Evaluation of coupled heat and moisture flow parameters in a bentonite-sand buffer material

Several series of one-dimensional tests were used to study the nature of transient heat and moisture movements in a clay buffer under different imposed temperature gradients. The measured temperature and moisture profiles were used to calculate the diffusion parameters governing heat and moisture movement in the buffer material. The experimentally determined diffusion parameters are shown to be dependent on the moisture content and temperature. The diffusion parameters were calculated by using an identification technique, the root-time method, and an analytical technique.     

IUE observations of HL CMa and the winds of cataclysmic variables

As evidenced by the P Cygni profiles of their ultraviolet resonance lines, cataclysmic variables—like early-type stars—are known to have extensive, high velocity winds. Assisted by AAVSO visual data andIUE ultraviolet spectra, we present an observational and theoretical study of the P Cygni profiles of the dwarf nova HL CMa. As these profiles are dependent upon the ionization structure of the wind, we describe a model of a radiatively-driven shocked wind for cataclysmic variables, and present results for the temperature and ionization structure of the outflowing gas.Paper presented at the IAU Colloquium No. 93 on Cataclysmic Variables. Recent Multi-Frequency Observations and Theoretical Developments, held at Dr. Remeis-Sternwarte Bamberg, F.R.G., 16–19 June, 1986.     

Nutrient flux in the Rhode River: Tidal exchange of nutrients by brackish marshes

Tidal exchanges of nitrogen, phosphorus, and organic carbon by a high and a low elevation marsh in the Rhode River estuary were measured throughout the year. Both marshes tended to import particulate matter and export dissolved matter, although they differed in the fluxes of certain nutrients. Compared with tidal exchanges, bulk precipitation was a major source of ammonia and nitrate and a minor source of other nutrients. There was a net retention of nutrients by the portion of the Rhode River that included both marshes and a mudflat. However, the marshes accounted for only 10% of the phosphorus retention and 1% of the nitrogen retention while they released organic carbon amounting to 20% of the retention. This suggests that the mudflat acted as a sink for nutrients. The primary role of the marshes seems to be transformation of particulate to dissolved nutrients rather than nutrient retention or release.     

Physical processes determining the chromospheric temperature distribution

Calculations performed with several models of the solar chromosphere support Ulmschneider's conclusion that relatively short period acoustic waves heat the low chromosphere in the region just above the temperature minimum. However, these same short period waves (10 period P80 s) are not able to maintain chromospheric temperatures at heights where _5000Å(normal) < 10^-6. The calculations also show that an earlier conjecture stating that the H₂ population might influence the non-LTE chromospheric H^- population is probably not correct, due to lower values of the ratio n _e/n _H inferred from more recent observations. Finally, the calculations support Athay's contention that the Cayrel mechanism alone cannot produce the observed temperature rise, because the magnitude of the radiative cooling in the lines is too great.     

Mariner 9: An instrument of dynamical science

We review and evaluate the contributions of Mariner 9 in improving our knowledge of the dynamical characteristics of Mars and its two satellites, Phobos and Deimos. Primary results include the discovery of the large gravitational and topographical bulge in the Tharsis region, the development of a detailed gravity model representable as coefficients in a spherical harmonic expansion, the development of a topographic model exhibiting a three kilometer displacement of the center of figure from the center of mass, and the determination of the size, shape and motion of Phobos and Deimos.     

Using GIS and statistics to study influences of geology on probability features of surface soil geochemistry in Northern Ireland

The probability features of non-normality and non-lognormality are widely observed in geochemistry due to the influences of multiple factors that are difficult to quantify and model. In Northern Ireland, the pseudo-total concentrations of 14 elements (Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, P, Pb and Zn) from 6138 topsoils were measured, and GIS mapping showed that the spatial distribution of these data were in line with the spatial distribution of geology in the area. Investigations into the influences of geology on the concentration data and their probability features were carried out using GIS and statistics in this study. The whole raw data sets for each element were positively skewed and none of them followed either normal or lognormal distributions. Logarithmic transformation was found to have “over-transformed” most of the data sets, changing their skewness from positive to negative values. When soil samples were classified by rock type using a GIS overlay function, obvious differences were observed in the chemical concentrations of soils derived from different rock types. Soils in basalt areas displayed the highest concentrations for most elements under study (Ca, Co, Cr, Cu, Fe, Mg, Mn, Na, Ni, P and Zn) but the lowest concentrations for K, while the highest levels for Cd and Pb occurred in the shale areas. Classifying soils by rock type produced more normally distributed data sets, especially for the igneous rock areas. To restrain the influence of soil type and land cover, samples from both gleys and pastures were extracted via a GIS and it was found the data sets then showed generally greater tendencies towards normality. However, many of the data sets would still not pass a test for normality unless the sample size was small (e.g. of the order of a couple of hundreds). Geology, soil type, land cover and sample size all played important roles in determining soil chemical concentrations and their probability features. However, the influences from other factors were still evident. Attempts made in this study show that it remains a challenging task in geochemistry to separate all the factors and to model their influence at the regional scale.     

Morphometric analysis and tectonic interpretation of digital terrain data: a case study

Tectonic movement along faults is often re?ected by characteristic geomorphological features such as linear valleys, ridgelines and slope‐breaks, steep slopes of uniform aspect, regional anisotropy and tilt of terrain. Analysis of digital elevation models, by means of numerical geomorphology, provides a means of recognizing fractures and characterizing the tectonics of an area in a quantitative way. The objective of this study is to investigate the use of numerical geomorphometric methods for tectonic geomorphology through a case study. The methodology is based on general geomorphometry. In this study, the basic geometric attributes (elevation, slope, aspect and curvatures) are complemented with the automatic extraction of ridge and valley lines and surface speci?c points. Evans' univariate and bivariate methodology of general geomorphometry is extended with texture (spatial) analysis methods, such as trend, autocorrelation, spectral, and network analysis. Terrain modelling is implemented with the integrated use of: (1) numerical differential geometry; (2) digital drainage network analysis; (3) digital image processing; and (4) statistical and geostatistical analysis. Application of digital drainage network analysis is emphasized. A simple shear model with principal displacement zone with an NE–SW orientation can account for most of the the morphotectonic features found in the basin by geological and digital tectonic geomorphology analyses. Copyright © 2003 John Wiley & Sons, Ltd.     

Apophyllite (001) surface alteration in aqueous solutions studied by HAFM

Depending on pH and temperature, two different types of surface reactions occur on the apophyllite (001) surface in aqueous HCl-solutions at temperatures from 20 to 130 °C. At low pH, laterally spreading hillocks cover the surface. The hillocks are softer than the pristine surface, chemical analysis shows a depletion in Ca + K, and the spreading velocity of hillocks depends on pH. This indicates a change in chemical bond strength, non-stoichiometric dissolution and a mechanism involving protons. External disturbances such as the AFM scanning tip cause the upper surface layers to peel off revealing that the active sites of hillock formation are between the silicate layers of apophyllite. The observed process can therefore be described by a penetrative ion-replacement reaction which proceeds well below the surface monolayer. By this ion-replacement, the silicate layers eventually become destabilised. The observed reaction, therefore, is equivalent to an incongruent dissolution process. Despite structural similarities, this process is only superficially similar to the ion-exchange occurring in clay minerals or zeolites. In these minerals, the structural backbone is not destabilized. At a more neutral pH and high temperatures, step retreat and etch pit formation can be observed on the apophyllite (001) surface thus indicating a more congruent dissolution mechanism.