Ionic conductivity in gem-quality single-crystal alkali feldspar from the Eifel: temperature,orientation and composition dependence

We measured the ion conductivity of single-crystal alkali feldspar originating from two different locations in the Eifel/Germany, named Volkesfeld and Rockeskyller sanidine and having potassium site fractions \(C_\mathrm{K}\) of 0.83 and 0.71, respectively. The dc conductivities resulting from electrochemical impedance spectroscopy over the temperature range of 300–900 \(^{\circ }\hbox {C}\) show a weak composition dependence but pronounced differences between the b-direction [\(\perp (010)\)] and \(c^{*}\)-direction [\(\perp (001)\)] of the monoclinic feldspar structure. Conductivity activation energies obtained from the observed linear Arrhenius plots are close to 1.2 eV in all cases, which is closely similar to the activation energies of the \(^{22}\mathrm{Na}\) tracer diffusivity in the same crystals. Taking into account literature data on K tracer diffusion and diffusion correlation effects, the present results point to a predominance of the interstitialcy mechanism over the vacancy mechanism in mass and charge transport on the alkali sublattice in potassium-rich alkali feldspar.     

Dynamic features in the western Baltic Sea investigated using NOAA-AVHRR data

Summary The western part of the Baltic Sea is a shallow transition area which is characterized by the water exchange between the Baltic and the North Sea. The dynamic processes in this area are forced by sea-level differences between the North Sea and Baltic Sea as well as by local wind and freshwater input. The response patterns are modified by Earth's rotation, bathymetric structures and the alignment of the coast. Series of satellite images permit synoptical views of these pattern and their temporal and spatial development.Sea surface temperature maps derived from infrared data supplied by the National Oceanic and Atmospheric Administration (NOAA) satellite-borne Advanced Very High Resolution Radiometer (AVHRR) are used to show various features like upwelling filaments and eddies.The River Oder discharges into the Pomeranian Bight is the main source of freshwater input into the western Baltic. The variability of this inflow and of the affected coastal seas is being presented in relation to the prevailing meteorological conditions.

---

Dynamische Besonderheiten in der westlichen Ostsee untersucht anhand von NOAA-AVHRR-Daten

Zusammenfassung Die westliche Ostsee ist ein flaches Übergangsgebiet, das durch den Wasseraustausch zwischen Nord- und Ostsee charakterisiert ist. Die dynamischen Prozesse werden in diesem Gebiet durch Wasserstandsdifferenzen zwischen Nord- und Ostsee, durch den lokalen Wind und die Süßwasserzufuhr getrieben. Die Reaktionsmuster werden modifiziert durch die Erdrotation, die Bathymetrie und den Küstenverlauf.Serien von Satellitendaten gestatten die synoptische Betrachtung dieser Muster und ihrer zeitlichen und räumlichen Entwicklung.Karten der Wasseroberflächentemperatur (SST), abgeleitet aus Infrarotdaten des Advanced Very High Resolution Radiometer (AVHRR), werden genutzt, um verschiedene Strukturen wie Auftrieb, Filamente und Wirbel zu präsentieren. Das Radiometer wird durch die National Oceanic and Atmospheric Administration (NOAA) auf Wettersatelliten betrieben.Der Flußeintrag der Oder in die Pommersche Bucht ist die bedeutendste Süßwasserzufuhr in die westliche Ostsee. Die Veränderlichkeit des Einstroms und die beeinflußten Gebiete sind in Abhängigkeit von den meteorologischen Bedingungen dargestellt.

---

Recherche du caractéristiques dynamiques en mer Baltique ouest á l'aide de données NOAA-AVHRR

Résumé La partie ouest de la mer Baltique est une zone de transition de profondeur réduite, caractérisée par un échange des eaux entre la mer du Nord et la mer Baltique.Dans cette zone, les processus dynamiques proviennent des différences de niveau de la mer du Nord et de la mer Baltique, des vents locaux et de l'apport en eau douce. Les modèles créés sont modifiés à partir de la rotation terrestre, de la bathymétrie et de la morphologie côtière.Les données satellite permettent d'établir une étude synoptique de ces processus dans l'ensemble de la zone ainsi que leur développement spatio-temporel au moyen de séries.Des cartes de température superficielle (SST) obtenues à partir des données radiométriques infrarouges AVHRR (Advanced Very High Resolution Radiometer) sont utilisées pour présenter des exemples SST caractéristiques de résultats de processus dynamiques de l'ouest de la mer Baltique. Les données radiométriques proviennent du National Oceanic and Atmospheric Administration (NOAA) à partir de satellites météorologiques.La dépendance des développements spatio-temporels de modèles en fonction des conditions météorologiques est discutée à partir de scènes et de séries particulières.Des exemples d'upwelling devant les côtes allemandes, suédoises et polonaises ainsi que des fronts, des filaments et des tourbillons sont présentés.La plus grande partie de l'apport en eau douce à l'ouest de la mer Baltique provient du fleuve Oder, en baie de Poméranie. L'influence des facteurs météorologiques sur la variation de ce déversement et sur les zones influencées est présentée.

     

Dynamics of coastline changes in Mexico

Journal of Geographical Sciences - The goal of our work was to locate and quantify changes that occurred in 66% of the Mexican coastline, based on four land cover maps generated by the Mexican...     

It starts at home? Climate policies targeting household consumption and behavioral decisions are key to low-carbon futures

Through their consumption behavior, households are responsible for 72% of global greenhouse gas emissions. Thus, they are key actors in reaching the 1.5 °C goal under the Paris Agreement. However, the possible contribution and position of households in climate policies is neither well understood, nor do households receive sufficiently high priority in current climate policy strategies. This paper investigates how behavioral change can achieve a substantial reduction in greenhouse gas emissions in European high-income countries. It uses theoretical thinking and some core results from the HOPE research project, which investigated household preferences for reducing emissions in four European cities in France, Germany, Norway and Sweden. The paper makes five major points: First, car and plane mobility, meat and dairy consumption, as well as heating are the most dominant components of household footprints. Second, household living situations (demographics, size of home) greatly influence the household potential to reduce their footprint, even more than country or city location. Third, household decisions can be sequential and temporally dynamic, shifting through different phases such as childhood, adulthood, and illness. Fourth, short term voluntary efforts will not be sufficient by themselves to reach the drastic reductions needed to achieve the 1.5 °C goal; instead, households need a regulatory framework supporting their behavioral changes. Fifth, there is a mismatch between the roles and responsibilities conveyed by current climate policies and household perceptions of responsibility. We then conclude with further recommendations for research and policy.     

Are C1 chondrites chemically fractionated? a trace element study

Six C1 chondrite samples and a C2 xenolith from the Plainview H5 chondrite were analyzed by radiochemical neutron activation for the elements Ag, Au, Bi, Br, Cd, Ce, Cs, Eu, Ge, In, Ir, Lu, Nd, Ni, Os, Pd, Pt, Rb, Re, Sb, Se, Sn, Tb, Te, Tl, Yb, and Zn. The data were combined with 9 earlier analyses from this laboratory and examined for evidence of chemical fractionation in C1 chondrites.A number of elements (Br, Rb, Cs, Au, Re, Os, Ni, Pd, Sb, Bi, In, Te) show small but correlated variations. Those of the first 8 probably reflect hydrothermal alteration in the meteorite parent body, whereas those of Sb, Bi, In, and Te may at least in part involve nebular processes. Br and Au show systematic abundance differences from meteorite to meteorite, which suggests hydrothermal transport on a kilometer scale. The remaining elements vary from sample to sample, suggesting transport on a centimeter scale.There is no conclusive evidence for nebular fractionation affecting C1 's. Though C1 chondrites have lower $\text{Zr}\text{Hf}$ and $\text{Ir}\text{Re}$ ratios than do other chondrite classes, these ratios vary in other classes, suggesting that those classes rather than C1's are fractionated. Three fractionation-prone REE—Ce, Eu, and Yb have essentially the same relative abundances in C1's and all other chondrite classes, and hence apparently are not fractionated in C1's. We did not confirm the large Tb and Yb variations in C1's reported by other workers.We present revised mean C1 abundances for 35 elements, based on the new data and a critical selection of literature data. Changes are generally less than 10%, except for Br, Rb, Ag, Sb, Te, Au, and the REE.The Plainview C2 xenolith has normal trace element abundances, except for 3 elements falling appreciably above the C2 range: Rb, Cs, and Bi. Hydrothermal alteration may be the reason for all 3, though nebular fractionation remains a possibility for Bi.     

A model for multiphase flow and transport in porous media including a phenomenological approach to account for deformation—a model concept and its validation within a code intercomparison study

Multiphase flow processes in unsaturated cohesive soils are often affected by deformation due to swelling and shrinking as a result of varying water contents. This paper presents a model concept which is denoted ‘phenomenological’ in terms of the processes responsible for soil deformation, since the effects of deformation on flow and transport are only considered by constitutive relations that allow an adaptation of the hydraulic properties. This new model is validated in a detailed intercomparison study with two state-of-the-art models that are capable of explicitly describing the processes relevant for the deformation. A ‘numerical experiment’ with a state-of-the-art reference model is used to produce ‘measurement data’ for an inverse-modelling-based estimation of the model input parameters for the phenomenological concept.     

Towards continuous long-term measurements of suspended particulate matter (SPM) in turbid coastal waters

The dynamics of sediment transport in the East Frisian Wadden Sea are important for the coastal zone and for ecosystem functioning. The tidal inlets between the East Frisian islands connect the back-barrier intertidal flats to the North Sea. Here, concentrations of suspended particulate matter (SPM) in the water column are highly variable, depending on weather conditions and tides. In order to estimate the nature and quantity of sediment transport, in situ measurements were carried out at a Time Series Station in the tidal inlet between the islands of Spiekeroog and Langeoog. This study shows the suitability of multispectral transmissometry (MST) for obtaining long-term SPM measurements with high resolution. The comparability of this technique to the standard filter method and the laser diffraction method [laser in situ scattering and transmissometry (LISST)] is demonstrated. In addition, the Junge coefficients derived from both MST and LISST measurements are compared. A time series of SPM data covering nearly 4 months is presented. As a major result, the data reveal that a single storm surge can have less impact on SPM dynamics than longer-lasting gales. This high-resolution long-term data set is very valuable for modelling suspended matter flux. It also provides background information for studying the influence of SPM dynamics on coastal sediments.     

Crustal thickness estimation beneath the southern central Andes at 30°S and 36°S from S wave receiver function analysis

We have used the S wave receiver function (SRF) technique to investigate the crustal thickness beneath two seismic profiles from the CHARGE project in the southern central Andes. A previous study employing the P wave receiver function method has observed the Moho interface beneath much of the profiles. They found, however, that the amplitude of the P to S conversion was diminished in the western part of the profiles and have attributed it to a reduction of the impedance contrast at the Moho due to lower crustal ecologitization. With SRF, we have successfully detected S to P converted waves from the Moho as well as possible conversions from other lithospheric boundaries. The continental South American crust reaches its maximum thickness of ∼70 km (along 30°S between 70°W and 68.5°W) beneath the Principal Cordillera and the Famatina system and becomes thinner towards the Sierras Pampeanas with a thickness of ∼40 km. Negative phases, possibly related to the base of the continental and oceanic lithosphere, can be recognized in the summation traces at different depths. By comparing our results with data obtained from previous investigations, we are able to further constrain the thickness of the crust and lithosphere beneath the central Andes.     

Laboratory measurements of the association rate coefficients of NO+, O+2, N+, and N+2 ions with N2 and CO2 at temperatures between 100 k and 400 k

Rate coefficients for the association reactions of NO⁺ ions with N₂ and CO₂, O₂⁺ with N₂, and N⁺ and N₂⁺ with N₂ have been determined as a function of gas temperature in a laboratory experiment employing a variable-temperature drift-tube apparatus. The measured rate coefficients were fitted to power laws of the form $\text{k = C}\text{(}\text{T}\text{300}\text{)}{}^{\mathrm{x}}$ where the exponents x ranged from 2.2 to 4.3. The strong temperature dependence observed in the case of the reaction of NO⁺ with N₂ (x = 4.3) supports the thesis by Arnold et al. (1979) that the temperature variability of D-region ion densities is a result of this reaction step in the ion clustering sequence.