methods (Sequential indicator simulation, SISIM; Transition probability geostatistical simulation, T-PROGS; Multiple point simulation, MPS) a comparison test at different scales was performed for a well-exposed aquifer analogue. In the analysed volume (approximately 30,000?m³) four operative hydrofacies have been recognised: very fine sand and silt, sand, gravelly sand and open framework gravel. Several equiprobable realizations were computed with SISIM, MPS and T-PROGS for a test volume of approximately 400?m³ and for the entire volume, and the different outcomes were compared with visual inspection and connectivity analysis of the very or poorly permeable structures. The comparison of the different simulations shows that the geological model is best reproduced when the simulations are realised separately for each highest rank depositional element and subsequently merged. Moreover, the three methods yield different images of the volume; in particular MPS is efficient in mapping the geometries of the most represented hydrofacies, whereas SISIM and T-PROGS can account for the distribution of the less represented facies.     

Coseismic rotation changes from the 2004 Sumatra earthquake: the effects of Earth's compressibility versus earthquake induced topography

Polar motion is modelled for the large 2004 Sumatra earthquake via dislocation theory for an incompressible elastic earth model, where inertia perturbations are due to earthquake-triggered topography of density–contrast interfaces, and for a compressible model, where inertia perturbation due to compression-dilatation of Earth's material is included; density and elastic parameters are based on a multilayered reference Earth. Both models are based on analytical Green's functions, propagated from the centre to the Earth's surface. Preliminary and updated seismological solutions are considered in elucidating the effects of improving earthquake parameters on polar motion. The large Sumatra thrust earthquake was particularly efficient in driving polar motion since it was responsible for large material displacements occurring orthogonally to the strike of the earthquake and to the Earth's surface, as imaged by GRACE gravity anomalies over the earthquake area. The effects of earthquake-induced topography are four times larger than the effects of Earth's compressibility, for l = 2 geopotential components. For varying compressional Earth properties and seismic solution, modelled polar motion ranges from 8.6 to 9.4 cm in amplitude and between 117° and 130° east longitude in direction. The close relationship between polar motion direction, earthquake longitude and thrust nature of the event, are established in terms of basic physical concepts.     

A new simple approach to evaluate pedogenic clay transformation in a Vertic Calcisol

The aim of this study is to characterize the pedogenic clay minerals by using simple approach: mixing mineralogical and geochemical findings.The fine clay fractions (< 0.1 μm) of a Vertic Cambisol profile were studied by means of X-ray diffraction (XRD), infrared spectroscopy (FTIR) and cation exchange capacity (CEC).Qualitative and quantitative mineralogical compositions of the clay mixture were determined.Moreover, chemical equilibria and thermodynamic stabilities of minerals (calcite, gypsum, kaolinite, smectites and illites) were studied using results of ionic activities obtained from total concentration of various aqueous species in water extracts from soil-saturated pastes.XRD analysis shows a good homogeneity in the mineralogical composition of the soil material, with depth of soil profiles. The identified clay minerals are mainly illite–smectite mixed layers (I/S) and kaolinite. The chemical analysis of saturated paste extracts with clay minerals shows a slight undersaturation of the illitic phase while smectites and also calcite and gypsum reach the thermodynamic equilibrium along the soil profile.     

Isotope geochemistry (Sr–Nd–Pb) and petrogenesis of leucite-bearing volcanic rocks from “Colli Albani” volcano, Roman Magmatic Province, Central Italy: inferences on volcano evolution and magma genesis

The “Colli Albani” composite volcano is made up of strongly silica-undersaturated leucite-bearing rocks. Magmas were erupted during three main periods, but a complex plumbing system dominated by regional tectonics channelled magmas into different reservoirs. The most alkali-rich magmas, restricted to the caldera-forming period (pre-caldera), are extremely enriched in incompatible trace elements and display more radiogenic Sr (⁸⁷Sr/⁸⁶Sr?=?0.71057–0.71067), with slightly less radiogenic Pb with respect to those of the post-caldera period. Post-caldera volcanic activity was concentrated in three different volcanic environments: external to the caldera, along the caldera edge and within the caldera. The post-caldera magmas produced melilite- to leucitite-bearing, plagioclase-free leucitites. In contrast to the pre-caldera lavas, they are characterised by lower incompatible trace element abundances and less radiogenic Sr (⁸⁷Sr/⁸⁶Sr?=?0.71006–0.71039). Magmas evolved through crystal fractionation plus minor crustal assimilation in a large magma chamber during the pre-caldera period. The multiple caldera collapses dissected and partially obliterated the early magma chamber. During the post-caldera stage, magmas were channelled through several pathways and multiple shallow-level magma reservoirs were established. A lithospheric mantle wedge previously depleted in the basaltic component and subsequently enriched by metasomatic slab-derived component is suggested as the mantle source of Colli Albani parental magmas. Two different parental magmas are recognised for the pre- and post-caldera stages. The differences may be related to the interplay between smaller degrees of melting for the pre-caldera magmas and more carbonate-rich recycled subducted lithologies in the post-caldera magmas.     

History of X-ray telescopes and astronomy

The development of X-ray telescopes over the last 45 years is briefly summarized. The first applications to the study of solar X-ray emission are described up to the 1973 Skylab mission. The rather convoluted path that led to the first stellar X-ray orbiting telescope Einstein (1978) and later to Chandra (1999) are discussed. During this 45 years period the angular resolution improved from 20 to 0.5 arc sec and the sensitivity by ten billions. X-ray observations have discovered new types of stellar systems (binary X-ray sources containing neutron stars and black holes) and intergalactic high temperature plasmas containing most of the baryonic mass of the universe. They have become an indispensable tool to study the role of energetic phenomena in the creation and dynamic evolution of cosmic structures. The methodology introduced by X-ray astronomy has influenced all of astronomy.     

The Campo Imperatore Near Earth Object Survey (CINEOS)

The Campo Imperatore Near Earth Object Survey (CINEOS) is an Italian survey dedicated to the search and follow-up of Near Earth Objects (NEOs). It is operated with the 90 cm f/3 Schmidt telescope at the Campo Imperatore of the Rome Astronomical Observatory (INAF-OAR) as a joint project with the Istituto di Astrofisica Spaziale and Fisica Cosmica (INAF-IASF) in Rome. Since the end of 2001 CINEOS has covered about 4,250 sq. deg to 20th magnitude in the course of about 160 nights. This effort led to the discovery of 7 Near Earth Asteroids (NEAs), 1 comet (167P/CINEOS; a member of the Centaur group) and a few other unusual objects including 2004 XH₅₀ with a unique comet-like orbit. CINEOS has also contributed almost 2,200 preliminary designations and over 30,000 detections to the Minor Planet Center. About 20% of the survey effort was carried out at low solar elongations (LSE), although no object with an orbit interior (Inner Earth Objects, IEO class) or nearly interior to the Earth (Aten class) was found. The work at LSE was, however, very important to test survey strategies implemented with larger telescopes. We also provide the results of a CINEOS simulation on a reliable NEO population model based on the results of two larger scale surveys, Spacewatch and LINEAR.     

Thick self-standing bent crystals as optical elements for a Laue lens for applications in astrophysics

In this paper we report progresses in the realization of self-standing bent crystals, which are suitable as optical elements for Laue lenses, i.e. for optic to focus hard X-rays in the 100–1000 keV energy range. The curvature of the crystals is a key factor to enhance diffraction efficiency and energy bandpass for such an optic. In particular, two bent crystals featuring a thickness of 5 mm, made of Si and Ge respectively, were produced at the Sensor and Semiconductor Laboratory in Ferrara, Italy. The crystals were bent through the application of a carbon fibre composite. This proved to be a relatively low cost method for crystal bending, suitable for mass production. The manufactured samples were characterised via optical interferometry, and showed a fairly uniform curvature. Finally, the samples were tested exploiting hard X-ray diffraction at the ID11 facility of the European Synchrotron Radiation Facility (ESRF) in Grenoble, France. A careful analysis of the experimental data highlighted that the samples feature large energy bandpass, wide geometrical acceptance for incoming hard X-rays, and high diffraction efficiency. We therefore conclude that such self-standing crystals are good candidates as Laue lens components for astrophysics applications.     

Constraints on the Genesis of Potassium-rich Italian Volcanic Rocks from U/Th Disequilibrium

We present new U-series isotope, ⁸⁷Sr/ ⁸⁶Sr, ¹⁴³Nd/ ¹⁴⁴Nd andtrace element data for a set of mafic, K-rich rocks from volcanoesin Central–Southern Italy. These shoshonitic to ultrapotassiclavas display strongly depleted high field strength element(HSFE) abundances with respect to other incompatible trace elementstogether with high but variable ⁸⁷Sr/ ⁸⁶Sr and low but variable¹⁴³Nd/ ¹⁴⁴Nd values. Such characteristics are thought to bedue to addition of subducted crust of variable amount and compositionto their mantle sources prior to magma genesis. Rocks from thenorthernmost region (i.e. Tuscan Magmatic Province and NorthernRoman Magmatic Province) display (²³⁰Th/ ²³⁸U) activity ratiosclose to radioactive equilibrium, suggesting that metasomatismof their sources occurred before 400 ka and recent melting tookplace at shallow depths, in the absence of garnet. A ²³⁸U excessof up to 27% has been measured in rocks from the NeapolitanDistrict. The occurrence of significant U excesses is a featureof arc magmas, but is typically seen in depleted lavas ratherthan in highly enriched rocks such as these (20 ppm Th). Thissignature requires a recent addition of a U-rich component tothe already strongly enriched mantle wedge beneath this regionof Italy. We suggest that a supercritical liquid, from deeplysubducted carbonate-rich sediments of the still-active Ionianslab, is responsible for generating a high-U, low-Th component,which produces the observed disequilibria. A 30% ²³⁰Th excessmeasured in a single unaltered sample from the Lucanian MagmaticProvince, along with a less marked negative HFSE anomaly, suggeststhe contribution of a deeper, garnet-bearing component in thegenesis of these magmas, plausibly related to the upwellingof asthenospheric mantle around the corner of the Ionian slab. KEY WORDS: U/Th disequilibria; potassic and ultrapotassic rocks; subduction: metasomatism; mantle melting; Central and Southern Italy