Zircon geochronology reveals polyphase magmatism and crustal anatexis in the Buchan Block,NE Scotland: Implications for the Grampian Orogeny

The type locality for high-temperature,low-pressure regional metamorphism,the Buchan Block in NE Scotland,exhibits profound differences to the rest of the Grampian Terrane.These differences have led some to regard the Buchan Block as an exotic crustal fragment comprising Precambrian basement gneisses and cover rocks thrust into their current position during Grampian orogenesis.Although rocks of the Buchan Block are now generally correlated with Dalradian strata elsewhere,the origin of the gneisses and the cause of the high heat flow and associated magmatism is debated.We report SIMS U-Pb and LA-ICPMS Hf isotopic data in zircon from high-grade rocks from the northeast(Inzie Head Gneiss)and northwest(Portsoy)corners of the Buchan Block.Around Inzie Head,upper amphibolite to granulite facies metasedimentary gneisses coexist with diorite sheets that were emplaced contemporaneously with partial melting of their host rocks,at least locally.U-Pb geochronology indicates a crystallisation age for the diorite of 486±9 Ma.Highly-deformed diorites within the Portsoy Gabbro have a crystallisation age of 493±8 Ma.Ages of ca.490 Ma for magmatism and high-grade metamorphism,which are broadly contemporaneous with ophiolite obduction and the onset of orogenesis,are significantly older than the established peak of Grampian metamorphism(ca.470 Ma).We propose a new model for the Grampian Orogeny involving punctuated tectonothermal activity due to tectonic switching during accretionary orogenesis.Rollback of a NW-dipping subduction zone at ca.490 Ma produced a back-arc environment(the Buchan Block)with associated arc magmatism and high dT/dP metamorphism.Arrival of an outboard arc resulted in shortening(the initial phase of the Grampian Orogeny)at ca.488 Ma.Rollback of a NW-dipping subduction zone to the SE of the ca.488 Ma suture began at 473 Ma and led to lithospheric-scale extension,decompression melting and advective heating of the middle crust,producing the widespread ca.470 Ma Grampian(classic Barrovian and Buchan)regional metamorphism.Resumed hinge advance and the final phase of shortening cut off the heat supply at ca.465 Ma,marking the end of the Grampian Orogeny.     

Influence of pH on Sporulation,Spore Germination and Germling Survival in Blue-green Algae

An investigation is made on the influence of the pH-value in the range of pH = 4.5 to 11.0 on sporulation, germination and germling development of Anabaena fertilissima and Anabaenopsis arnoldii, isolated from the Sambhar Salt Lake, Rajasthan. Maximum rates of germination were obtained with Anabaena at pH = 7.0… 10.5, with Anabaenopsis at pH = 7.0 to 8.5. With both species, sporulation occurs in the same pH-ranges, Anabaena dying without sporulation in the range of pH = 5.5… 6.5 and above pH = 10.5 and Anabaenopsis surviving without sporulation above pH = 9.5. With Anabaena the germling growth steadily increases from pH = 7 to 10.5, whereas Anabaenopsis shows a maximum at pH = 7 and at any other pH-value growth is considerably lower. Moreover, spore germination is bound to an exchange of the medium. In agreement with these experimental findings concerning the cultures, from July to February Anabaenopsis occurs in the Sambhar Lake as a vegetative form with a partial mass development, and from March to June it survives as a spore. Anabaena, however, has only a short vegetative phase in June, and it survives the remaining part of the year as a spore. Thus, the fast germination and sporulation in the range of higher alkalinity is the ecological strategy for Anabaena to resist the competition offered by Anabaenopsis.     

A string cosmological model in a scalar – Tensor theory of gravitation

An exact Boanchi type -I string cosmological model is obtained in a scalar-tensor theory of gravitation proposed by Saez and Ballester (1985). Some physical properties of the model are also discussed. This revised version was published online in July 2006 with corrections to the Cover Date.     

Optimization of spatial statistical approaches to identify land use/land cover change hot spots of Pune region of Maharashtra using remote sensing and GIS techniques

This study investigated land use/land cover change (LULCC) dynamics using temporal satellite images and spatial statistical cluster analysis approaches in order to identify potential LULCC hot spots in the Pune region. LULCC hot spot classes defined as new, progressive and non-progressive were derived from Gi* scores. Results indicate that progressive hot spots have experienced high growth in terms of urban built-up areas (20.67% in 1972–1992 and 19.44% in 1992–2012), industrial areas (0.73% in 1972–1992 and 3.46% in 1992–2012) and fallow lands (4.35% in 1972–1992 and ?6.38% in 1992–2012). It was also noticed that about 28.26% of areas near the city were identified as new hot spots after 1992. Hence, non-significant change areas were identified as non-progressive after 1992. The study demonstrated that LULCC hot spot mapping through the integrated spatial statistical approach was an effective approach for analysing the direction, rate, spatial pattern and spatial relationship of LULCC.     

Multiseason evaluation of the MM5, COAMPS and WRF over southeast United States

Three models, MM5, COAMPS, and WRF, have been applied for the warm season in 2003 and the cool season in 2003?C2004 to evaluate their performances. All models run over the same domain area covering the north Gulf Mexico and southeastern United States (US) region with the same spatial resolution of 27?km. It was found that the temporal variations of the mean error distribution and strength at 24 and 36?h were rather weak for surface temperature, sea level pressure, and surface wind speed for all models. A warm bias in surface temperature forecasts dominated over land during the warm season, whereas a cool bias existed during the cool season. The MM5 and WRF produced negative biases of sea level pressure during the warm season and positive biases during the cool season while the COAMPS yielded a similar distribution of sea level pressure biases during both seasons. During both seasons, similar surface wind speed biases produced by each model included a high wind speed forecast over most areas by MM5 while the COAMPS and WRF yielded weak surface winds over the western Plains and stronger surface winds over the eastern Plains. Root-mean-squared errors revealed that the forecast of surface temperature, sea level pressure, and surface wind speed were degraded with the increase of forecast time. For rainfall evaluation, it was found that the MM5 underpredicted seasonal precipitation while the COAMPS and WRF overpredicted. The bias scores revealed that the MM5 yielded an underprediction of the coverage of precipitation areas, especially for heavier rainfall events. The MM5 presented the lower threat score at lighter rainfall events compared to the COAMPS and WRF. For moderate and heavier thresholds, all models lacked forecast accuracy. The WRF accuracy in predicting precipitation was heavily dependent upon the performance of the selected cumulus parameterization scheme. Use of the Grell?CDevenyi and Bette?CMiller?CJanjic schemes helps suppress precipitation overprediction.     

Hydrometallurgical processing and recovery of molybdenum trioxide from spent catalyst

Hydrometallurgical processing of spent hydrodesulphurisation (HDS) catalyst for the recovery of molybdenum using sodium carbonate and hydrogen peroxide mixtures was investigated. The results indicated that the recovery of molybdenum was largely dependent on the concentrations of Na₂CO₃ and H₂O₂ in the reaction medium, which controls the acidity of the leach liquor and carry over of impurities such as Al, Ni, P, Si and V. Leaching process was exothermic and leaching efficiency of molybdenum decreased with increasing solid to liquid ratio. Large scale leaching of spent catalyst, under optimum conditions: 20% pulp density, 85 g/L Na₂CO₃, 10 vol.% H₂O₂ and 1 h reaction, resulted a leaching efficiency of 84% Mo. The obtained leach liquor contained (g/L): Mo — 22.0, Ni — 0.015 and Al — 0.82, P — 1.1, Si — 0.094 and minor quantities of V — 8 mg/L, As and Co — < 1 mg/L. Recovery of Mo from leach solution as MoO₃ of 97.30% purity was achieved by ammonium molybdate precipitation method.     

Photometric,spectral phase and temperature effects on 4 Vesta and HED meteorites: Implications for the Dawn mission

Phase angle and temperature are two important parameters that affect the photometric and spectral behavior of planetary surfaces in telescopic and spacecraft data. We have derived photometric and spectral phase functions for the Asteroid 4 Vesta, the first target of the Dawn mission, using ground-based telescopes operating at visible and near-infrared wavelengths (0.4–2.5 μm). Photometric lightcurve observations of Vesta were conducted on 15 nights at a phase angle range of 3.8–25.7° using duplicates of the seven narrowband Dawn Framing Camera filters (0.4–1.0 μm). Rotationally resolved visible (0.4–0.7 μm) and near-IR spectral observations (0.7–2.5 μm) were obtained on four nights over a similar phase angle range. Our Vesta photometric observations suggest the phase slope is between 0.019 and 0.029 mag/deg. The G parameter ranges from 0.22 to 0.37 consistent with previous results (e.g., Lagerkvist, C.-I., Magnusson, P., Williams, I.P., Buontempo, M.E., Argyle, R.W., Morrison, L.V. [1992]. Astron. Astrophys. Suppl. Ser. 94, 43–71; Piironen, J., Magnusson, P., Lagerkvist, C.-I., Williams, I.P., Buontempo, M.E., Morrison, L.V. [1997]. Astron. Astrophys. Suppl. Ser. 121, 489–497; Hasegawa, S. et al. [2009]. Lunar Planet. Sci. 40. ID 1503) within the uncertainty. We found that in the phase angle range of 0° < α ? 25° for every 10° increase in phase angle Vesta’s visible slope (0.5–0.7 μm) increases 20%, Band I and Band II depths increase 2.35% and 1.5% respectively, and the BAR value increase 0.30. Phase angle spectral measurements of the eucrite Moama in the lab show a decrease in Band I and Band II depths and BAR from the lowest phase angle 13° to 30°, followed by possible small increases up to 90°, and then a dramatic drop between 90° and 120° phase angle. Temperature-induced spectral effects shift the Band I and II centers of the pyroxene bands to longer wavelengths with increasing temperature. We have derived new correction equations using a temperature series (80–400 K) of HED meteorite spectra that will enable interpretation of telescopic and spacecraft spectral data using laboratory calibrations at room temperature (300 K).     

Characteristics of spectral aerosol optical depths over India during ICARB

Spectral aerosol optical depth (AOD) measurements, carried out regularly from a network of observatories spread over the Indian mainland and adjoining islands in the Bay of Bengal and Arabian Sea, are used to examine the spatio-temporal and spectral variations during the period of ICARB (March to May 2006). The AODs and the derived Ångström parameters showed considerable variations across India during the above period. While at the southern peninsular stations the AODs decreased towards May after a peak in April, in the north Indian regions they increased continuously from March to May. The Ångström coefficients suggested enhanced coarse mode loading in the north Indian regions, compared to southern India. Nevertheless, as months progressed from March to May, the dominance of coarse mode aerosols increased in the columnar aerosol size spectrum over the entire Indian mainland, maintaining the regional distinctiveness. Compared to the above, the island stations showed considerably low AODs, so too the northeastern station Dibrugarh, indicating the prevalence of cleaner environment. Long-range transport of aerosols from tshe adjoining regions leads to remarkable changes in the magnitude of the AODs and their wavelength dependencies during March to May. HYSPLIT back-trajectory analysis shows that enhanced long-range transport of aerosols, particularly from the west Asia and northwest coastal India, contributed significantly to the enhancement of AOD and in the flattening of the spectra over entire regions; if it is the peninsular regions and the island Minicoy are more impacted in April, the north Indian regions including the Indo Gangetic Plain get affected the most during May, with the AODs soaring as high as 1.0 at 500 nm. Over the islands, the Ångström exponent (α) remained significantly lower (～1) over the Arabian Sea compared to Bay of Bengal (BoB) (～1.4) as revealed by the data respectively from Minicoy and Port Blair. Occurrences of higher values of α, showing dominance of accumulation mode aerosols, over BoB are associated well with the advection, above the boundary layer, of fine particles from the east Asian region during March and April. The change in the airmass to marine in May results in a rapid decrease in α over the BoB.