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141.
Some of the factors that affect the preferred positions of cations in ionic-solid solutions were investigated utilizing vibrational spectroscopy. Solid solutions of the sulfate and chromate ions codoped with La3+ and Ca2+ in a KBr host lattice were examined as a function of the polyvalent-cation concentration. The cation—anion pairing process was found to be random for Ca2+ whereas the formation of La3+SO42? ion-pairs with a C2v bonding geometry is highly preferential to any type of La3+CrO42? ion-pair formation. The relative populations of ion-pair site configurations are discussed in terms of an energy—entropy competition which can be applied to the partition of trace elements during magmatic processes.  相似文献   
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A technique, referred to as SARTopo, has been developed for obtaining surface height estimates with 10 km horizontal resolution and 75 m vertical resolution of the surface of Titan along each Cassini Synthetic Aperture Radar (SAR) swath. We describe the technique and present maps of the co-located data sets. A global map and regional maps of Xanadu and the northern hemisphere hydrocarbon lakes district are included in the results. A strength of the technique is that it provides topographic information co-located with SAR imagery. Having a topographic context vastly improves the interpretability of the SAR imagery and is essential for understanding Titan.SARTopo is capable of estimating surface heights for most of the SAR-imaged surface of Titan. Currently nearly 30% of the surface is within 100 km of a SARTopo height profile. Other competing techniques provide orders of magnitude less coverage.We validate the SARTopo technique through comparison with known geomorphological features such as mountain ranges and craters, and by comparison with co-located nadir altimetry, including a 3000 km strip that had been observed by SAR a month earlier. In this area, the SARTopo and nadir altimetry data sets are co-located tightly (within 5-10 km for one 500 km section), have similar resolution, and as expected agree closely in surface height. Furthermore the region contains prominent high spatial resolution topography, so it provides an excellent test of the resolution and precision of both techniques.  相似文献   
147.
We examine the chemical and dynamical structure in the solar neighbourhood of a model Galaxy that is the endpoint of a simulation of the chemical evolution of the Milky Way in the presence of radial mixing of stars and gas. Although the simulation's star formation rate declines monotonically from its unique peak and no merger or tidal event ever takes place, the model replicates all known properties of a thick disc, as well as matching special features of the local stellar population such as a metal-poor extension of the thin disc that has high rotational velocity. We divide the disc by chemistry and relate this dissection to observationally more convenient kinematic selection criteria. We conclude that the observed chemistry of the Galactic disc does not provide convincing evidence for a violent origin of the thick disc, as has been widely claimed.  相似文献   
148.
Some 20% of Titan’s surface is covered in large linear dunes that resemble in morphology, size and spacing (1-3 km) those seen on Earth. Although gravity, atmospheric density and sand composition are very different on these two worlds, this coincident size scale suggests that the controlling parameter limiting the growth of giant dunes, namely the boundary layer thickness (Andreotti et al., 2009). Nature, 457, 1120-1123], is similar. We show that a ∼3 km boundary layer thickness is supported by Huygens descent data and is consistent with results from Global Circulation Models taking the distinctive thermal inertia and albedo of the dune sands into account. While the boundary layer thickness on Earth controlling dunes can vary by an order of magnitude depending on the proximity of oceans, which have very different thermal properties from dry land, the relative invariance of dune spacing on Titan is consistent with relatively uniform thermal properties near the dunes and no prominent variation with latitude is seen.  相似文献   
149.
Motivated by radar and near-infrared data indicating that Titan’s polar lakes are extremely smooth, we consider the conditions under which a lake surface will be ruffled by wind to form capillary waves. We evaluate laboratory data on wind generation and derive, without scaling for surface tension effects, a threshold for pure methane/ethane of ∼0.5-1 m/s. However, we compute the physical properties of predicted Titan lake compositions using the National Institute for Standards Technology (NIST) code and note that dissolved amounts of C3 and C4 compounds are likely to make Titan lakes much more viscous than pure ethane or methane, even without allowing for suspended particulates which would increase the viscosity further. Wind tunnel experiments show a strong dependence of capillary wave growth on liquid viscosity, and this effect may explain the apparent absence so far of waves, contrary to prior expectations that generation of gravity waves by wind should be easy on Titan. On the other hand, we note that winds over Titan lakes predicted with the TitanWRF Global Circulation Model indicate radar observations so far have in any case been when winds have been low (∼0.5-0.7 m/s), possibly below the wave generation threshold, while peak winds during summer may reach 1-2 m/s. Thus observations of Titan’s northern lakes during the coming years by the Cassini Solstice mission offer the highest probability of observing wind-roughening of lake surfaces, while observations of Ontario Lacus in the south will likely continue to show it to be flat and smooth.  相似文献   
150.
The Huygens probe landed on the then unknown surface of Titan in January 2005. A small, protruding penetrometer, part of the Surface Science Package (SSP), was pushed into the surface material measuring the mechanical resistance of the ground as the probe impacted the landing site. We present laboratory penetrometry into room temperature surface analogue materials using a replica penetrometer to investigate further the nature of Titan’s surface and examine the sensor’s capabilities. The results are then compared to the flight instrument’s signature and suggest the Titan surface substrate material consists of sand-sized particles with a mean grain size ~2 mm. A possible thin 7 mm coating with mechanical properties similar to terrestrial snow may overlie this substrate, although due to the limited data we are unable to detect any further layering or grading within the near-surface material. The unusual weakening with depth of the signature returned from Titan has, to date, only been reproduced using a damp sand target that becomes progressively wetter with depth, and supports the suggestion that the surface may consist of a damp and cohesive material with interstitial liquid contained between its grains. Comparison with terrestrial analogues highlights the unusual nature of the landing site material.  相似文献   
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