Hydrogeochemical processes controlling fluoride enrichment within alluvial and hard rock aquifers in a part of a semi-arid region of Northern India

Rock–water interaction along with mineral dissolution/ precipitation plays a profound role in the control of fluoride ion concentration within the alluvial groundwater in a part of semi-arid northern India. In the premonsoon season, the alluvial region experiences evaporative processes leading to increase in Na⁺ ions which through reverse ion exchange processes are adsorbed onto suitable sites within the aquifer matrix in exchange for Ca²⁺ ion in solution. Increase in Ca²⁺ ions in solution inhibits fluorite mineral dissolution, thereby controlling premonsoon fluoride ion concentration within alluvial groundwaters (1.40?±?0.5 mg/l). In the postmonsoon season, however, higher average fluoride ion concentration within the alluvial aquifer samples (2.33?±?0.80 mg/l) is observed mainly due to increase in silicate weathering of fluoride-bearing rocks and direct ion exchange processes enabling Ca²⁺ ion uptake from solution accompanied with the release of fluoride ions. Combined effect of these processes results in average fluoride ion concentration falling above the WHO drinking water permissible limit (1.5 mg/l). Alternatively, the hard rock aquifer samples within the study area have an average fluoride ion concentration falling below the permissible limit in both the seasons.     

Application of cubic spline in soil erosion modeling from Narmada Watersheds,India

Soil erosion by water is ubiquitous, exhibits spatio-temporal variability, and is fundamental to determining sediment yield which is key to proper watershed management. In this study, we propose a relationship between the curve number and sediment yield index (SYI) using cubic splines. Using field data from four watersheds, the relation between observed and computed SYI is found to have a coefficient of determination (R²) value from 0.63 to 0.88 suggesting that such a relation can be used to determine SYI from the available CN value. It is found that cubic splines perform satisfactorily with Nash-Sutcliff efficiency ranging from 60.18 to 64.01%, absolute prediction error from 1.35 to 5.56%, integral square error from 1.21 to 5.82%, coefficient of correlation from 79.32 to 93.78%, and degree of agreement from 0.87 to 0.99%.     

Mapping of hydrothermally altered zones in Aravalli Supergroup of rocks around Dungarpur and Udaipur,India, using Landsat-8 OLI and spectroscopy

We explored the utilization of Landsat-8 Operational Land Imager (OLI) data for mapping of hydrothermal alteration zones. The region in and around the cities of Dungarpur and Udaipur of Rajasthan state in India was selected for this study. The rock types of Dungarpur and Udaipur are serpentinites, talc-carbonate, talc-schist, and quartzite of the Aravalli Supergroup. Hydrothermally altered zones and resultant hydrous minerals play an important role in the genesis of these rocks. We aimed to identify possible locations of hydrothermally altered zones in regional context around Dungarpur and Udaipur using Landsat-8 OLI data. False-color composite maps and band ratios were prepared from Landsat-8 bands. Band ratios such as band 6/band 7 (short-wave infrared 1 (SWIR1)/short wave infrared 2 (SWIR2)), band 4/band 3 (red/green), and band 5/band 6 (near infrared (NIR)/SWIR1) and visual interpretation techniques were used to identify the hydrothermally altered zones. Spectroscopic analyses of field rock samples were done to validate the hydrothermal alteration zones delineated from the analysis of Landsat-8 data. We present the combined results of Landsat-8 and field spectroradiometer analysis which brings out the hydrothermal alteration zones associated with hydrous minerals (antigorite, lizardite, montmorillonite, vermiculite, talc, and saponite). The study demonstrates the utility Landsat-8 OLI (with field spectroradiometer data) in the mapping of hydrothermally altered zones as a key in understanding geological processes.     

Fluoride contamination of groundwater and its seasonal variability in parts of Purulia district,West Bengal,India

The contamination of aquifers by fluoride and arsenic is a major cause of concern in several parts of India. A study has thus been conducted to evaluate the extent and severity of fluoride contamination and also its seasonal variability. Two blocks (Purulia-1 and Purulia-2) were considered for this purpose. Twenty groundwater samples (in each season) were collected from tube wells during the pre-monsoon and post-monsoon seasons. In addition to fluoride, groundwater samples were also analyzed for major cations, anions, and other trace elements. The concentration of fluoride shows significant seasonal variation and ranges between 0.94–2.52 and 0.25–1.43 mg/l during the pre-monsoon and post-monsoon seasons, respectively. In pre-monsoon season, more than 40% of the water samples show fluoride concentrations higher than the WHO limit. However, during the post-monsoon season, none of the groundwater sample shows fluoride concentrations higher than the WHO limit. Lesser concentration during the post-monsoon season is attributed to the dilution effect by the percolating rainwater, which has also been reflected in the form of a decrease in concentrations of other elements. The petrographic studies of the rock samples collected from the study area show that the rocks are mainly composed of plagioclase, orthoclase, and quartz with abundant biotite. The weathering and dissolution of biotite plays an important role in controlling the fluoride concentrations in the groundwater of the study area.     

Structurally-controlled melt accumulation: Himalayan migmatites and related deformation — Dhauli Ganga valley, Garhwal Himalaya

In the uppermost parts of the Higher Himalayan Crystallines (HHC) of the Great Himalaya, widespread in situ partial melting of sillimanite+K-feldspar gneiss resulted in the formation of migmatite and resultant melt accumulation near the South Tibetan Detachment System (STDS) during various deformation events along the Dhauli Ganga valley in Garhwal. The oldest migmatite phase, designated as the Me1, parallels the main foliation S_m as the stromatite layers and concordant leucogranite bands. Younger melt phases Me2, Me3 and Me5 are recorded along small-scale ductile thrusts, extensional fabric and structureless patches, respectively. It is only the Me4 melting phase that is evidenced by large-scale melt migration along cross-cutting irregular veins. These were possible conduits for migration and accumulation of melt into larger leucogranite bodies like the Malari granite (19.0± 0.5 Ma).     

Proterozoic crustal scale shearing in the Bundelkhand massif with special reference to quartz reefs

Quartz reefs that constitute the most spectacular feature of the Bundelkhand massif of Central India are as yet riddled with controversy. We consider the NE-SW trending quartz reefs and the NE-SW trending brittle-ductile shear system developed outside the quartz reefs to constitute a single tectonic fabric of the massif. The study of structural features of the quartz reefs and the associated NE-SW trending shear zones coupled with the mineralogical and structural features suggests that the quartz reefs represent strike-slip dominated vertical to subvertical shear zones with dominantly sinistral sense of shear. The loci of the quartz reefs constitute the large scale fractures developed as a consequence of extensional processes in this part of Central India. These fractures were the sites for later emplacement of siliceous magmatic melt, commonly known as quartz reef that was also responsible for the mineralization of some base metals as well as pyrophyllite and diaspore. The lithotectonic system of these quartz reefs thus developed was later on subjected to strike-slip movements. A generalized model of large scale extensional tectonics during the Proterozoic times has thus been suggested for the development of the NE-SW tectonic fabric of the Bundelkhand massif.     

Juxtaposition of India and Antarctica During the Precambrian: Inferences from Geochemistry of Mafic Dykes

There are several geological, geochemical and geophysical evidences, which corroborate reconstruction of Gondwanaland and juxtaposition of India and Antarctica. Petrology of the Precambrian mafic dykes of East Antarctica and Central-East India also support juxtaposition of India and Antarctica. Mafic dykes of different generations are emplaced in the Archaean granite gneisses of these regions. These dykes appear to be an important tool to support juxtaposition of India and Antarctica. Geological and petrological data of the Central-East India Precambrian mafic dykes suggest four episodes of mafic magmatism in the region - three tholeiitic and one noritic (?). Similarly, East Antarctica also comprises four dyke suites, emplaced during three distinct periods. These suites are 2.4 Ga meta-tholeiites, 2.4 Ga high-Mg tholeiites, 1.8 Ga dolerites and 1.2–1.4 Ga dolerites. Geochemical compositions of these mafic dykes are compared and they show good relationships with each other. Similarities in petrological and geochemical characteristics of Precambrian mafic dykes of East Antarctica and Central-East India strongly support juxtaposition of these two continents.