Mineralogy of Erromango lavas (New Hebrides): Evidence of an early stage of fractionation in island arc basalts

The orogenic volcanic rocks of Erromango island are divided into a Quaternary theoleiitic group and an older Pliocene one showing calc-alkalic affinity. The microprobe mineralogy of these lavas agrees with this geochemical distinction and indicates a marked iron enrichment trend in the recent tholeiitic lavas, whereas titanomagnetite occurs as early formed phenocrysts (Al, Cr, Mg-rich) only in Pliocene basalts. Some Ni and Mg-rich olivine phenocrysts (Fo88) and unusual chemically zoned clinopyroxene megacrysts are described from Pliocene basic lavas and interpreted as deep-fractionated minerals. The large compositional range of these latter (diopside core to augite rim, through salite intermediate zone) leads us to discuss the physical conditions and the corresponding cation substitutions prevailing during their formation. Diopside cores crystallized at depths of about 20 km from a relatively ‘primitive’ melt. The formation of salite is considered to be the result of concomitant fractionation of Mg-rich phases and increase of f_O2. An early stage of fractionation of Cr-bearing diopside + Ni-bearing olivine would account for the typical Cr and Ni depletion of Erromango lavas.     

The stratigraphic record of minibasin subsidence,Precaspian Basin,Kazakhstan

Minibasins are fundamental components of many salt-bearing sedimentary basins, where they may host large volumes of hydrocarbons. Although we understand the basic mechanics governing their subsidence, we know surprisingly little of how minibasins subside in three-dimensions over geological timescales, or what controls such variability. Such knowledge would improve our ability to constrain initial salt volumes in sedimentary basins, the timing of salt welding and the distribution and likely charging histories of suprasalt hydrocarbon reservoirs. We use 3D seismic reflection data from the Precaspian Basin, onshore Kazakhstan to reveal the subsidence histories of 16, Upper Permian-to-Triassic, suprasalt minibasins. These minibasins subsided into a Lower-to-Middle Permian salt layer that contained numerous relatively strong, clastic-dominated minibasins encased during an earlier, latest Permian phase of diapirism; because of this, the salt varied in thickness. Suprasalt minibasins contain a stratigraphic record of symmetric (bowl-shaped units) and then asymmetric (wedge-shaped units) subsidence, with this change in style seemingly occurring at different times in different minibasins, and most likely prior to welding. We complement our observations from natural minibasins in the Precaspian Basin with results arising from new physical sandbox models; this allows us to explore the potential controls on minibasin subsidence patterns, before assessing which of these might be applicable to our natural example. We conclude that due to uncertainties in the original spatial relationships between encased and suprasalt minibasins, and the timing of changes in style of subsidence between individual minibasins, it is unclear why such complex temporal and spatial variations in subsidence occur in the Precaspian Basin. Regardless of what controls the observed variability, we argue that vertical changes in minibasin stratigraphic architecture may not record the initial (depositional) thickness of underlying salt or the timing of salt welding; this latter point is critical when attempting to constrain the timing of potential hydraulic communication between sub-salt source rocks and suprasalt reservoirs. Furthermore, temporal changes in minibasin subsidence style will likely control suprasalt reservoir distribution and trapping style.     

Temporal Geochemical Evolution of Neogene Magmatism in the Baguio Gold–Copper Mining District (Northern Luzon, Philippines)

Baguio, in the Central Cordillera of Northern Luzon, is a district that displays porphyry copper and epithermal gold mineralization, associated with Early Miocene–Pliocene–Quaternary calc‐alkaline and adakitic intrusions. Systematic sampling, K‐Ar dating, major and trace elements, and Sr, Nd, Pb isotopic analyses of fresh magmatic rocks indicate three magmatic pulses: an Early Miocene phase (21.2–18.7 Ma), a Middle–Late Miocene phase (15.3–8 Ma) and finally a Pliocene–Quaternary event (3–1 Ma). The first phase emplaced evolved calc‐alkaline magmas, essentially within the Agno Batholith complex, and is thought to be related to the westward‐dipping subduction of the West Philippine Basin. After a quiescence period during which the Kennon limestone was deposited, magmatic activity resumed at 15.3 Ma, in connection with the start of the subduction of the South China Sea along the Manila Trench. It emplaced first petrogenetically related and relatively unradiogenic low‐K calc‐alkaline lavas and intermediate adakites. Temporal geochemical patterns observed from 15.3 to 1 Ma include progressive enrichment in K and other large ion lithophile elements, increase in radiogenic Sr and Pb and corresponding decrease in radiogenic Nd. These features are thought to reflect the progressive addition to the Luzon arc mantle wedge of incompatible elements largely inherited from South China Sea sediments. The origin of the long quiescence period, from 8 to 3 Ma, remains problematic. It might represent a local consequence of the docking of the Zambales ophiolitic terrane to Northern Luzon. Then, magmatic activity resumed at 3 Ma, emplacing chemically diversified rocks ranging from low K to high K and including a large proportion of adakites, especially during the Quaternary (dacitic plugs). The authors tentatively relate this diversity to the development of a slab tear linked with the subduction of the fossil South China Sea ridge beneath the Baguio area.     

Exploring aberrant bivalve shell ultrastructure and geochemistry as proxies for past sea water acidification

Throughout much of Earth's history, marine carbonates have represented one of the most important geological archives of environmental change. Several pivotal events during the Phanerozoic, such as mass extinctions or hyperthermal events have recently been associated with ocean acidification. Nevertheless, well‐defined geological proxies for past ocean acidification events are, at best, scarce. Here, experimental work explores the response of bivalve shell ultrastructure and isotope geochemistry (δ¹³C, δ¹⁸O and δ²⁶Mg) to stressful environments, in particular to sea water acidification. In this study, the common blue mussel, Mytilus edulis, was cultured (from early juvenile stages to one year of age) at four pH regimes (pH_NBS 7·2 to pH 8·0). Shell growth rate and ultrastructure of mainly the calcitic portion of the shells were compared between experimental treatments. Specimens exposed to low‐pH environments show patches of disordered calcitic fibre orientation in otherwise well‐structured shells. Furthermore, the electron backscattered diffraction analyses reveal that, under acidified conditions, the c‐axis of the calcite prisms exhibits a bimodal or multi‐modal distribution pattern. Similar shell disorder patterns have been reported from mytilids kept under naturally acidified sea water conditions. In contrast, this study found no evidence that different pH regimes affect shell carbon, oxygen or magnesium isotope ratios. Based on these observations, it is proposed that: (i) stressful environments, in this case low sea water pH, predictably affect bivalve biomineralization patterns; and (ii) these findings bear potential as a novel (petrographic) proxy for ancient sea water acidification. An assessment of the applicability of these data to well‐preserved fossil shell material from selected time intervals requires additional work.     

Novel Algorithms for Astronomical Plate Analyses

Powerful computers and dedicated software allow effective data mining and scientific analyses in astronomical plate archives. We give and discuss examples of newly developed algorithms for astronomical plate analyses, e.g., searches for optical transients, as well as for major spectral and brightness changes.     

Statistical Properties of the Immediate Aftershocks of the 15 October 2013 Magnitude 7.1 Earthquake in Bohol,Philippines

The aftershock records of the magnitude 7.1 earthquake that hit the island of Bohol in central Philippines on 15 October 2013 is investigated in the light of previous results for the Philippines using historical earthquakes. Statistics of interevent distances and interevent times between successive aftershocks recorded for the whole month of October 2013 show marked differences from those of historical earthquakes from two Philippine catalogues of varying periods and completeness levels. In particular, the distributions closely follow only the regimes of the historical distributions that were previously attributed to the strong spatio-temporal correlations. The results therefore suggest that these correlated regimes which emerged naturally from the analyses are strongly dominated by the clustering of aftershock events.     

Airborne Gravimetry Survey for the Marine Area of the United Arab Emirates

The Military Survey Department (MSD) of the United Arab Emirates (UAE) undertook an airborne gravity survey project for the marine area of the country in 2009, especially to strengthen the marine and coastal geoid in the near-shore regions. For the airborne gravity survey, 5 km spacing coast-parallel flight lines were planned and surveyed. These lines were supplemented by cross-lines in order to assess the quality of the airborne gravity surveys. The flight lines were extended 10 km, spacing lines further offshore. A Beech King Air 350 aircraft was used for the surveys, collecting data at a typical flight speed of 170 knots and a typical flight elevation of 900–1500 m, depending on weather conditions and topography. Gravity was measured with a ZLS-modified LaCoste and Romberg gravimeter (S-99), augmented with a Honeywell strap-down inertial navigation system unit. The estimated accuracy for the airborne gravity data is better than 2.0 mGal r.m.s., as judged from the airborne track crossovers. The new airborne gravimetry data changed the UAE coastal geoid by up to 30 cm in some regions, highlighting the importance of airborne gravity coastal surveys.     

Distinguishing salt welds from shale detachments on the inner Texas shelf, western Gulf of Mexico

Detachment surfaces have important implications for structural restoration, burial-history and thermal modeling, hydrocarbon migration, and diagenesis. We present criteria to distinguish salt welds from shale detachments based on geophysical data from the inner Texas shelf. Here, the Paleogene detachment has been variously interpreted as salt or shale by different people. A newly reprocessed 8200 km² (3200 mi²) 3D seismic volume provides excellent imaging of this detachment, which separates growth-faulted Oligocene–Miocene strata from the underlying, gently folded Cretaceous–Eocene section. Key criteria to evaluate detachment origins include seismic amplitude response, geometry, and relationship to supradetachment and subdetachment reflections. We argue that the detachment is a salt weld because (a) it is imaged as a high-amplitude, discrete reflection; (b) it has a ramp-flat geometry, cutting across underlying reflections; (c) it locally forms bowl-shaped depotroughs interpreted as former diapiric salt feeders; (d) it is overlain by seismically incoherent pods having high-amplitude tops and bases interpreted as remnant salt; and (e) in the depotroughs associated with former diapiric salt feeders the detachment has hints of upturned strata just beneath (possible halokinetic sequences). The inferred weld represents the evacuated remains of a patchy salt canopy emplaced across the study area during the Late Eocene to Early Oligocene. Preliminary examination beyond our study area suggests that this discontinuous canopy may have extended across most of the modern Texas shelf. Most of the salt was expelled from the canopy by loading from prograding Oligo–Miocene deltaic deposits.     

Melt inclusions in high-An plagioclase from the Gorda Ridge: an example of the local diversity of MORB parent magmas

 The use of ocean floor basalt chemistry as a tool to investigate mantle composition and processes requires that we work with basalts that have been modified little since leaving the mantle. One source of such basalts is melt inclusions trapped in primitive crystals. However, obtaining information from these melt inclusions is complicated by the fact that melt inclusions in natural basalts are essentially always altered by post-entrapment crystallization. This requires that we develop techniques for reconstructing the original trapped liquid compositions. We conducted a series of experiments to reverse the effects of post-entrapment crystallization by re-heating the host crystals to their crystallization temperature. For these experiments we used plagioclase crystals separated from a single Gorda Ridge lava. The crystallization temperature for these crystals was determined by a set of incremental re-heating experiments to be ∼1240–1260° C. The inclusions are primitive, high Ca-Al basaltic melts, saturated with plagioclase, olivine and Al-rich chromite at low pressure. The inclusion analyses can be linked to the host lava composition by low pressure fractionation. The major element composition of the re-homogenized melt inclusions within each crystal is relatively constant. However, the incompatible element analyses have extremely wide ranges. The range of La/Sm and Ti/Zr from inclusions analyzed from a single sample from the Gorda Ridge exceeds the range reported for lavas sampled from the entire ridge. The pyroxene compositions predicted to be in equilibrium with the melt inclusion trace element signature cover much of the range represented by pyroxenes from abyssal peridotites. The volumetric proportions of the magmas entering the base of the crust can be evaluated using frequency distribution of melt inclusion compositions. This distribution suggests that the array of magmas was skewed towards the more depleted compositions, with little evidence for an enriched component in this system. This pattern is more consistent with a dynamic flow model of the mantle or of a passive flow model where the melts produced in the peripheral areas of the melting regime were not focused to the ridge. Received: 5 January 1995 / Accepted: 13 June 1995     

X-Ray and optical observations of the X-ray source EX0020528+1454.8

We present preliminary results of the EXOSAT X-ray observations and quasisimultaneous and simultaneous optical photometry of the X-ray source EX0020528+1454.8=1E0205+149 found independently as an serendipitous source both with Einstein and EXOSAT satellites. The optical counterpart is a pair of dMe stars. Our results indicate that the object is variable both in X-rays and optical wavelenghts, and probably belongs to dMe flare stars.Paper presented at the IAU Colloquium No. 93 on Cataclysmic Variables. Recent Multi-Frequency Observations and Theoretical Developments, held at Dr. Remeis-Sternwarte Bamberg, F.R.G., 16–19 June, 1986.