Medium-term responses of rocky bottoms to sewage discharges from a deepwater outfall in the NE Atlantic

An investigation on the effects of deepwater outfall discharges on the status of rocky reef communities was carried out. The sanitation system was found to be an environmentally suitable option for the protection of those habitats situated in high energy coastal environments. Sediments occurring between the predominating rocky substrates showed low values of the fine fraction (<63microm) and organic matter content. In addition, high average concentrations of Cd, Hg and Zn were found in these sediments, though these values were similar to those registered in non-affected sites, far away from the outfall. On the other hand, those assemblages typical of hard substrates that settled near the outfall showed an increase in total richness and abundance of macroinvertebrates. Moreover, the average number of species of each taxonomic group, a good indicator of the maintenance of the previous trophic structure, only varied considerably over time at the rip-rap protection. In a global context, those changes were not directly related to the discharge disturbances, but to the natural variability or the successional processes occurring within those communities. Only communities dwelling in the rip-rap protection area were affected by the proximity of the discharges.     

Exotic ion H 3 ++ in strong magnetic fields

1. The exotic system H ₃ ⁺⁺ (which does not exist without magnetic field) exists in strong magnetic fields:
   1. In triangular configuration for B≈10⁸–10¹¹?G (under specific external conditions)
   2. In linear configuration for B>10¹⁰?G
2. In the linear configuration the positive z-parity states 1σ _g , 1π _u , 1δ _g are bound states
3. In the linear configuration the negative z-parity states 1σ _u , 1π _g , 1δ _u are repulsive states
4. The H ₃ ⁺⁺ molecular ion is the most bound one-electron system made from protons at B>3×10¹³?G

Possible application: The H ₃ ⁺⁺ molecular ion may appear as a component of a neutron star atmosphere under a strong surface magnetic field B=10¹²–10¹³?G.     

Eustatic and tectonic controls on Quaternary Ras Leona marine terraces (Strait of Gibraltar, northern Morocco)

Well-preserved Quaternary staircased marine terraces appear on Ras Leona limestone relief. This is a peculiar sector of the Betic-Rif Cordillera, lying in the four-way junction between the Atlantic and the Mediterranean, and Europe and Africa. The age and altitude correlation of the Ras Leona terraces with travertine-covered lateral equivalent terraces fashioned in the neighbouring Beni Younech area, and comparison with those along the Moroccan Atlantic coasts, would suggest that the Ras Leona terraces were mainly formed by eustatic factors. The importance of the eustasy is supported by further comparisons with Spanish and Moroccan Mediterranean terraces and with different marine terraces developed on passive-margin coasts around the world. A tectonic event occurred mainly during the period between the formation of the Maarifian and the Ouljian terraces (i.e., between 370 and 150 ka). The moderate Quaternary tectonic uplift deduced from the marine terraces and its comparison with uplifted marine terraces developed in active subduction setting disagrees with the model of an active eastwards subduction below the Gibraltar tectonic arc.     

Thick sections of layered ultramafic cumulates in the Oman ophiolite revealed by an airborne hyperspectral survey: Petrogenesis and relationship to mantle diapirism

Using the HyMap instrument, we have acquired visible and near infrared hyperspectral data over the Maqsad area of the Oman ophiolite (~ 15 × 60 km). This survey allowed us to identify and map the distribution of clinopyroxene-rich cumulates (inter-layered clinopyroxenites and wehrlites) whose occurrence was previously undocumented in this area. The cumulates reach several hundred meters in thickness and crop out at distances exceeding 15 km on both sides of the Maqsad former spreading centre. They occur either in mantle harzburgites, as km-sized layered intrusions surrounded by fields of pegmatitic dykes consisting of orthopyroxene-rich pyroxenite and gabbronorites, or at the base of the crustal section where they are conformably overlain by cumulate gabbros. These ultramafic cumulates crystallized from silica- and Mg-rich melts derived from a refractory mantle source (e.g. high Cr#, low [Al₂O₃], low [TiO₂]). These melts are close to high-Ca boninites, although, strictly speaking, not perfect equivalents of present-day, supra-subduction zone, boninites. Chemical stratigraphy reveals cycles of replenishment, mixing and fractional crystallization from primitive (high Mg#) melts, typical of open magma chambers and migration of inter-cumulus melts. The TiO₂ content of clinopyroxene is always low (≤ 0.2 wt.%) but quite variable compared to the associated pegmatites that are all derived from a source ultra-depleted in high field strength elements (HFSE). This variability is not caused by fractional crystallization alone, and is best explained by hybridization between the ultra-depleted melts (parent melts of the pegmatites) and the less depleted mid-ocean ridge basalts (MORB) parent of the dunitic–troctolitic–gabbroic cumulates making up the crustal section above the Maqsad diapir.We propose that, following a period of magma-starved spreading, the Maqsad mantle diapir, impregnated with tholeiitic melts of MORB affinity, reached shallow depths beneath the ocean ridge. This diapir induced melting of the formerly accreted and hydrothermally altered lithosphere. At this stage, these boninitic-like lithospheric melts crystallized as pegmatitic dykes. As the diapir continued to rise, the amount of MORB reaching shallow depths increased, together with the surrounding temperature, leading to the formation of magma chambers where the crystallization of layered cumulates became possible. These cumulates remained rich in pyroxene and devoid of plagioclase as long as the contribution of MORB-derived melts was moderate relative to the lithospheric-derived melts. As the contribution of MORB to the refilling of the magma chamber increased, gabbroic cumulates started to crystallize.     

Rhizosphere and flooding regime as key factors for the mobilisation of arsenic and potentially harmful metals in basic,mining-polluted salt marsh soils

The occurrence of mining areas in the vicinities of salt marshes may affect their ecological functions and facilitate the transfer of pollutants into the food chain. The mobilisation of metals in salt marsh soils is controlled by abiotic (pH, redox potential) and biotic (influence of rhizosphere) factors. The effect of the rhizosphere of two plant species (Sarcocornia fruticosa and Phragmites australis) and different flooding regimes on potentially harmful metals and As mobilisation from salt marsh soil polluted by mining activities were investigated (total concentrations: 536 mg kg⁻¹ As, 37 mg kg⁻¹ Cd, 6746 mg kg⁻¹ Pb, 15,320 mg kg⁻¹ Zn). The results show that the changes in redox conditions (from 300 mV to −100 mV) and pH after flooding and rewetting periods may mobilise the contaminant elements into soil solution (e.g., 100 μg L⁻¹ Cd, 30 μg L⁻¹ Pb, 7 mg L⁻¹ Zn), where they are available for plants or may be leached from the soil. Drying periods generated peaks of concentrations in the soil solution (up to 120 μg L⁻¹ Cd and 50 μg L⁻¹ Pb). The risk assessment of As and metal-polluted salt marshes should take into account flood dynamics in order to prevent metal(loid) mobilisation.     

A combined hydrologic and hydraulic modeling approach for testing efficiency of structural flood control measures

The necessity of estimating the degree and spatial extent of positive impacts with regard to protecting communities and properties through potential flood control projects can be considered one of the main reasons for performing flood modeling. This paper presents an overall systematic approach based on the simulation of some extreme event conditions, using a hydrological model to generate the resulting river flows and then using a hydraulic modeling exercise to decide upon floodplain evolution in the case-study area, Bostanli river basin, which has been under the threat of flooding for many years. The potential serviceability of the planned Bostanli Dam in the study area was examined by using the HEC-HMS and HEC-RAS modeling tools, both integrated with GIS functions for spatial operations. The results indicate that the dam construction as planned would have a somewhat positive impact as a potential flood control measure, since it seems to decrease the flood peaks of 68.9 and 158.7 m³/s (that would potentially be generated by 100- and 500-year storm events under current conditions) to 65.5 and 150.7 m³/s (when the dam is in operation), respectively. However, this seems to contribute little to the overall flood mitigation performance in the basin.     

Geotechnical Characterization by In situ and Lab Tests to the Back-Analysis of a Supported Excavation in Metro do Porto

This paper summarizes the geotechnical characterization conducted for the design and subsequent analysis of a strutted excavation in “Metro do Porto”. This region is geologically dominated by heterogeneous weathered granite masses with deep residual soil profiles. Local saprolitic soils exhibit, by their nature, a particular behavior characterized by very sensitive and weak relic micro-structures, due to their specific genesis. This study has included the interpretation of a significant volume of in situ test results, triaxial tests over undisturbed samples and monitoring data, giving rise to specific correlations between testing and design parameters. Real time monitoring enabled a back-analysis by FEM of a well instrumented section of the strutted excavation, which was calibrated taking into account the derived correlations and the deformability behavior of this specific geotechnical ambient. This geomaterial, although revealing very high initial stiffness values (for very small strain ranges) has shown low stiffness values for “medium to high” strain levels, reflecting a singular strong non-linearity in the stress-strain behavior.