Removal of Pyridine from Aqueous Solution by Adsorption on an Activated Carbon Cloth

Pyridine is a very toxic pollutant that has to be removed from wastewater. In this work, adsorption of pyridine on activated carbon cloth (ACC) is studied as a possible alternative for eliminating pyridine from aqueous solution. The ACC was produced from polyacrylonitrile. The adsorption equilibrium data of pyridine on ACC was obtained in a batch adsorber. The experimental data was interpreted with the isotherms of Langmuir, Freundlich, and Prausnitz‐Radke (PR), and the PR isotherm better represented the experimental data. The capacity of ACC for adsorbing pyridine was favored increasing the solution pH from 3 to 6, and this effect was due to the π–π dispersive and electrostatic interactions between the pyridine species in solution and the surface complexes of ACC. The modified Langmuir model fitted reasonably well the influence of pH on the adsorption capacity. In this model was assumed that both neutral pyridine and pyridinium were simultaneously adsorbed on ACC accordingly to the experimental results. The adsorption capacity was almost independent of temperature. The reversibility study revealed that 75% of the pyridine can be desorbed from ACC indicating that part of the pyridine was irreversibly adsorbed, and possibly chemisorbed.     

Interactive discovery of sequential patterns in time series of wind data

Wind speed and direction vary over space and time due to the interactions between different pressures and temperature gradients within the atmospheric layers. Near the earth’s surface, these interactions are modulated by topography and artificial structures. Hence, characterizing wind behaviour over large areas and long periods is a complex but essential task for various energy-related applications. In this study, we present a novel approach to discover wind patterns by integrating sequential pattern mining and interactive visualization techniques. The approach relies on the use of the Linear time Closed pattern Miner sequence algorithm in conjunction with a time sliding window that allows the discovery of all sequential patterns present in the data. These patterns are then visualized using integrated 2D and 3D coordinated multiple views and visually explored to gain insight into the characteristics of the wind from a spatial, temporal and attribute (type of wind pattern) point of view. This proposed approach is used to analyse 10 years of hourly wind speed and direction data for 29 weather stations in the Netherlands. The results show that there are 15 main sequential patterns in the data. The spatial task shows that weather stations located in the same region do not necessarily experience similar wind pattern. For within the selected time interval, similar wind patterns can be observed in different stations and in the same station at different times of occurrence. The attribute task discovered that the repetitive occurrences of chosen pattern indicate as regular wind behaviour at different weather stations that persisted continuously over time. The results of these tasks show that the proposed interactive discovery facilitates the understanding of wind dynamics in space and time.     

An aromatase inhibitor and tamoxifen decrease plasma levels of o,p'-DDT and its metabolites in Nile tilapia (Oreochromis niloticus)

The objective of this study was to determine if tamoxifen or an aromatase inhibitor (4-hydroxyandrostenedione; 4-OHA) affected plasma concentrations of o,p' -DDT and its metabolites, o,p'-DDD and o,p'-DDE, in mature tilapia. Male and female tilapia were injected 6 times intraperitoneally with o,p'-DDT (40 mg/kg) alone or in combination with 4-OHA (2 mg/kg) over a 12 day period. An additional group of male fish was injected with tamoxifen (5 mg/kg) plus o,p'-DDT. At the end of the treatment period, plasma samples were extracted and analyzed by GC/ECD. Females injected only with o,p'-DDT had significantly higher levels of o,p'-DDT compared with males. Interestingly, females and males treated concomitantly with o,p'-DDT and 4-OHA or tamoxifen had significantly lower concentrations of plasma o,p'-DDT (about 50%) compared with fish treated with only o,p'-DDT. These initial results suggest that an interaction between endocrine-active compounds occurs in vivo in tilapia and may involve alterations in metabolism of o,p'-DDT.     

Effects of wave–current interaction on the current profile

Wave–current laboratory experiments have shown that the logarithmic current profile observed in pure current flows is modified due to the presence of waves. When waves propagate opposite the current, an increase in the current intensity is achieved near the mean water level, while a reduction is obtained for following waves and currents. With the aim of analyzing these nonlinear effects along the whole water column, an Eulerian wave–current model is presented. In contrast to previously presented wave–current models, the present is able to include the variation of the free surface elevation due to the wave motion and the effect of a non hydrostatic pressure field. Therefore it does not restrict its application to waves in shallow waters. Moreover, the model is able to simulate all the possible angles between waves and currents.     

Location of Moderate-Sized Earthquakes Recorded by the NARS�CBaja Array in the Gulf of California Region Between 2002 and 2006

We relocated the hypocentral coordinates of small to moderate-sized earthquakes reported by the National Earthquake Information Center (NEIC) between April 2002 and August 2006 in the Gulf of California region and recorded by the broadband stations of the network of autonomously recording seismographs (NARS?CBaja array). The NARS?CBaja array consists of 19 stations installed in the Baja California peninsula, Sonora and Sinaloa, Mexico. The events reported by the preliminary determinations of epicenters (PDE) catalog within the period of interest have moment magnitudes (M _w) ranging between 1.1 and 6.7. We estimated the hypocentral location of these events using P and S wave arrivals recorded by the regional broadband stations of the NARS?CBaja and the RESBAN (Red Sismológica de Banda Ancha) arrays and using a standard location procedure with the HYPOCENTER code (Lienert and Havskov in Seism Res Lett 66:26?C36, 1995) as a preliminary step. To refine the location of the initial hypocenters, we used the shrinking box source-specific station term method of Lin and Shearer (J Geophys Res 110, B04304, 2005). We found that most of the seismicity is distributed in the NW?CSE direction along the axis of the Gulf of California, following a linear trend that, from north to south, steps southward near the main basins (Wagner, Delfin, Guaymas, Carmen, Farallon, Pescadero and Alarcon) and spreading centers. We compared the epicentral locations reported in the PDE with the locations obtained using regional arrival times, and we found that earthquakes with magnitudes in the range 3.2?C5.0?mb differ on the average by as much as 43?km. For the M _w magnitude range between 5 and 6.7 the discrepancy is less, differing on the average by about 25?km. We found that the relocated epicenters correlate well with the main bathymetric features of the Gulf.     

Brazilian health regions and scales: A geographical perspective

Abstract:  This paper offers a geographical perspective on the way in which health regions have been defined and established in São Paulo as part of overall Brazilian health policy. To accomplish this, I first situate the Brazilian case in the international debate over the regionalization of health services. Second, I examine health regionalization in the case of São Paulo and show how the process is dynamic and complex, involving geographical scales that go well beyond the administrative boundaries of Brazilian municipalities.     

Origin of biotite-apatite-rich enclaves, Achala batholith, Argentina

The Achala batholith of Argentina contains very unusual layered enclaves containing up to 30% apatite and 50% biotite in some layers. This modal mineralogy produces bulk-rock compositions that cannot represent liquids, having as little as 29% SiO₂ and up to 8% P₂O₅. Nor can the enclaves represent metasedimentary xenoliths because: (1) none of the Precambrian wall rocks has these compositions; (2) none of the metasedimentary xenoliths present within the batholith shows any degree of transition to the mica-apatite-rich enclaves; (3) the compositions and textures in the enclaves are inconsistent with metasediments; (4) a geochronological study of zircon from an enclave gives an age of 368 ± 2 Ma, the exact age of zircons in the granitic host rocks. For these reasons, we conclude that the enclaves are neither xenoliths of Precambrian wall rocks nor restite of a Precambrian source. The identical age of the enclave and the host granites, coupled with textural, mineralogical, and bulk-rock characteristics of the enclaves, indicates that the enclaves are magmatic segregations, i.e., cumulates. The F-rich nature of the stubby-shaped apatites and biotites indicates a high F content of the magma parental to the enclaves. We infer that the viscosity of the melt was lowered sufficiently to allow cumulates to form in spite of the granitic composition of the melt. Received: 12 December 1996 / Accepted: 11 August 1997