Effect of phosphatation and calcination on the environmental behaviour of sediments

Dredging operations produce considerable quantities of materials, to be managed and this opens an opportunity for valorization in civil engineering. However, the contamination of the dredged sediments has become a major problem to solve. The major contaminants are heavy metals and organic compounds. This study focuses on the use of phosphoric acid (H3PO4) to stabilize heavy metals from sediments and destroy organic matter by calcination at 650 °C with a goal of using sediments in roadworks. Several studies have been conducted in this eld. The stabilized materials obtained have been used in civil engineering. The main purpose of this work is to discuss the environmental behavior of marine sediment treated by phosphatation and calcination. Two types of phosphoric acids were used. The pH dependence leaching test has been used as the basic characterization to evaluate the effect of the type of phosphoric acid on the metals behavior in a valorization scenario. The standard leaching test and the Toxicity Characteristic Leaching Procedure (TCLP) were conducted as compliance tests. In regards of the obtained results, the environmental assessment has also shown a reduction in the availability of targeted heavy metals in alkaline environment whatever the type of acid used for treatment. This opens opportunities for co-valorization.     

Environmental factors structuring fish composition and assemblages in a small macrotidal estuary (eastern English Channel)

The fish assemblage structure was analyzed along an estuarine gradient of a small macrotidal estuary (the Canche, France). Fishes were collected every two months between May 2006 and July 2007 from 12 sampling stations using a 1.5-m beam trawl with a 5 mm mesh size in the cod end. To complement this information, sampling was also performed using 15-m fyke nets (8 mm mesh size in the cod end). For each sample, abiotic (temperature, salinity, pH, oxygen, turbidity, river flow, wind speed and depth) and biotic (macro crustacean species abundances) were recorded. Throughout the study, 28 fish species belonging to 20 families were collected. Fish catches were dominated by juveniles, especially Young-Of-the-Year (YOY) for the majority of the species. According to the Index of Relative Importance (IRI), common goby Pomatoschistus microps, flounder Platichtys flesus, sprat Sprattus sprattus, sea-bass Dicentrarchus labrax and plaice Pleuronectes platessa were the most abundant species, together accounting for 99.2% of the total IRI. Estuarine residents (ER = 66.2%) and marine juvenile migrants species (MJ = 31.4%) were the most important ecological guilds. The structure of the fish assemblage and its relationship to environmental variables was examined using multivariate techniques. Cluster and non-metric multidimensional scaling (nMDS) analysis defined six distinct groups in the Canche estuary, which are discriminated by specific species (SIMPER). Spatio-temporal variations in fish assemblage structure reflect the density peaks of the most abundant species. Spearman rank correlations and canonical correspondence analysis (CCA) showed that among the ten environmental variables examined, temperature, salinity and Crangon crangon (a potential predator for YOY fish or prey for older ones) are the three most important factors influencing fish species richness and abundances. Our observations reinforce the idea that certain fish species may have different life history styles in different geographic areas. The present study highlights the necessity of a better knowledge of the connectivity between estuaries and adjacent marine areas. The Canche constitutes an important ecosystem for fishes and as it is subject to little anthropogenic disturbance; its ichthyofauna can be viewed as a reference or normal assemblage for small temperate macrotidal estuaries.     

Spatial gradient of temperature and potential vegetation feedback across Europe during the late Quaternary

After the last glacial maximum (LGM; 18,000 years. bp) plants migrated onto areas made free by the retreating ice sheets. Pollen records document changes in ecosystems and are an important proxy for the reconstruction of climate parameters. Here, we quantify changes in January temperature (Tjan) over the past 14,000 years using 216 European pollen records. We used functional principal component analysis to evaluate the patterns of change over this period of time. Between 14 and 12 ka, Tjan records show comparable changes across Europe. After this time period, northwest and southeast Europe experienced differing trends in Tjan, trends that became pronounced by 9 ka. The spatial gradient of Tjan records is well-correlated with the overall change from steppe to increasingly diverse forest ecosystems. In particular, differential incorporation of conifer vs. deciduous species into forest ecosystems, based on differential colonization out of refugia, likely resulted in albedo gradients over Europe that affected regional Tjan.     

An XPEEM study of structural cation distribution in swelling clays. I. Synthetic trioctahedral smectites

X-PEEM images and XPS were collected on isolated layers of three synthetic swelling clays, one hectorite and two saponites with various charge, recording the Si(2p), Al(2p) and Mg(2p) core level spectra from the clay sheets. Spectra were fitted to determine the different components of the core levels. Due to their large full width at half maximum, Si XPS spectra were fitted using two to three doublets. It appears that, for a given clay mineral, Si, Al and Mg binding energies (BE) were constant, for all the observed layers. However, variations of the Si BE were observed depending on the nature of the mineral investigated. The various components obtained from the fit of Si spectra could be assigned to different substitution rates; binding energy shifting to lower values with substitution increase in the layer. Furthermore, variations in Si BE according to charge location were assigned to the influence of exchangeable cation.     

“Anti-glitches” in the Quark–Nova model for AXPs I

In the Quark–Nova model, Anomalous X-ray Pulsars (AXPs) are quark stars surrounded by a degenerate iron-rich Keplerian ring (a few stellar radii away). AXP bursts are caused by accretion of chunks from the inner edge of the ring following magnetic field penetration. For bright bursts, the inner disk is prone to radiation induced warping which can tilt it into counter-rotation (i.e. retrograde). For AXP 1E2259+586, the 2002 burst satisfies the condition for the formation of a retrograde inner ring. We hypothesize the 2002 burst reversed the inner ring setting the scene for the 2012 outburst and “anti-glitch” when the retrograde inner ring was suddenly accreted leading to the basic observed properties of the 2012 event.     

Improvement of the JRC Calculation Using Different Parameters Obtained Through a New Survey Method Applied to Rock Discontinuities

This paper presents a new, fast and economical method for digitizing a rock surface profile to determine its joint roughness coefficient (JRC) value (Barton and Choubey, Rock Mech Rock Eng 10:1–54, 1977) using a set of existing parameters, the appropriateness of which has been tested. The new procedure was applied to four rock road cuts in the Alpujarra area of Granada province (Andalusia, Spain), supported by 117 digitized profiles. The method avoids any personal subjectivity bias. The usual subjectivity in the visualization and assessment of the JRC value is estimated here by a survey test answered by 90 trained users. The survey test consisted of a set of JRC visual comparisons of 12 roughness profiles, selected from the 117 profiles surveyed during the field research in the Alpujarra region, with the Barton typical profiles. The results of the survey clearly show systematic inaccuracies in the traditional procedure that are reduced if the advice presented in the conclusions of this paper is taken in account when performing the visual estimation.     

Spatial and morphometric relationships of submarine landslides offshore west and southwest Iberia

Landslides - Submarine landslides are a ubiquitous geohazard in the marine environment and occur at multiple scales. Increasing efforts have been made during the last decade to catalogue and...     

The Importance of the Precipitation and the Susceptibility of the Slopes for the Triggering of Landslides Along the Roads

In order to characterise the influence of the heavyrains on the observed landslides during the 1996–1997hydrological cycle, rainfall records for the last 100years are analysed from 104 stations in easternAndalusia. Regarding the amounts of rain recordedbetween October 1996 and March 1997 in the 104stations studied, 31 presented new all-time records;15 presented values that were 80–100% of thepre-1995 record; 49 stations, 80–50%; and 9stations, < 50%. A map has been devised of thesusceptibility of the materials through which thesouth-eastern Andalusian road network crosses,together with an inventory of the damage caused byinstability phenomena on banks and cuttings of theroad network during the winter of 1996–1997. Therelationships between the rainfall during the studyperiod, the damage caused to the road network and thesusceptibility of the materials affected are analysed.The results indicate that there is a clearcorrespondence between the rainfall recorded and thesusceptibility of the materials with the inventorieddamage. It is concluded that the widespread seriousdamage caused in early 1997 to the roads andsurrounding areas in the Alpujarra region and thecoast of the Province of Granada was mainly caused bythe extraordinarily heavy rains. However, considerablyless damage was observed where the susceptibility ofthe terrain is low, thus highlighting the extremeusefulness of terrain-susceptibility maps for riskprevention and territorial planning.     

Influence of a Brazilian sewage outfall on the toxicity and contamination of adjacent sediments

The submarine sewage outfall of Santos (SSOS) is situated in the Santos Bay (São Paulo, Brazil) and is potentially a significant source of contaminants to the adjacent marine ecosystem. The present study aimed to assess the influence of SSOS on the sediment toxicity and contamination at Santos Bay. At the disposal site, sediments tended to be finer, organically richer and exhibited higher levels of surfactants and metals, sometimes exceeding the “Threshold Effect Level” values. The SSOS influence was more evident toward the East, where the sediments exhibited higher levels of TOC, total S and metals during the summer 2000 sampling campaign. Sediment toxicity to amphipods was consistently detected in four of the five stations studied. Amphipod survival tended to correlate negatively to Hg, total N and % mud. This work provides evidence that the SSOS discharge affects the quality of sediments from Santos Bay, and that control procedures are warranted.     

Première caractérisation palynologique du Trias moyen dans le Haut Atlas ; implications pour l'initiation du rifting téthysien au Maroc

The Middle Anisian has been palynologically characterized for the first time, at the whole Moroccan scale, in the High Atlas of Marrakech. The stratigraphic, tectonic and paleogeographic implications of this discovery are analysed. To cite this article: E.H. El Arabi et al., C. R. Geoscience 338 (2006).